Standard Raman spectroscopy

APPLICATIONS OF FT-RAMAN SPECTROMETRY 18.4.1. Standard Raman Spectroscopy 

As noted above, Raman spectra of most solid or liquid samples can be measured with an FT-Raman spectrometer. Solid samples such as polymers can often be 

One of the advantages of Raman spectroscopy that is listed in most textbooks on instrumental analysis is the fact that it is easier to measure the Raman spectra of solutes in aqueous solution than the infrared spectrum. This claim is based on the 

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Using standard Raman spectroscopy for surface studies leads to rather tedious experiments because of its generally very low sensitivity. In contrast, SERS often provides high sensitivity due to a giant enhancement. The first paper on SERS pubhshed by the Van Duyne group reported a million-fold enhanced Raman intensity for pyridine molecules adsorbed on a silver electrode compared with the Raman intensity for unbound pyridine molecules [21]. Hence, SERS makes it possible to detect submonolayer quantities of adsorbates. 

We would like to mention one further practical application of standard Raman spectroscopy, namely the method of Raman lidar, which is now routinely used to monitor the upper atmosphere for composition (e.g. the presence of water vapour), chemical processes (e.g. the generation or depletion of ozone (O3)), and the determination of temperature profiles at high altitudes. Although absorption and fluorescence lidar systems are also widely used, Raman lidar has the distinct advantage that it is a simultaneous multispecies measurement technique, and that only a single fixed-wavelength laser is required. 

The resonance-enhanced method offers three major advantages over standard Raman spectroscopy ... 

All nonlinear (electric field) spectroscopies are to be found in all temis of equation (B 1.3.1) except for the first. The latter exclusively accounts for the standard linear spectroscopies—one-photon absorption and emission (Class I) and linear dispersion (Class II). For example, the temi at third order contains by far the majority of the modem Raman spectroscopies (table B 1.3.1 and tableBl.3.2). 

Undeniably, one of the most important teclmological achievements in the last half of this century is the microelectronics industry, the computer being one of its outstanding products. Essential to current and fiiture advances is the quality of the semiconductor materials used to construct vital electronic components. For example, ultra-clean silicon wafers are needed. Raman spectroscopy contributes to this task as a monitor, in real time, of the composition of the standard SC-1 cleaning solution (a mixture of water, H2O2 and NH OH) [175] that is essential to preparing the ultra-clean wafers. 

D. A. Long. Raman Spectroscopy. McGraw-Hill, New York, 1977. A standard reference work on Raman spectroscopy with much theoretical detail on the underlying physics. Most of the needed equations for any application of Raman spectroscopy can be found in this book. 

In Raman spectroscopy the intensity of scattered radiation depends not only on the polarizability and concentration of the analyte molecules, but also on the optical properties of the sample and the adjustment of the instrument. Absolute Raman intensities are not, therefore, inherently a very accurate measure of concentration. These intensities are, of course, useful for quantification under well-defined experimental conditions and for well characterized samples otherwise relative intensities should be used instead. Raman bands of the major component, the solvent, or another component of known concentration can be used as internal standards. For isotropic phases, intensity ratios of Raman bands of the analyte and the reference compound depend linearly on the concentration ratio over a wide concentration range and are, therefore, very well-suited for quantification. Changes of temperature and the refractive index of the sample can, however, influence Raman intensities, and the band positions can be shifted by different solvation at higher concentrations or... 

QCMB RAM SBR SEI SEM SERS SFL SHE SLI SNIFTIRS quartz crystal microbalance rechargeable alkaline manganese dioxide-zinc styrene-butadiene rubber solid electrolyte interphase scanning electron microscopy surface enhanced Raman spectroscopy sulfolane-based electrolyte standard hydrogen electrode starter-light-ignition subtractively normalized interfacial Fourier transform infrared... 

For electrolytes where dissociation is extensive, but not complete, the classification is somewhat arbitrary, and the electrolyte can be considered to be either strong or weak. Thermodynamics does not prevent us from treating an electrolyte either way, but we must be careful to designate our assignment because the choice of standard state is different for a strong electrolyte and a weak electrolyte. Assuming that an electrolyte is weak requires that we have some nonthermodynamic procedure for distinguishing clearly between the dissociated and undissociated species. For example, Raman spectroscopy... 

In either case, the information on the vibrational transition is contained in the energy difference between the excitation radiation and the inelastically scattered Raman photons. Consequently, the parameters of interest are the intensities of the lines and their position relative to the Rayleigh line, usually expressed in wavenumbers (cm 1). As the actually recorded emissions all are in the spectral range determined by the excitation radiation, Raman spectroscopy facilitates the acquisition of vibrational spectra through standard VIS and/or NIR spectroscopy. 

Though Raman spectroscopy and HPLC provide important tools for the chemistry of cyclic selenium sulfides it will be essential to design new chemical reactions for the preparation of as pure phases as possible. With identification and characterization of each new molecule a new standard for HPLC has been obtained and more information gained of the nature of sulfur-selenium pha s. Synthetic chemistry, Raman spectroscopy, and HPLC may well provide the key for a better understanding of the molecular composition of the cyclic selenium sulfides prepared according to the above-mentioned methods. 

IQiowledge of parameters such as reactivity ratios, is necessary for synthesis of polymer based resists, and an accurate method of analysis should be useful in various areas associated with resist development such as quality control. Raman spectroscopy provides a convenient, absolute, nondestructive method for compositional analysis of polymer systems which, if an internal standard is present, does not require standards of known composition or ancillary calibration curves. The accuracy, with appropriate selection of experimental conditions such as slit width and integration time, is limited only by the instrumentation. 

IR spectroscopy is a fast, simple, and cheap method for the qualitative detection of certain functional groups on insoluble supports [77-79]. Dried supports can be used directly to prepare KBr pellets for standard recording of IR spectra [54,80-82], Newer IR-based techniques, which require much less support material than required for a KBr pellet, include single-bead FT-IR spectroscopy [16,77,83-86], single-bead Raman spectroscopy [87], near-IR multispectral imaging [88], and the simultaneous analysis of several different beads by FT-IR microscopy for analysis of combinatorial libraries [89,90],... 

Means of study Standard absorption spectroscopy Infrared and Raman spectroscopy Nuclear magnetic resonance... 

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