Solids insoluble solid

Total Solids Soluble Solids (%) Insoluble Solids (%) Sol. Solids (%) Tot. Solids (%) Insol. Solids (%) Total Solids (%)... 

I. I-dichli)rt)ethene, I. l-dichloroethylene, asymmetric dichloroethene, CH2=CCl2, colourless liquid, b.p. 37 C. Prepared by heating 1,1,1- or 1,1,2-trichloroethene with excess lime at 70-80 C. Polymerizes readily to an insoluble solid. 

The lower members of the series are liquids soluble in water and volatile in steam. As the number of carbon atoms in the molecule increases, the m.p. and b.p. rise and the acids become less soluble in water and less volatile. The higher fatty acids are solids, insoluble in water and soluble in organic solvents. 

Aluminium oxide is a white solid, insoluble in water, with a very high melting point. If heated above red heat, it becomes insoluble in acids and alkalis, and can only be brought into solution by first fusing it with sodium or potassium hydroxide when an aluminate is formed. 

Manganese(IV) oxide is a dark-brown solid, insoluble in water and dilute acids. Its catalytic decomposition of potassium chlor-ate(V) and hydrogen peroxide has already been mentioned. It dissolves slowly in alkalis to form manganates(lW), but the constitution of these is uncertain. It dissolves in ice-cold concentrated hydrochloric acid forming the complex octahedral hexachloromangan-ate(IV) ion ... 

Copperil) chloride, CuCl, is a white solid, insoluble in water. It is prepared as follows ... 

Zinc(II) oxide, ZnO, is prepared by heating the hydroxide ZnlOH) or the carbonate ZnCOj. It is a white solid, insoluble in water, but readily soluble in acids to give a solution containing the zincfll) cation, and in alkalis to give a hydroxozincate(II) anion ... 

The product, commonly called calomel, is a white solid, insoluble in water in its reactions (as expected) it shows a tendency to produce mercury(II) and mercury. Thus under the action of light, the substance darkens because mercury is formed addition of aqueous ammonia produces the substance HjN—Hg—Hg—Cl, but this also darkens on standing, giving HjN—Hg—Cl and a black deposit of mercury. 

B). Many nitriles when treated with hydrogen peroxide in warm alkaline solution undergo hydrolysis to amides which can thus be readily obtained in high yield. Insoluble liquid nitriles can be treated directly in the aqueous suspension, but for insoluble solid nitriles the addition of a suitable organic solvent to give a complete solution may be desirable, although the completion of the hydrolysis may not then be so readily detected. 

Physical Properties. Nitrobenzene, C HjNOj pale yellow liquid, insoluble in and heavier than water, characteristic odour of bitter almonds, (similar to that of benzaldehyde and benzonitrile). /> Nitro toluene, C,H4(CH3)N02, usually pale yellow solid, insoluble in water, m-Dinitrobenzene, C8H4(N02)g, colourless solid when pure, but often pale yellow insoluble in water. 

Dilute sodium hydroxide solution (and also sodium carbonate solution and sodium bicarbonate solution) can be employed for the removal of an organic acid from its solution in an organic solvent, or for the removal of acidic impurities present in a water-insoluble solid or liquid. The extraction is based upon the fact that the sodium salt of the acid is soluble in water or in dilute alkali, but is insoluble in the organic solvent. Similarly, a sparingly soluble phenol, e.g., p-naphthol, CioH,.OH, may be removed from its solution in an organic solvent by treatment with sodium hydroxide solution. 

