Product particle size distribution

Results of an experimental program in which aluminum particles were burned with steam and mixtures of oxygen and argon in small-scale atmospheric dump combustor are presented. Measurements of combustion temperature, radiation intensity in the wavelength interval from 400 to 800 nm, and combustion products particle size distribution and composition were made. A combustion temperature of about 2900 K was measured for combustion of aluminum particles with a mixture of 20%(wt.) O2 and 80%(wt.) Ar, while a combustion temperature of about 2500 K was measured for combustion of aluminum particles with steam. Combustion efficiency for aluminum particles with a mean size of 17 yum burned in steam with O/F) / 0/F)st 1-10 and with residence time after ignition estimated at 22 ms was about 95%. A Monte Carlo numerical method was used to estimate the radiant heat loss rates from the combustion products, based on the measured radiation intensities and combustion temperatures. A peak heat loss rate of 9.5 W/cm was calculated for the 02/Ar oxidizer case, while a peak heat loss rate of 4.8 W/cm was calculated for the H2O oxidizer case. 

Figure 8.7 Combustion products particle size distributions for O2 oxidizer tests 1 — 02/Ar, 2 — H2O...

In this study, measurements of the combustion temperature, radiation intensity, combustion products particle size distribution, and combustion efficiency have been made for combustion of aluminum particles with steam in a small-scale atmospheric dump combustor. This data will be useful for designers of combustion chambers for burning of aluminum powder with steam. 

The pressure of C02 will affect the pH of the solutions, with one outcome that higher pH levels will result in smaller particles. Likewise, also mixing and stirring will affect particle size (distribution), to a large extent following general experiences with crystallization. Strong relationships between the product particle size (distribution) and the process conditions do not exist, however. 

Product particle size distributions of impact ground thermoplastics (specifically PETP and PVC) are interpreted and models describing these distributions developed. Results from multiple and single particle breakage in a hammer mill are used. The values of the model coefficients are related to the brittle-ductile transition grinding conditions and breakage mechanisms. Results are relevant to the separation of thermoplastics, as for example, is required when recycling consumer products such as bottles. 3 refs. 

The measurement of particle size is a key issue in the formulation of many pharmaceutical products. Particle size distribution is known to directly influence physical properties of powders, such as dissolution rate, powder flow, bulk density, and compressibility. Conventional methods of particle size measurement include sieve analysis and laser diffractometry. ... 

Improved sharpness of product particle size distribution and optimization of yield. Particularly if the primary granulator (22) has been installed in the... 

Slurries vary significantly in filtration characteristics. Even batch to batch variation in product particle size distribution and slurry concentration will greatly influence filterability and capacity of a given filter. It is, therefore, essential to evaluate a slurry in laboratory tests at a vendor s facility or at one s plant with rental equipment to prove the application. 

A classification effect at the top of the bed allows selective removal of the largest particles through the outlet pipe, yielding a relatively narrow product particle size distribution. 

A typical comminution process is depicted in Figure 5.10. A particular feature that comminution shares with granulation is the use of high solids recycle ratios to achieve the desired product particle size distribution. 

The RDX particle size distribution must be carefully controlled to produce castable slurries of RDX and TNT having acceptable viscosity. Several classes of RDX are produced to satisfy requirements for the various pressed and cast RDX-based compositions. A continuous process for medium-scale production of RDX has been developed by Biazzi based on the Woolwich process (79,151—154). 

Table 4. Particle Size Distribution of Ground Mica Products ...

The most commonly measured pigment properties ate elemental analysis, impurity content, crystal stmcture, particle size and shape, particle size distribution, density, and surface area. These parameters are measured so that pigments producers can better control production, and set up meaningful physical and chemical pigments specifications. Measurements of these properties ate not specific only to pigments. The techniques appHed are commonly used to characterize powders and soHd materials and the measutiag methods have been standardized ia various iadustries. 

Of the three worldwide manufacturers of poly(ethylene oxide) resins. Union Carbide Corp. offers the broadest range of products. The primary quaUty control measure for these resins is the concentrated aqueous solution viscosity, which is related to molecular weight. Specifications for Polyox are summarized in Table 4. Additional product specifications frequendy include moisture content, particle size distribution, and residual catalyst by-product level. 

Aluminum chlorohydrate [12359-72-7] Al2(OH) Gl 2H20 is a PAG product of specific composition, having r = 2.5. Aluminum chlorohydrate is used in antiperspirants regulated by the U.S. Food and Dmg Administration (FDA). Solutions sold for FDA-approved use are colorless in appearance, have 23—24% Al as AI2O2, and low levels of iron (<50 ppm), sulfate (<0.025 %), metals (Ga, Mg, Na <10 ppm), and heavy metals (as Pb <10 ppm). The pH of these solutions at 25°G is about 3.8—4.0. Typically, solutions at 25°G have specific gravities from 1.33 to 1.35 and viscosities from 40 to 60 mPa-s(=cps). Aluminum chlorohydrate [12042-91 -0] is also available in dry form with different particle-size distributions. 

Tantalum Compounds. Potassium heptafluorotantalate [16924-00-8] K TaF, is the most important tantalum compound produced at plant scale. This compound is used in large quantities for tantalum metal production. The fluorotantalate is prepared by adding potassium salts such as KCl and KF to the hot aqueous tantalum solution produced by the solvent extraction process. The mixture is then allowed to cool under strictiy controlled conditions to get a crystalline mass having a reproducible particle size distribution. To prevent the formation of oxyfluorides, it is necessary to start with reaction mixtures having an excess of about 5% HF on a wt/wt basis. The acid is added directiy to the reaction mixture or together with the aqueous solution of the potassium compound. Potassium heptafluorotantalate is produced either in a batch process where the quantity of output is about 300—500 kg K TaFy, or by a continuously operated process (28). 

The particle size distribution of Rhovanil Extra Pure vanillin shows a less narrow profile than other standard mesh grades available on the market. The product shows an improved mixabiUty in blending operations, allowing shorter blending time of compounds or food mixes, and better homogeneity of vanillin content, especially in low content vanillin blends. 

Suspension Polymerization. At very low levels of stabilizer, eg, 0.1 wt %, the polymer does not form a creamy dispersion that stays indefinitely suspended in the aqueous phase but forms small beads that setde and may be easily separated by filtration (qv) (69). This suspension or pearl polymerization process has been used to prepare polymers for adhesive and coating appHcations and for conversion to poly(vinyl alcohol). Products in bead form are available from several commercial suppHers of PVAc resins. Suspension polymerizations are carried out with monomer-soluble initiators predominantly, with low levels of stabilizers. Suspension copolymerization processes for the production of vinyl acetate—ethylene bead products have been described and the properties of the copolymers determined (70). Continuous tubular polymerization of vinyl acetate in suspension (71,72) yields stable dispersions of beads with narrow particle size distributions at high yields. 

In addition to surface area, pore size distribution, and surface chemistry, other important properties of commercial activated carbon products include pore volume, particle size distribution, apparent or bulk density, particle density, abrasion resistance, hardness, and ash content. The range of these and other properties is illustrated in Table 1 together with specific values for selected commercial grades of powdered, granular, and shaped activated carbon products used in Hquid- or gas-phase appHcations (19). 

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