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Precision analysis

Dravid et al. examined anisotropy in the electronic structures of CNTs from the viewpoint of momentum-transfer resolved EELS, in addition to the conventional TEM observation of CNTs, cross-seetional TEM and precise analysis by TED [5]. Comparison of the EEL spectra of CNTs with those of graphite shows lower jc peak than that of graphite in the low-loss region (plasmon loss), as shown in Fig. 7(a). It indicates a loss of valence electrons and a change in band gap due to the curved nature of the graphitic sheets. [Pg.35]

Some conseivation measures do not easily fit into the form of an initial investment followed by a stream of energy savings because there will be other costs and benefits occurring during the measure s operating life. Furthermore, it is difficult to incorporate peak power benefits into the CCE approach. In these situations, a more precise analysis will be necessary. However, the CCE and supply cuive approaches provide first-order identifications of cost-effective conseivation, those... [Pg.290]

Perhaps, first of all, we must know that our food is nutritious, that it contains the elements essential to growth and maintenance of our bodies in optimum amount along with the calories needed for the fuel supply. As our living habits become more complex, we are increasingly dependent on precise analysis because the naturally balanced diet of our ancestors is no longer to be had by most of us. [Pg.1]

In any particular situation, it is usually possible to give a variety of reasons why the observed quantity behaves in an erratic manner. The observed quantity may be critically dependent on certain parameters and the observed fluctuations attributed to slight variations of these parameters. The implication here is that the observed fluctuations appear erratic only because we have not taken the trouble to make a sufficiently precise analysis of the situation to disclose the pattern the observations are following. It is also possible, in some situations, to adopt the viewpoint that certain aspects of the phenomenon being studied are inherently unknowable and that the best physical laws we can devise to explain the phenomenon will have some form of randomness or unpredictability built into them. Such is the case, for example, with thermal noise voltages, which are believed to be governed by the probabilistic laws of quantum physics. [Pg.99]

An analysis of alcohol and alcohol ether sulfates should determine the anionic active matter, the unsulfated matter, the inorganic sulfate content, the chloride content, and water. Other more precise analysis must determine the alkyl chain distribution of the alcohol and in the case of alcohol ether sulfates the number of ethoxy groups and its distribution, as well as other more specialized determinations, such as the content of 1,4-dioxane and other impurities. [Pg.278]

In terms of the carbanion equivalent, the enolase superfamily has a strong relation with decarboxylation reaction. This family is characteristic in its promiscuity. If one is reminded of the phrase lock and key theory for the relation between the substrate and the enzyme, the word promiscuity of the enzyme may be unbelievable. However, in addition to natural promiscuity, we can change the enzyme to be promiscuous by introducing mutation, especially in the case of the enolase superfamily. This will be one of the challenging problems in future. For that purpose, biotechnology and informatics skill will be essential tool in addition to precise analysis of the reaction mechanism. [Pg.339]

Hotta, J., Takasaki, H., Eujiwara, H. and Sasaki, K. (2002) Precise analysis of optically trapped particle position and interaction forces in the vidnity of an interface. Int. J. Nanosci., 1, 645-649. [Pg.131]

Accuracy for all thorium measurements by TIMS is limited by the absence of an appropriate normalization isotope ratio for internal correction of instrumental mass fractionation. However, external mass fractionation correction factors may be obtained via analysis of suitable thorium standards, such as the UC-Santa Cruz and IRMM standards (Raptis et al. 1998) for °Th/ Th, and these corrections are usually small but significant (< few %o/amu). For very high precision analysis, the inability to perform an internal mass fractionation correction is probably the major limitation of all of the methods for thorium isotope analysis discussed above. For this reason, MC-ICPMS techniques where various methods for external mass fractionation correction are available, provide improved accuracy and precision for Th isotope determinations (Luo et al. 1997 Pietruszka et al. 2002). [Pg.37]

Marechal CN, Telouk P, Alberede F (1999) Precise analysis of copper and zinc isotopic compositiorrs by plasma-source mass spectrometry. Chem Geol 156 251-273 Martin P, Hancock GJ, Paulka S, Akber RA (1995) Determination of Ac-227 by alpha-particle spectrometry. Appl Radiat Isot 46 1065-1070... [Pg.57]

Yokoyama T, Makishima A, Nakamura E (2001) Precise analysis of ratio using U02 ion with... [Pg.59]

Figure 2. Histograms of Monte Carlo simulations for two synthetic analyses (Table 1) of a 330 ka sample. The lower precision analysis (A) has a distinctly asymmetric, non-Gaussian distribution of age errors and a misleading first-order error calculation. The higher precision analysis (B) yields a nearly symmetric, Gaussian age distribution with confidence limits almost identical those of the first-order error expansion. Figure 2. Histograms of Monte Carlo simulations for two synthetic analyses (Table 1) of a 330 ka sample. The lower precision analysis (A) has a distinctly asymmetric, non-Gaussian distribution of age errors and a misleading first-order error calculation. The higher precision analysis (B) yields a nearly symmetric, Gaussian age distribution with confidence limits almost identical those of the first-order error expansion.
For a precise analysis of the shear rate dependent viscosity it is necessary to know at which critical rate of deformation shear-induced disturbance can no longer be leveled out by the recoil of the polymers. [Pg.25]

