Runoff river

As a specific example, consider oceanic sulfate as the reservoir. Its main source is river runoff (pre-industrial value 100 Tg S/yr) and the sink is probably incorporation into the lithosphere by hydrogeothermal circulation in mid-ocean ridges (100 Tg S/yr, McDuff and Morel, 1980). This is discussed more fully in Chapter 13. The content of sulfate in the oceans is about 1.3 X lO TgS. If we make the (im-realistic) assumption that the present runoff, which due to man-made activities has increased to 200 Tg S/yr, would continue indefinitely, how fast would the sulfate concentration in the ocean adjust to a new equilibrium value The time scale characterizing the adjustment would be To 1.3 X 10 Tg/(10 Tg/yr) 10 years and the new equilibrium concentration eventually approached would be twice the original value. A more detailed treatment of a similar problem can be found in Southam and Hay (1976). 

Unlike other biogeochemical elements, phosphorus does not have a significant atmospheric reservoir. Thus, while some amount of phosphorus is occasionally dissolved in rain, this does not represent an important link in the phosphorus cycle. River runoff is the primary means of transport between the land surface and oceans, and unlike the other elements discussed. 

The dependence of the oxygen content in reservoirs on the hydrological input to the system opens the interesting possibility of using long-term hydrological data to quantify the impact of recent climate change. Since precipitation and river runoff... 

The dominant supply of U to the oceans is from the continents by river runoff Palmer and Edmond (1993) measured dissolved U concentrations in a number of rivers and summarized existing literature to arrive at a total flux close to that of Cochran (1992) of 11 X 10 g/year. This flux is uncertain by about 35% due to inadequate sampling of rivers with large seasonal cycles (Palmer and Edmond 1993). 

River runoff and i situ production are the major sources of U-Th series nuclides (Table 1) to the oceans. The concentrations of the various U-Th series nuclides in rivers vary considerably and depend upon several factors prime among them being their chemical reactivity [13], the chemistry of river water, and the nature of the river bed. 

Besides, publications of rivers runoff and ratio in wet and dry season are usually out of data or average values, which have been changed greatly by human in past decades. To this day, we can t get exact runoff data for different departments data share difficulty. 

The concentrations of seawater and brackish water can vary significantly, and as such there is a difference between the concentrate produced from seawater desalination plants and brackish water desahnation plants. Seawater typically has a level of total dissolved solids (TDS) between 33,000-37,000 mg/L. The average major ion concentration of seawater is shown in Table 2.1 along with water from the Mediterranean Sea, and water from Wonthaggi off the southern coast of Australia. Seawater sahnity increases in areas where water evaporates or freezes, and it decreases due to rain, river runoff, and melting ice. The areas of greatest salinity occur and latitudes of 30° N and S where there are high evaporation rates. 

The ion proportions in most river water is significantly different from that in seawater. As a result, river runoff can have a local impact on the ion ratios of coastal waters. This effect is most pronounced in marginal seas and estuaries where mixing with the open ocean is restricted and river input is relatively large. The variable composition of river water and its impact on the chemical composition of seawater are discussed further in Chapter 21. 

Once in the atmosphere, the water evaporates and some of the sea salt falls back to the sea surfece. The rest is transported considerable distances by winds imtil it is washed out of the atmosphere by rainfall. The salts that are transported back to the continents by this process are termed cyclic salts. After having been rained out onto the continents, the salts are carried back into the ocean by river runoff On short time scales, the global cycling of chlorine and sodium are dominated by this process. The cyclic salts are discussed further in Chapter 21. 

In the Broecker Box model, the total amount of water in the ocean is assumed to remain constant over time. In other words, the evaporation rate and burial of water in the sediments is equal to the rate of water input from river runoff and precipitation. The sizes of the surface- and deep-water reservoirs are also assumed to remain constant over time. This requires the global rate of upwelling to equal the global rate of downwelling. 

From the perspective of the surface box, the biolimiting elements are supplied via river runoff and from upweUing. The elements are removed via the sinking of biogenic particles and downwelling. Since this model considers only the transport of materials into and out of the ocean and between the two reservoirs, details as to what happens to the elements while they reside in the boxes are not needed other than that they are present in a steady state. In such a case, the input rate of a biolimiting element will equal its output rate. For the surface-water reservoir, the mass balance that describes this steady state is given by... 

Up welling flux + River runoff flux = Downwelling flux + Particle flux (91)... 

Therefore, the up welling flux is computed as x the river runoff flux as p ver ... 

In this model, the rate of river runoff (uriver) expressed as the depth of a layer of water produced by spreading the annual river-water input across the entire surfece area of the ocean. The annual amount of river water entering the ocean is 47,000 km /y (Figure 2.1). Assuming that the average area of the ocean is equal to that at the sea surfece (3.6 x 10 cm ), the river input represents the annual addition of a layer of water approximately 10 cm deep, making y ver = lOcm/y. 

For phosphorus,/x g = 0.01 x 0.95 = 0.01. This means that only 1 percent of the phosphorus introduced into the ocean by river runoff is removed to the sediments during each mixing cycle. 

The trace elements are introduced into seawater by river runoff, atmospheric transport, hydrothermal venting, groundwater seeps, diffusion from the sediments, and transport from outer space, usually as micro meteorites. The magnitudes of the first three of these fluxes, which are considered to be the major ones, are given in Table 11.1. Anthropogenic activities have significantly increased some of these fluxes, as discussed later. 

