Slow processes

Although lusting is normally a slow process, it can be rapid under some conditions. Two men collapsed in an evaporator, which had contained warm, moist magnesium chloride. One of them later died. Afterward, tests showed that the oxygen content fell to 1% in 24 hours [9, 10]. Other tests showed that corrosion rates increased ten times when the relative humidity increased from 38% to 52% [11]. 

The commeicialization of new watei-soluble polymers is most often a slow process. Eor example, hydroxyethylceUulose (HEC) was envisaged in 1937 by 

Mixing. The most widely used mixing method is wet ball milling, which is a slow process, but it can be left unattended for the whole procedure. A ball mill is a barrel that rotates on its axis and is partially filled with a grinding medium (usually of ceramic material) in the form of spheres, cylinders, or rods. It mixes the raw oxides, eliminates aggregates, and can reduce the particle size. 

For complexes such as Ar-H2, Ar-HF and Ar-lTCl, vibrational predissociation is a very slow process and does not cause appreciable broadening of the lines in the infrared spectmm. Indeed, for Ar-ITF, ITuang et al [20] showed that 

Mixing of fluids is a discipline of fluid mechanics. Fluid motion is used to accelerate the otherwise slow processes of diffusion and conduction to bring about uniformity of concentration and temperature, blend materials, facihtate chemical reactions, bring about intimate contact of multiple phases, and so on. As the subject is too broad to cover fully, only a brier introduction and some references for further information are given here. 

For most color photographic systems, development is the rate determining step, and within that step the formation of semiquinone is the slow process (37). The fate of the highly reactive QDI is deterrnined by the relative rates of a number of competing processes (38). The desired outcome is reaction with ionized coupler to produce dye (eq. 3). Typically, the second-order rate constant for this process with ionized coupler is about 10 to 10  

For a chemical reaction such as combustion to proceed, mixing of the reactants on a molecular scale is necessary. However, molecular diffusion is a very slow process. Dilution of a 10-m diameter sphere of pure hydrocarbons, for instance, down to a flammable composition in its center by molecular diffusion alone takes more than a year. On the other hand, only a few seconds are required for a similar dilution by molecular diffusion of a 1-cm sphere. Thus, dilution by molecular diffusion is most effective on small-scale fluctuations in the composition. These fluctuations are continuously generated by turbulent convective motion. 

Evidence of 3, 4, 8, and 9 was reported by Todesco and coworkers (51, 87, 88), while 2 and 8 were found by Illuminati and coworkers (96). The ring-opening reaction is a slow process in methanol and can be made faster using a solvent such as DMSO. 

Excretion factors are often related to lipophilicity. More lipophilic compounds tend to be excreted by the Hver into the bile, resulting in elimination ultimately in the feces. As this is a relatively slow process, much of the radioactivity having a shorter half-life decays before being eliminated. Polar compounds are more likely to be excreted by the kidneys. 

Heat is produced by chemical reaction in a reaction zone. The heat is transported, mainly by conduction and molecular diffusion, ahead of the reaction zone into a preheating zone in which the mixture is heated, that is, preconditioned for reaction. Since molecular diffusion is a relatively slow process, laminar flame propagation is slow. Table 3.1 gives an overview of laminar burning velocities of some of the most common hydrocarbons and hydrogen. 

In addition to time-related effects, the soUd-state physical properties are also affected by adsorbed water, which functions as a plasticizer. Water pickup is affected by the nature of the cation, with sodium ionomers absorbing about 10 times the level of the zinc equivalent (6) under the same conditions. Drying must be carried out at temperatures below 100°C and is therefore a slow process. In commercial practice, ionomers are suppUed dry, and techniques have been developed to minimize moisture absorption during processing. 

Other properties of association colloids that have been studied include calorimetric measurements of the heat of micelle formation (about 6 kcal/mol for a nonionic species, see Ref. 188) and the effect of high pressure (which decreases the aggregation number [189], but may raise the CMC [190]). Fast relaxation methods (rapid flow mixing, pressure-jump, temperature-jump) tend to reveal two relaxation times t and f2, the interpretation of which has been subject to much disagreement—see Ref. 191. A fast process of fi - 1 msec may represent the rate of addition to or dissociation from a micelle of individual monomer units, and a slow process of ti < 100 msec may represent the rate of total dissociation of a micelle (192 see also Refs. 193-195). 

In the bacterial reaction center the photons are absorbed by the special pair of chlorophyll molecules on the periplasmic side of the membrane (see Figure 12.14). Spectroscopic measurements have shown that when a photon is absorbed by the special pair of chlorophylls, an electron is moved from the special pair to one of the pheophytin molecules. The close association and the parallel orientation of the chlorophyll ring systems in the special pair facilitates the excitation of an electron so that it is easily released. This process is very fast it occurs within 2 picoseconds. From the pheophytin the electron moves to a molecule of quinone, Qa, in a slower process that takes about 200 picoseconds. The electron then passes through the protein, to the second quinone molecule, Qb. This is a comparatively slow process, taking about 100 microseconds. 

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