Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Quantitative measurements analytical techniques

The physicochemical approach to odor detection involves instrumental analysis of the chemical structure and concentration of an odorant. The relationship between the sensation of an odor as perceived by a human and the physical or chemical properties of the odor is not as simple as other sensations such as color or sound, which can be related to known physical forms such as intensity and wavelength. Measurement of odorant structure and concentration is possible through quantitative chemical analytical techniques. The ideal situation is to develop an instrument that is capable of replicating the human olfactory system without the added problems of human variability, sensitivity, and perception. [Pg.169]

For a detailed discussion on the analytical teclmiques exploiting the amplitude contrast of melastic images in ESI and image-EELS, see chapter B1.6 of this encyclopedia. One more recent but also very important aspect is the quantitative measurement of atomic concentrations in the sample. The work of Somlyo and colleagues [56]. Leapman and coworkers and Door and Gangler [59] introduce techniques to convert measured... [Pg.1645]

The potentiometric determination of an analyte s concentration is one of the most common quantitative analytical techniques. Perhaps the most frequently employed, routine quantitative measurement is the potentiometric determination of a solution s pH, a technique considered in more detail in the following discussion. Other areas in which potentiometric applications are important include clinical chemistry, environmental chemistry, and potentiometric titrations. Before considering these applications, however, we must first examine more closely the relationship between cell potential and the analyte s concentration, as well as methods for standardizing potentiometric measurements. [Pg.485]

Analytical Approaches. Different analytical techniques have been appHed to each fraction to determine its molecular composition. As the molecular weight increases, complexity increasingly shifts the level of analytical detail from quantification of most individual species in the naphtha to average molecular descriptions in the vacuum residuum. For the naphtha, classical techniques allow the isolation and identification of individual compounds by physical properties. Gas chromatographic (gc) resolution allows almost every compound having less than eight carbon atoms to be measured separately. The combination of gc with mass spectrometry (gc/ms) can be used for quantitation purposes when compounds are not well-resolved by gc. [Pg.167]

Analytical Techniques. Sorbic acid and potassium sorbate are assayed titrimetricaHy (51). The quantitative analysis of sorbic acid in food or beverages, which may require solvent extraction or steam distillation (52,53), employs various techniques. The two classical methods are both spectrophotometric (54—56). In the ultraviolet method, the prepared sample is acidified and the sorbic acid is measured at 250 260 nm. In the colorimetric method, the sorbic acid in the prepared sample is oxidized and then reacts with thiobarbituric acid the complex is measured at - 530 nm. Chromatographic techniques are also used for the analysis of sorbic acid. High pressure Hquid chromatography with ultraviolet detection is used to separate and quantify sorbic acid from other ultraviolet-absorbing species (57—59). Sorbic acid in food extracts is deterrnined by gas chromatography with flame ionization detection (60—62). [Pg.284]

The analytical techniques covered in this chapter are typically used to measure trace-level elemental or molecular contaminants or dopants on surfaces, in thin films or bulk materials, or at interfaces. Several are also capable of providing quantitative measurements of major and minor components, though other analytical techniques, such as XRF, RBS, and EPMA, are more commonly used because of their better accuracy and reproducibility. Eight of the analytical techniques covered in this chapter use mass spectrometry to detect the trace-level components, while the ninth uses optical emission. All the techniques are destructive, involving the removal of some material from the sample, but many different methods are employed to remove material and introduce it into the analyzer. [Pg.527]

Quantitation in high performance liquid chromatography, as with other analytical techniques, involves the comparison of the intensity of response from an analyte ( peak height or area) in the sample under investigation with the intensity of response from known amounts of the analyte in standards measured under identical experimental conditions. [Pg.40]

Resident Time Distribution (RTD) is widely employed in the chemical engineering industry, as an analytical tool for characterizing flow dynamics within reactor vessels. RTD provides a quantitative measure of the back-mixing with in a reactor system [2]. However the cost and time involved in building and operating a pilot- or full scale reactor for RTD analysis can be economically prohibitive. As such we have implemented a numerical RTD technique through the FLUENT (ver. 6.1) commercial CFD package. [Pg.669]

