Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Physics, quantum

Tracing the historical development of quantum physics, the author describes the baffling and seemingly lawless world of leptons, hadrons, gluons and quarks and provides a lucid and exciting guide for the layman to the world of infinitesimal particles. [Pg.440]

Chemistry students are familiar with spectrophotometry, the qualitative and quantitative uses of which are widespread in contemporary chemistry. The various features of absorption spectra are due to the absorption of radiation to promote a particle from one quantized energy state to another. The scattering phenomena we discuss in this chapter are of totally different origin classical not quantum physics. However, because of the relatively greater familiarity of absorption spectra, a comparison between absorption and scattering is an appropriate place to begin our discussion. [Pg.660]

Stehle, P. (1994) Order, Chaos, Order The Transition from Classical to Quantum Physics (Oxford University Press, Oxford) pp. 55, 123. [Pg.155]

E.N. Economou, Green s Functions in Quantum Physics, Springer Series in Solid State Sciences, Vol. 7 Springer, Berlin (1983), p.l52 ff. [Pg.282]

This morc-philosophicai view of Ihc elements has come to the rescue of chemistry as its own field, rather than simply a pari of physics, on more than one occasion. It suggests that chemistry possesses an essential philoscphlcal foundation even though It Is popularly presumed lo reduce to quantum physics and thus to be devoid of a philosophical character. In the early years of the 20th century, when Isotopes of many elements were discovered, it suddenly seemed as if the number of "elements," in the sense of simplest substances, that can be Isolated had multiplied. Some chemists believed that this proliferation would signal the demise of the periodic table, which would give way to a table of Ihe isotopes. [Pg.128]

In any particular situation, it is usually possible to give a variety of reasons why the observed quantity behaves in an erratic manner. The observed quantity may be critically dependent on certain parameters and the observed fluctuations attributed to slight variations of these parameters. The implication here is that the observed fluctuations appear erratic only because we have not taken the trouble to make a sufficiently precise analysis of the situation to disclose the pattern the observations are following. It is also possible, in some situations, to adopt the viewpoint that certain aspects of the phenomenon being studied are inherently unknowable and that the best physical laws we can devise to explain the phenomenon will have some form of randomness or unpredictability built into them. Such is the case, for example, with thermal noise voltages, which are believed to be governed by the probabilistic laws of quantum physics. [Pg.99]

Sokolov, A. V., and Shirokovski, V. P., Group Theoretical Methods in the Quantum Physics of Solids (Spatial Symmetry), Soviet Physics—Uspekhi, 3, 651 (1961). [Pg.768]

In optical domain, preamplifier is no more an utopia and is in actual use in fiber communication. However quantum physics prohibits the noiseless cloning of photons an amplifier must have a spectral density of noise greater than 1 photon/spatial mode (a "spatial mode" corresponds to a geometrical extent of A /4). Most likely, an optical heterodyne detector will be limited by the photon noise of the local oscillator and optical preamplifier will not increase the detectivity of the system. [Pg.368]

Porphyrin is a multi-detectable molecule, that is, a number of its properties are detectable by many physical methods. Not only the most popular nuclear magnetic resonance and light absorption and emission spectroscopic methods, but also the electron spin resonance method for paramagnetic metallopor-phyrins and Mossbauer spectroscopy for iron and tin porphyrins are frequently used to estimate the electronic structure of porphyrins. By using these multi-detectable properties of the porphyrins of CPOs, a novel physical phenomenon is expected to be found. In particular, the topology of the cyclic shape is an ideal one-dimensional state of the materials used in quantum physics [ 16]. The concept of aromaticity found in fuUerenes, spherical aromaticity, will be revised using TT-conjugated CPOs [17]. [Pg.70]

Singer, Computational Methods in Classical and Quantum Physics, The Many-Body Problem in Statistical Mechanics, Ed. by M. B. Hooper, Advance Pub., London, 1976, p. 289. [Pg.200]

Gribbin, John. In Search of Schrodinger s Cat Quantum Physics and Reality. New York Bantam Books, 1984. [Pg.127]

The harmonic oscillator is an important system in the study of physical phenomena in both classical and quantum mechanics. Classically, the harmonic oscillator describes the mechanical behavior of a spring and, by analogy, other phenomena such as the oscillations of charge flow in an electric circuit, the vibrations of sound-wave and light-wave generators, and oscillatory chemical reactions. The quantum-mechanical treatment of the harmonic oscillator may be applied to the vibrations of molecular bonds and has many other applications in quantum physics and held theory. [Pg.106]

Nothing is quite what it seems in this fizzy, heady brew. Alchemy, tarot cards and cabbalistic theology mix with coincidence and quantum physics to create a world of virtual reality. .. the writing is often sharply, blackly funny"... [Pg.714]