Trace elements are discharged into the ocean in particulate and dissolved form as a component of river runoff and groundwater seeps. They are introduced into these waters during the chemical and mechanical weathering of crustal rocks. Thus, the chemical composition of river water is dependent on the composition of the rocks in the... 

Th, Co, and, in some locations, Fe. Surfece-water enrichments are usually caused by rapid rates of supply to the mixed layer via atmospheric deposition or river runoff. Removal usually occurs through relatively rapid precipitation into or adsorption onto sinking particles. Trace elements controlled by scavenging tend to have short (100 to lOOOy) residence times. Since these residence times are less than the mixing time of the ocean, significant geographic gradients are common. 

Weathered fragments of continental crust comprise the bulk of marine sediments. These particles are primarily detrital silicates, with clay minerals being the most abmidant mineral type. Clay minerals are transported into the ocean by river runoff, winds, and ice rafting. Some are authigenic, being produced on and in the seafloor as a consequence of volcanic activity, diagenesis and metagenesis. 

Direct evidence supporting the occurrence of reverse weathering has proven difficult to obtain for two reasons. First, the same kinds of clay minerals produced by this process are also transported to the ocean as part of the suspended load in river runoff. Second, the rate of reverse weathering is so slow that laboratory studies of this process are difficult to conduct. 

A box model fiar the marine silica cycle is presented in Figure 6.11 with respect to the processes that control DSi and BSi. An oceanic budget is provided in Table 16.3 in which site-specific contributions to oceanic outputs are given. This table illustrates that considerable uncertainty still exists in estimating the burial rate of BSi. Regardless, burial of BSi is responsible for most of the removal of the oceanic inputs of DSi, with the latter being predominantly delivered via river runoff. This demonstrates the importance of the biological silica pump in the crustal-ocean-atmosphere factory. 

On the early Earth, ions were mobilized from volcanic rocks by chemical weathering. Rivers and hydrothermal emissions transported these chemicals into the ocean, making seawater salty. These salts are now recycled within the crustal-ocean-atmosphere fectory via incorporation into sediments followed by deep burial, metamorphosis into sedimentary rock, uplift, and weathering. The last process remobilizes the salts, enabling their redelivery to the ocean via river runoff and aeolian transport. In the case of sodium and chlorine, evaporites are the single most important sedimentary sink. This sedimentary rock is also a significant sink for magnesium, sulfate, potassium, and calcium. 

Shallow-water embayments provide a mechanism to isolate seawater so that evaporation can raise salt ion concentrations. Arid climates are required to ensure that the rate of water loss from evaporation exceeds the rate of water supply by rainfell, groundwater seeps, or river runoff. Seawater can be resupplied continuously via a type of antiestuar-ine circulation as illustrated in Figure 17.2 or episodically as a result of sea level change, plate tectonics, or very high tides and storm surges. 

Trace metals are introduced to the ocean by atmospheric feUout, river runoff, and hydrothermal activity. The latter two are sources of soluble metals, which are primarily reduced species. Upon introduction into seawater, these metals react with O2 and are converted to insoluble oxides. Some of these precipitates settle to the seafloor to become part of the sediments others adsorb onto surfaces of sinking and sedimentary particles to form crusts, nodules, and thin coatings. Since reaction rates are slow, the metals can be transported considerable distances before becoming part of the sediments. In the case of the metals carried into the ocean by river runoff, a significant fraction is deposited on the outer continental shelf and slope. Hydrothermal emissions constitute most of the somce of the metals in the hydrogenous precipitates that form in the open ocean. 

Biogeochemists are working to construct numerical models that include all of these interlinked feedbacks to explain how the chemistry of seawater has changed over time in response to various forces, including tectonism, biological activity, ocean-atmosphere interactions, crustal weathering, and river runoff To incorporate all of these linkages into a numerical multielemental model of seawater is very complex because most of... 

The distribution of sediment types in the Pacific Ocean is much different from that of the Atlantic. Except for the coastline of the northwest United States, the Pacific is ringed by deep-sea trenches and, hence, has relatively narrow continental shelves. The trenches effectively trap all the terrigenous particles carried to the sea by river runoff. The Pacific Ocean is much wider than the other oceans thus the flux of wind-borne lithogenous particles is spread over a much greater area and produces a much lower mass flux, on an areal basis, to the seafloor. This makes other particles relatively important in determining the composition of the sediments in the Pacific ocean. 

The continental shelves cover most of the seafloor in the Arctic Ocean, making this the shallowest ocean. Thus, most of the sediments are neritic. Because of light limitation, primary production is inhibited, so river runoff and ice rafting supply most of the particles to this ocean. As a result, lithogenous and glacial marine sediments are most common. 

One of the most notable features of seawater is its high degree of saltiness. In previous chapters, we have discussed various sources of this salt, these being rivers, volcanic gases, and hydrothermal fluids. These elements have ended up in one of four places (1) as dissolved ions in seawater, (2) as sedimentary minerals, (3) as hydrothermal minerals, and (4) as volatiles that reside in the atmosphere. The minerals are recycled via geologic uplift and subduction. Upon return to Earth s surface, these minerals are chemically weathered via acid attack by the atmospheric volatiles remobilizing the salts for return to the ocean in river runoff. 

---