HPLC), an advanced, accurate, and well-developed technique for both qualitative and quantitative measurements based on reverse phase stationary phases, or ion pairs applied for analytical or preparative purposes. [Pg.523]

Quantitative and qualitative analytical techniques are of considerable importance in various aspects of life sciences for the purpose of detection, identification and measurement of concentrations of biologically important molecules, cells, chemical compounds, etc. [Pg.377]

Only arc/spark, plasma emission, plasma mass spectrometry and X-ray emission spectrometry are suitable techniques for qualitative analysis as in each case the relevant spectral ranges can be scanned and studied simply and quickly. Quantitative methods based on the emission of electromagnetic radiation rely on the direct proportionality between emitted intensity and the concentration of the analyte. The exact nature of the relation is complex and varies with the technique it will be discussed more fully in the appropriate sections. Quantitative measurements by atomic absorption spectrometry depend upon a relation which closely resembles the Beer-Lambert law relating to molecular absorption in solution (p. 357 etal.). [Pg.289]

The use of visible and UV spectrometry for quantitative analysis by comparing the absorbance of standards and samples at a selected wavelength is one of the most widespread of all analytical techniques. It is also one of the most sensitive. The analysis of mixtures of two or more components is facilitated by the additivity of absorbances. This has been discussed earlier (p. 356). Other applications include measurement of the absorption of complexes as a function of solution conditions or time to establish their composition, and to determine thermodynamic and kinetic stability for analytical purposes or for more fundamental studies. [Pg.372]

A large proportion of analytical measurements is subject to interference from other constituents of the sample. Newer methods increasingly employ instrumental techniques to distinguish between analyte and interference signals. However, such distinction is not always possible and sometimes a selective chemical reaction can be used to mask the interference. If this approach fails, the separation of the analyte from the interfering component will become necessary. Where quantitative measurements are to be... [Pg.614]

Stable-isotope dilution analysis is an analytical technique in which a known quantity of a stable-labelled isotope is added to a sample prior to extraction, in order to quantitate a particular compound. The ratio of the naturally abundant and the stable-labelled isotope is a measure of the naturally abundant compound and can be determined only by gas chromatography-mass spectrometry since the naturally abundant and the stable-labelled isotope cannot be completely separated gas chromatographically. [Pg.167]

As seen in Equations (14.2) and (14.4), the potential of cells and half-cells is dependent on the concentrations of the dissolved species involved. Clearly, the measurement of a potential can lead to the determination of the concentration of an analyte. This, therefore, is the basis for all quantitative poten-tiometric techniques and measurements to be discussed in this chapter. [Pg.398]

Measurement of fluorescence intensity can be used for quantitative analysis of fluorescent compounds where the intensity of fluorescence is proportional to the concentration of the compound. Because of their high sensitivity and selectivity, analytical techniques based on fluorescence detection are commonly used. If a target compound is fluorescent then direct detection of the fluorescence emitted is possible using a fluorimeter (Figure 4.7). [Pg.67]


See other pages where Quantitative measurements analytical techniques is mentioned: [Pg.536]    [Pg.1324]    [Pg.398]    [Pg.475]    [Pg.398]    [Pg.199]    [Pg.144]    [Pg.357]    [Pg.533]    [Pg.609]    [Pg.622]    [Pg.84]    [Pg.181]    [Pg.138]    [Pg.61]    [Pg.585]    [Pg.243]    [Pg.305]    [Pg.453]    [Pg.135]    [Pg.1004]    [Pg.150]    [Pg.475]    [Pg.67]    [Pg.534]    [Pg.623]    [Pg.25]    [Pg.69]    [Pg.16]    [Pg.289]    [Pg.959]    [Pg.143]    [Pg.339]    [Pg.252]   
See also in sourсe #XX -- [ Pg.136 ]




SEARCH



Analyte Analytical measurement

Analyte quantitation

Analyte, measurement

Analytical Quantitation

Analytical measurement

Analytical techniques

Quantitation measurements

Quantitative measure

Quantitative measurements

Quantitative techniques

© 2024 chempedia.info