Byron, F. W. Jr. and Fuller, R. W., Mathematics of Classical and Quantum Physics, Addison-Wesley Publishing Company, Reading, Massachusetts (1969). [Pg.408]

Roepstorff, G., Path Integral Approach to Quantum Physics, Springer Berlin, Heidelberg, New York, 1994... [Pg.196]

A straightforward definition of the term ab initio is from the beginning , from the first principles . Ab initio calculation of some property implies not using any experimental data or input, but relating the calculated property only to the fundamental constants entering the applied quantum-physical laws. [Pg.153]

Gieser, Suzanne. 2005. The Innermost Kernel Depth Psychology and Quantum Physics. Wolfgang Pauli s Dialogue with C. G. Jung. Berlin Springer. [Pg.240]

Heller, E. J. Chaos and Quantum Physics, edited by M. J. Giannoni, A. Voros, and J. Zinn-Justin (Elsevier, Amsterdam, 1991). [Pg.134]

The previous result is an important one. It indicates that there can be yet another fruitful route to describe lipid bilayers. The idea is to consider the conformational properties of a probe molecule, and then replace all the other molecules by an external potential field (see Figure 11). This external potential may be called the mean-field or self-consistent potential, as it represents the mean behaviour of all molecules self-consistently. There are mean-field theories in many branches of science, for example (quantum) physics, physical chemistry, etc. Very often mean-field theories simplify the system to such an extent that structural as well as thermodynamic properties can be found analytically. This means that there is no need to use a computer. However, the lipid membrane problem is so complicated that the help of the computer is still needed. The method has been refined over the years to a detailed and complex framework, whose results correspond closely with those of MD simulations. The computer time needed for these calculations is however an order of 105 times less (this estimate is certainly too small when SCF calculations are compared with massive MD simulations in which up to 1000 lipids are considered). Indeed, the calculations can be done on a desktop PC with typical... [Pg.51]

Bonding of Quantum Physics with Quantum Chemistry References. [Pg.1]

BONDING OF QUANTUM PHYSICS WITH QUANTUM CHEMISTRY ... [Pg.1]

The bond that developed between quantum physics and quantum chemistry, that led to the award of a big chemistry prize to the physicist Walter Kohn in 1998, developed not without trial. Here I give an account of it. An element in this bond has been a friendship between Walter Kohn and me. My having reached 80 first, he has already kindly spoken of this [1], Now it is my turn. [Pg.1]

Sources for the History of Quantum Physics, Office for the History of Science and Technology, University of California at Berkeley University College, London, Archives... [Pg.17]

On the other hand, Perrin made confused remarks from the standpoint of quantum physics "We need not believe that the absorption of radiation is discon-... [Pg.143]

But it was not really until 1931, when Slater and Pauling independently developed methods to explain directed chemical valence by orbital orientation that it can truly be said that a chemical quantum mechanics, rather than an application of quantum mechanics to chemistry, had been created. In a study of Slater, S. S. Schweber notes the distinction between the Heitler-London-Pauling-Slater theory and the Heitler-London theory. Heitler and London successfully explained the electron-valence pair on the basis of the Goudsmit-Uhlenbeck theory of spin. Slater and Pauling explained the carbon tetrahedron. This second explanation distinguishes quantum chemistry from quantum physics.2... [Pg.244]

Assmus, Alexi. "Molecular Structure and the Genesis of the American Quantum Physics Community 19161926."... [Pg.303]


See other pages where Physics, quantum is mentioned: [Pg.78]    [Pg.7]    [Pg.775]    [Pg.780]    [Pg.402]    [Pg.5]    [Pg.369]    [Pg.373]    [Pg.232]    [Pg.575]    [Pg.24]    [Pg.28]    [Pg.185]    [Pg.308]    [Pg.229]    [Pg.93]    [Pg.339]    [Pg.289]    [Pg.289]    [Pg.20]    [Pg.27]    [Pg.245]    [Pg.269]   
See also in sourсe #XX -- [ Pg.28 , Pg.52 , Pg.98 , Pg.130 ]

See also in sourсe #XX -- [ Pg.118 ]

See also in sourсe #XX -- [ Pg.5 ]

See also in sourсe #XX -- [ Pg.84 ]

See also in sourсe #XX -- [ Pg.18 ]

See also in sourсe #XX -- [ Pg.96 , Pg.99 ]

See also in sourсe #XX -- [ Pg.121 ]

See also in sourсe #XX -- [ Pg.257 ]

See also in sourсe #XX -- [ Pg.71 , Pg.72 ]

See also in sourсe #XX -- [ Pg.2 ]

See also in sourсe #XX -- [ Pg.136 ]




SEARCH



© 2024 chempedia.info