Method 2. Place a 3 0 g. sample of the mixture of amines in a flask, add 6g. (4-5 ml.) of benzenesulphonyl chloride (or 6 g. of p-toluenesulphonyl chloride) and 100 ml. of a 5 per cent, solution of sodium hydroxide. Stopper the flask and shake vigorously until the odour of the acid chloride has disappeared open the flask occasionally to release the pressure developed by the heat of the reaction. AUow the mixture to cool, and dissolve any insoluble material in 60-75 ml. of ether. If a solid insoluble in both the aqueous and ether layer appears at this point (it is probably the sparingly soluble salt of a primary amine, e.g., a long chain compound of the type CjH5(CH2) NHj), add 25 ml. of water and shake if it does not dissolve, filter it off. Separate the ether and aqueous layers. The ether layer will contain the unchanged tertiary amine and the sulphonamide of the secondary amine. Acidify the alkaline aqueous layer with dilute hydrochloric acid, filter off the sulphonamide of the primary amine, and recrystaUise it from dilute alcohol. Extract the ether layer with sufficient 5 per cent, hydrochloric acid to remove all the tertiary amine present. Evaporate the ether to obtain the sulphonamide of the secondary amine recrystaUise it from alcohol or dilute alcohol. FinaUy, render the hydrochloric acid extract alkaline by the addition of dilute sodium hydroxide solution, and isolate the tertiary amine. 

An insoluble solid that forms when two or more soluble reagents are combined. 

The specific ability of certain finely divided, insoluble solids to sta-bihze foam has long been known [Berkman and Egloff, op. cit., p. 133 and Bikerman, op. cit.. Chap. II]. Bartsch [Kolloidchem. Beth, 20, I (1925)] found that the presence of fine galena greatly extended the life of air foam in aqueous isoamyl alcohol, and the finer the sohds, the... 

Composition Uiagrants In its elemental form, a leaching system consists of three components inert, insoluble solids a single non-adsorbed solute, which may be liqmd or solid and a single solvent. Thus, it is a ternaiy system, albeit an unusual one, as already mentioned, by virtue of the total mutual Mnsolubility of two of the phases and the simple nature of equilibrium. 

Naphthalene-l-sulfonyl chloride [85-46-1] M 226.7, m 64-67°, 68°, b 147.S°/0.9mm, 147.S°/13mm. If the IR indicates the presence of OH then treat with an equal weight of PCI5 and heat at ca 100° for 3h, cool and pour into ice + H2O, stir well and filter off the solid. Wash the solid with cold H2O and dry the solid in a vacuum desiccator over P2O5 + solid KOH. Extract the solid with pet ether (b 40-60°) filter off any insoluble solid and cool. Collect the crystalline sulfonyl chloride and recryst from pet ether or C6H6 pet ether. If large quantities are available then it can be distd under high vacuum. [Fierz-Davaid and Weissenbach Helv Chim Acta 3 2312 1920.] The sulfonamide has m 150° (from EtOH or H2O). 

Where inerting is not used, one guideline restricts operations to metal or enameled metal tanks having a volume no greater than 5 m, a diameter no greater than 3 m and all conductive parts grounded. The liquid should contain a maximum of 1 wt% insoluble solids, have a maximum feed rate of 60 L/min and the delivery pressure should not exceed 50 bar. The vessel should be continuously drained to prevent liquid accumulation [127]. 

Nickel peroxide is a solid, insoluble oxidant prepared by reaction of nickel (II) salts with hypochlorite or ozone in aqueous alkaline solution. This reagent when used in nonpolar medium is similar to, but more reactive than, activated manganese dioxide in selectively oxidizing allylic or acetylenic alcohols. It also reacts rapidly with amines, phenols, hydrazones and sulfides so that selective oxidation of allylic alcohols in the presence of these functionalities may not be possible. In basic media the oxidizing power of nickel peroxide is increased and saturated primary alcohols can be oxidized directly to carboxylic acids. In the presence of ammonia at —20°, primary allylic alcohols give amides while at elevated temperatures nitriles are formed. At elevated temperatures efficient cleavage of a-glycols, a-ketols... 

In either case the Pb contains numerous undesirable metal impurities, notably Cu, Ag, Au, Zn, Sn, As and Sb, some of which are clearly valuable in themselves. Copper is first removed by liquation the Pb bullion is melted and held just above its freezing point when Cu rises to the surface as an insoluble solid which is skimmed off. Tin, As and Sb are next removed by preferential oxidation in a reverberatory furnace and skimming off the oxides alternatively, the molten bullion is churned with an oxidizing flux of molten NaOH/NaN03 (Harris process). The softened Pb may still contain Ag, Au and perhaps Bi. Removal of the first two depends on their preferential solubility in Zn the mixed metals are cooled slowly from 480° to below 420° when the Zn (now containing nearly all the Ag and Au) solidifies as a crust which is skimmed off the... 

