Viscous material

In a wide-mouthed test-tube ( boiling tube ) place 5 g. of phenol, 15 ml. of 40 per cent, formaldehyde solution and 3 ml. of concentrated ammonia solution (sp. gr. 0-88). Warm the mixtme with a small flame until it becomes opaque. Cool, discard the aqueous layer, but retain the viscous material in the tube. Heat the latter in a water bath at 60° for 30 minutes and then heat the pasty mass in an air oven at 75° for 4-6 hours. A hard sohd resin is produced. 

Sepro Conta.iner, The Sepro container consists of a collapsible plastic bag fitted into a standard three-piece, tin-plated container such as a 202 X 214, 202 x 406, or 202 x 509 can. The product is placed within the bag, and the propellant is added through the bottom of the container, which is fitted with a one-way valve. There is no limitation on the viscosity of the product but compatibiUty with the plastic bag must be considered. A free-dowing hquid can be dispensed either as a stream or a fine spray, depending on the type of valve employed. A viscous material is often dispensed as a stream. This system has been used for caulking compounds, postfoaming gels, and depilatories. 

Applications. The high heat tolerance and good salt compatibiUty of welan gum indicate its potential for use as an additive in several aspects of oil and natural gas recovery. Welan also has suspension properties superior to xanthan gum, which is desirable in oil-field drilling operations and hydraulic fracturing projects. It is compatible with ethylene glycol, and a welan—ethylene glycol composition that forms a viscous material useful in the formulation of insulating materials has been described (244). 

Ko//M //s. When dispersion is requited ia exceedingly viscous materials, the large surface area and small mixing volume of roU mills allow maximum shear to be maintained as the thin layer of material passiag through the nip is continuously cooled. The roUs rotate at different speeds and temperatures to generate the shear force with preferential adhesion to the warmer roU. 

In knife-over-roll or blade coating, the coating material is placed on the fabric surface behind a knife, or doctor blade, and metered according to the gap set between the blade and the fabric surface. This method is used to apply thick coatings of highly viscous materials such as pastes, plastisols, or foams. 

Fig. 15. Stress—strain diagrams, (a) Viscous material of viscosity Tj the stress is independent of strain, but dependent on the speed of testing, (b) Elastic material of modulus E the slope is the modulus which is independent of the speed of testing.

Piston Cylinder (Extrusion). Pressure-driven piston cylinder capillary viscometers, ie, extmsion rheometers (Fig. 25), are used primarily to measure the melt viscosity of polymers and other viscous materials (21,47,49,50). A reservoir is connected to a capillary tube, and molten polymer or another material is extmded through the capillary by means of a piston to which a constant force is appHed. Viscosity can be determined from the volumetric flow rate and the pressure drop along the capillary. The basic method and test conditions for a number of thermoplastics are described in ASTM D1238. Melt viscoelasticity can influence the results (160). 

Figure 36 is representative of creep and recovery curves for viscoelastic fluids. Such a curve is obtained when a stress is placed on the specimen and the deformation is monitored as a function of time. During the experiment the stress is removed, and the specimen, if it can, is free to recover. The slope of the linear portion of the creep curve gives the shear rate, and the viscosity is the appHed stress divided by the slope. A steep slope indicates a low viscosity, and a gradual slope a high viscosity. The recovery part of Figure 36 shows that the specimen was viscoelastic because relaxation took place and some of the strain was recovered. A purely viscous material would not have shown any recovery, as shown in Figure 16b. 

Agitator discs are available is several forms smooth, perforated, eccentric, and pinned. Effect of disc design has received limited study, but pinned discs are usually reserved for highly viscous materials. 

When it is deleterious, laminar flow can be avoided by mixing over the cross section. For this purpose static mixers in line can be provided. For very viscous materi s and pastes, screws of the type used for pumping and extrusion are used as reactors. 

The exponential term appears for the same reason as it does in diffusion it describes the rate at which molecules can slide past each other, permitting flow. The molecules have a lumpy shape (see Fig. 5.9) and the lumps key the molecules together. The activation energy, Q, is the energy it takes to push one lump of a molecule past that of a neighbouring molecule. If we compare the last equation with that defining the viscosity (for the tensile deformation of a viscous material)... 

Static sampling systems are defined as those that do not have an active air-moving component, such as the pump, to pull a sample to the collection medium. This type of sampling system has been used for over 100 years. Examples include the lead peroxide candle used to detect the presence of SO2 in the atmosphere and the dust-fall bucket and trays or slides coated with a viscous material used to detect particulate matter. This type of system suffers from inability to quantify the amount of pollutant present over a short period of time, i.e., less than 1 week. The potentially desirable characteristics of a static sampling system have led to further developments in this type of technology to provide quantitative information on pollutant concentrations over a fked period of time. Static sampling systems have been developed for use in the occupational environment and are also used to measure the exposure levels in the general community, e.g., radon gas in residences. 

Figure 9.7. Types of deformalional response as a result of a fixed load being imposed betweem times to and ti (a), (b) Ordinary elastic material, (c) Highly elastic material, (d) Viscous material...

It is important that care should be taken to remove residual caustic soda and other contaminates when preparing the higher molecular weight resins and in order to avoid the difficulty of washing highly viscous materials these resins may be prepared by a two-stage process. 

Resin viscosity is an important property to consider in handling the resins. It depends on the molecular weight, molecular weight distribution, chemical constitution of the resin and presence of any modifiers or diluents. Since even the diglycidyl ethers are highly viscous materials with viscosities of about 40-100 poise at room temperature it will be appreciated that the handling of such viscous resins can present serious problems. 

Fire Hazards - Flash Point Non flammable solution Flammable Limits in Air (%) Not pertinent Fire Extinguishing Agents Not pertinent Fire Extinguishing Agents Not To Be Used Not pertinent Special Hazards of Combustion Products Not pertinent Behavior in Fire Exposure to heat can cause polymerization to a combustible, viscous material Ignition Temperature Not pertinent Electrical Hazard Not pertinent Burning Rate Not pertinent. 

It is particularly significant that no evidence is found for localized melting at particle interfaces in the inorganic materials studied. Apparently, effects commonly observed in dynamic compaction of low shock viscosity metals are not obtained in the less viscous materials of the present study. To successfully predict the occurrence of localized melting, it appears necessary to develop a more realistic physical model of energy localization in shock-compressed powders. 

Harz-alkohol, m. resin alcohol, -austauscher, m. ion-exchange resin, -baum, m. pitch tree (applied to various conifers), -bildung, /. resin (or rosin) formation, (of gasoline) giim-ming. -brei, m. a viscous material trapped in the pores of a synthetic plastic, resin magma, -cerat, n. Pharm.) rosin cerate, -elektrizi-tat, /. resinous (negative) eleetricity. 

Used for viscous materials has inner and outer flights. 

The work of Uhl [22] gave particular emphasis to viscous materials in Jacketed vessels, and the correlating equations are ... 

Uh , V. W., Heat Transfer to Viscous Materials in Jacketed Agitated Ketdes, Chem. Eng. Prog. Symposium, Series No. 17, 31, 1955, 93. 

In vacuum service, the large fraction of the tube length used for sensible heating leaves little density difference for thermal circulation. This fact, plus the frequent need for circulating viscous materials, points towards forced-circulation reboilers for vacuum service. 

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