Because the templates compete for amplification and, in the case of reverse transcription PCR (RT-PCR), also for reverse transcription, any variable affecting amplification has the same effect on both. Thus, the ratio of PCR products reflects the ratio of the initial amounts of the two templates as demonstrated by the function C/W=C (l+ )"/Wi(l+ )n, where Cand Ware the amounts of competitor and wild-type product, respectively, and C and W are the initial amounts of competitor and wild-type template, respectively, (Clementi etal., 1993). From this linear relationship, it could be concluded that a single concentration of competitor could be sufficient for quantitating unknown amounts of wild-type templates. However, in practice, the precise analysis of two template species in very different amounts has proved difficult and cPCRs using three to four competitor concentrations within the expected range of wild-type template concentrations are usually performed. In a recent study of different standardization concepts in quantitative RT-PCR assays, coamplification on a single concentration of a competitor with wild-type template was comparable to using multiple competitor concentrations and was much easier to perform (Haberhausen et al, 1998). [Pg.214]

According to the demands of the analysis, analytical chemistry can be classified into analysis of major components (major component analysis, precision analysis, investigation of stoichiometry), minor components, and trace components (trace analysis, ultra trace analysis). On the other hand, analytical problems are differentiated according to the number of analytes involved. Accordingly, single component and multicomponent analysis are distinguished. [Pg.34]

It was found that the concentration of total oxidants measured in the off-gas from the hypo unit varied with process conditions. Precise analysis of the off-gas showed that under certain conditions chlorine dioxide is formed in the reaction step where the hypochlorite concentration is approximately 160-180 g l-1. In the sections below formation of chlorine dioxide in the hypochlorite unit is discussed with regard to process conditions and peak load of the feed stream. In essence, the emission of chlorine dioxide can be reduced to nearly zero by using a scrubber in which the chlorine dioxide reacts with hydrogen peroxide. [Pg.319]

For reactions in solvents of much lower DC, such as chloroform or benzene, the situation is of course entirely different, because then ion-pairs, and perhaps higher aggregates, will dominate the reaction pattern, and in such circumstances counter-ion effects are of course quite plausible. However, at present we have no experimental information which would be of use in a more precise analysis of such systems. [Pg.419]

The point where the heat production rate reaches its maximum value is of critical importance for a chemical process. This maximum value needs to be compared with the total given maximum heat removal capacity. A reaction going to completion can be considered safe, for normal operation, if the maximum heat removal capacity is greater than the maximum heat production rate. For more precise analysis see the literature 19, 10, 11/. [Pg.236]

Gas liquid chromatography (GLC) or gas chromatography (GC) finds its abundant applications in the accurate and precise analysis of plethora of official pharmaceutical substances covering a wide range as enumerated below ... [Pg.445]

In these time-resolved studies, a simplified, non-normalized theory [i.e., effectively lacking the division by PT in Eq. (7.34)] was used for comparison with the experimental results, so that the observed fluorescence from any region was assumed to be proportional to the local evanescent intensity in that region. A more precise analysis must take into account that distance from the interface affects the angular distribution of emission and that fluorescence lifetimes are necessarily affected by the proximity of the dielectric interface. [Pg.325]

Norman M, McCulloch M, O Neill H, Brandon A (2004) Magnesium isotopes in the Earth, Moon, Mars, and Pallasite parent body high precision analysis of olivine by laser ablation multi-collector ICPMS. Lunar and Planetary Science Conference XXXV 1447... [Pg.230]

Fitzsimons et al. (2000) have reviewed the factors that influence the precision of SIMS stable isotope data. All sample analyses must be calibrated for instrumental mass fractionation using SIMS analyses of a standard material. Under favorable circumstances, precision can reach a few tenths of a per mill. The latest version of ion-microprobe is the Cameca-lMS-1280 type, allowing further reduction in sample and spot size and achieving precise analysis of isotope ratios at the 0. %o level (Page et al. 2007). [Pg.33]

High precision analysis of the multiple rare isotopes of a specific element permit the distinction of different mass-dependent fractionation mechanisms. [Pg.290]

In many cases, determining the correct decision does not require perfect precision. Analysis can reveal whether the uncertainty makes it unclear what the best decision is. Because the bounds on uncertainty tend to tighten as we collect more data, as soon as the best decision is obvious, one can stop gathering data. For approximations that contain no associated statement about their own reliability, scientists tend to always clamor for more data no matter how much they already have. For approximations, it takes an explicit uncertainty analysis to discern whether the data are essential to make the decision at hand. [Pg.90]

There have been major advances in the development of both methods in recent years and fluorescence lifetime measurements on the picosecond time scale are now quite feasible. Precise analysis of the fluorescence decay revealed that even in the case of a peptide containing a single fluorophore multiexponential decay rather than single-exponential decay is often observed, as described by eq 5... [Pg.699]


See other pages where Precision analysis is mentioned: [Pg.463]    [Pg.461]    [Pg.874]    [Pg.259]    [Pg.303]    [Pg.465]    [Pg.627]    [Pg.392]    [Pg.273]    [Pg.137]    [Pg.52]    [Pg.41]    [Pg.231]    [Pg.188]    [Pg.217]    [Pg.294]    [Pg.150]    [Pg.64]    [Pg.235]    [Pg.210]    [Pg.257]    [Pg.222]    [Pg.706]   
See also in sourсe #XX -- [ Pg.6 ]

See also in sourсe #XX -- [ Pg.6 ]

See also in sourсe #XX -- [ Pg.125 ]

See also in sourсe #XX -- [ Pg.36 ]

See also in sourсe #XX -- [ Pg.125 ]




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