The eluate was titrated to pH 7 with 0572N NaOH (63 ml). Removal of solvent left a gum, which was boiled with methanol (400 ml) for 20 minutes. The solid insoluble inorganic phosphate was filtered off and washed with methanol (200 ml). The slightly cloudy filtrate was filtered again, and evaporated to dryness in vacuo. The residual gum dissolved readily in water (40 ml) and on addition of acetone (600 ml) to the solution a mixture of sodium salts of hydrocortisone 21 -phosphate separated as a white solid. This was collected after 2 days, washed with acetone and dried at 100°C/0.1 mm/2 hrto constant weight. Yield4.45g. 

Procedure The sodium methoxide is cautiously added in portions to 200 ml of methanol with stirring. Some heat is evolved. To this warm solution is rapidly added the ethyl acetoacetate with continued stirring. The solution is stirred for 10 minutes and then cooled in an ice-salt-acetone mixture (-25°C). If desired a Dry Ice-acetone cooling bath may be used to shorten the addition time. The crude material from (B) is dissolved in 200 ml of methanol. At this point it Is probably easier to filter this mixture by suction to remove a large amount of insoluble solid, which is probably sodium chloride. The solid may be rinsed with more methanol. 

Sometimes when water solutions of two different ionic compounds are mixed, an insoluble solid separates out of solution. The precipitate that forms is itself ionic the cation comes from one solution, the anion from the other. To predict the occurrence of reactions of this type, you must know which ionic substances are insoluble in water. 

Metallic Cations, mobile — Metallic bond Variable mp good conductors in solid insoluble in Na... 

Precipitate A solid that forms when two solutions are mixed, 78 Precipitation diagram, 78 Precipitation reaction Formation of an insoluble solid when two electrolyte solutions are mixed, 78,95-96q diagram, 78... 

Among the chemical methods proposed for the objective measurement of maturity may be listed total solids, alcohol-insoluble solids, and starch, based upon the fact that these constituents increase in concentration with maturity. Each has its limitations and advantages, and all are equally applicable as long as the limitations are taken into account. These methods as they apply to frozen peas have been discussed by Nielsen and co-workers (31) and by Lee (22). 

The determination of alcohol-insoluble solids as a means for grading peas can... 

Additional problems that may cause serious contamination of the treated MU water are those related to carryover and after-precipitation from external treatment processes. Both of these processes may result in the presence of insoluble solids in the various lines, tanks, and valve areas of the pre-boiler section. Some solids may even pass through to the boiler. 

In a precipitation reaction, an insoluble solid product forms when we mix two electrolyte solutions. When an insoluble substance is formed in water, it immediately precipitates. In the chemical equation for a precipitation reaction, we use (aq) to indicate substances that are dissolved in water and (s) to indicate the solid that has precipitated ... 

STRATEGY First, write and balance the complete ionic equation, showing all the dissolved ions as they actually exist in solution, as separate, charged ions. Insoluble solids are shown as complete compounds. Next, cancel the spectator ions, the ions that remain in solution on both sides of the arrow. 

We can now see why nature has adopted an ionic solid, calcium phosphate, for our skeletons the doubly charged small Ca2+ ions and the triply charged P04, ions attract one another very strongly and clump together tightly to form a rigid, insoluble solid (Fig. 2.8)... 

As a starting point we can view the ocean as one large reservoir to which materials are continuously added and removed (Fig. 10-17). The major sources of material include rivers and winds, which carry dissolved and particulate materials from the continents to the sea. The major removal process is the formation of marine sediments both by settling of particles through the water column as well as by precipitation of insoluble solid phases. For many ele-... 

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