Pressure sensitive adhesives types

Adhesives. Acryhc emulsion and solution polymers form the basis of a variety of adhesive types. The principal use is in pressure-sensitive adhesives, where a film of a very low T (<—20 " C) acrylic polymer or copolymer is used on the adherent side of tapes, decals, and labels. Acrylics provide a good balance of tack and bond strength with exceptional color stabiUty and resistance to aging (201,202). AcryUcs also find use in numerous types of constmction adhesive formulations and as film-to-film laminating adhesives (qv). 

Sihcone products dominate the pressure-sensitive adhesive release paper market, but other materials such as Quilon (E.I. du Pont de Nemours Co., Inc.), a Werner-type chromium complex, stearato chromic chloride [12768-56-8] are also used. Various base papers are used, including polyethylene-coated kraft as well as polymer substrates such as polyethylene or polyester film. Sihcone coatings that cross-link to form a film and also bond to the cellulose are used in various forms, such as solvent and solventless dispersions and emulsions. Technical requirements for the coated papers include good release, no contamination of the adhesive being protected, no blocking in roUs, good solvent holdout with respect to adhesives appHed from solvent, and good thermal and dimensional stabiUty (see Silicon COMPOUNDS, silicones). 

NR adhesives can be divided in two types wet bonding and dry bonding. Wet bonding adhesives are applied on substrates in a fluid state, the bond being formed by drying. The dry bonding NR adhesives are pressure-sensitive adhesives because the bond is created under pressure. 

The adhesives employed for in-line adhesive application are generally of two types (1) flexible, but non-pressure-sensitive adhesives based on blends of saturated stryenic block copolymers and wax and (2) pressure sensitives based... 

NR, styrene-butadiene mbber (SBR), polybutadiene rubber, nitrile mbber, acrylic copolymer, ethylene-vinyl acetate (EVA) copolymer, and A-B-A type block copolymer with conjugated dienes have been used to prepare pressure-sensitive adhesives by EB radiation [116-126]. It is not necessary to heat up the sample to join the elastomeric joints. This has only been possible due to cross-linking procedure by EB irradiation [127]. Polyfunctional acrylates, tackifier resin, and other additives have also been used to improve adhesive properties. Sasaki et al. [128] have studied the EB radiation-curable pressure-sensitive adhesives from dimer acid-based polyester urethane diacrylate with various methacrylate monomers. Acrylamide has been polymerized in the intercalation space of montmorillonite using an EB. The polymerization condition has been studied using a statistical method. The product shows a good water adsorption and retention capacity [129]. 

Pressure-sensitive adhesives Pressure-sensitive adhesions are actually viscous polymer melts at room temperature. The polymers must be applied at temperatures above their Tg to permit rapid flow. The adhesive is made to flow by application of pressure. When the pressure is removed, the viscosity of the polymer is sufficient to hold and adhere to the surface. Many tapes are of this type where the back is smooth and coated with a nonpolar coating so as not to bond with the sticky surface. The two adhering surfaces can be separated, but only with some difficulty. 

UV curable pressure-sensitive adhesives (PSAs) are based on two types of UV curable maferials ... 

The main property that distinguishes a pressure-sensitive adhesive from other types of adhesives is that it exhibits a permanent and controlled tack. This tackiness is what causes the adhesive to adhere instantly when it is pressed against a substrate. After it adheres, the PSA should exhibit tack, peel, and shear properties, which are reproducible within... 

Film Adhesive. A further type which is of importance commercially is the film adhesive which exists usually as pre-formed shapes on suitable substrate materials (often, siliconized release paper). When being applied, such adhesives are activated by heat or pressure and so converted into a semi-fluid condition, when they can wet the surface to be bonded. The pressure-sensitive adhesives are an example of this type—the application of finger pressure alone being sufficient to form the bond. 

Prior to this discovery, in 1954 Silberberg and Kuhn (62) were first to study the polymer-in-polymer emulsion containing ethylcellulose and polystyrene in a nonaqueous solvent, benzene. The mechanisms of polymer emulsification, demixing, and phase reversal were studied. Wetzel and Hocks discovery would then equate the pressure-sensitive adhesive to a polymer-polymer emulsion instead of a polymer-polymer suspension. Since the interface is liquid-liquid, the adhesion then becomes one type of R-R adhesion (35, 36). According to our previous discussion, diffusion is not operative unless both resin and rubber have an identical solubility parameter. The major interfacial interaction is physical adsorption, which, in turn, determines adhesion. Our previous work on the wettability of elastomers (37, 38) can help predict adhesion results. Detailed studies on the function of tackifiers have been made by Wetzel and Alexander (69), and by Hock (20, 21), and therefore the subject requires no further elaboration. 

Filled Graft Rubber as the Disperse Phase. Rubber-modified polystyrene is generally obtained by polymerization grafting of a rubber in the presence of styrene monomer. The polymerization is carried out totally or partially in mass with the aid of shearing agitation, as patented by Amos et al. (1). The study on the initial stage of this type of polymerization was first published by Bender (5), and phase inversion similar to that discovered for the two-phase pressure-sensitive adhesives was observed. The mechanism of particle formation has also been reviewed (47). 

There are two main types of coldseal adhesive and these are based on natural latex or synthetic polymers. They differ from pressure-sensitive adhesives in that they stick only to themselves. They are applied to form dry but gummy adhesive layers on flexible plastic films or paper and can be subsequently sealed together by pressure alone to form wrappers for food items and especially for confectionery. 

In terms of the system design of TDS, there are three types of system constructions reservoir type, matrix type, and drug-in-adhesive type. In reservoir type and matrix type, pressure-sensitive adhesive (PSA) is only expected to keep the system on the skin. Hence, the necessary conditions for adhesives are almost the same as those of bandages, namely, well skin adhesiveness and low skin toxicity whereas in drug-in-adhesive type, the drug is incorporated into the adhesive so that the interaction between drugs and the PSA is more critical, as discussed later. 

Batteries are typically produced with deep drawn metal cans on which a pressure sensitive adhesive label is applied for product identification, branding and safety information. Customers began complaining of batteries becoming jammed in various types of equipment. Devices returned to the manufacturer showed that the pressure sensitive labels had peeled back, resulting in adhesion between the overturned label and the device. Further examination of batteries on store shelves for more than a year also indicated peeling labels in a low frequency of batteries. These labels consisted of laminates of paper and polyester. The labels are normally flat and stiff and when applied over a battery, the labels will return to the flat condition if the adhesive fails. This results in peel-back at the edges of the label. 

Type of adhesive Adhesives based on different adhesive raw materials with special processing properties (e.g., hot-melt adhesives, pressure-sensitive adhesives), different purposes of use (e.g., wallpaper paste, wood glue), processing temperatures (e.g., cold glue, heat-curing adhesives), availabilities (e.g., adhesive films, solvent-based adhesive). 

A number of reviews have appeared on the function of different types of photoinitiators and their future development and applications. A number of articles have targeted interest in photosensitive polyelectrolyte diazo systems," pressure sensitive adhesives and coatings, bonding of epoxy resins, electrodeposition materials, heat transfer in thick films, ring opening metathesis and curing for microelectronics. ... 

Kokubo, T., K. Sugibayashi, and Y. Morimoto. 1991. Diffusion of drug in acrylic-type pressure-sensitive adhesive matrices. I. Influence of physical property of the matrices on the drug diffusion. /. Contr. Rel. 17 69-78. 

Toddywala, R. D., K. Ulman, P. Walters, and Y. W. Chien. 1991. Effect of physicochemical properties of adhesive on the release, skin permeation and adhesiveness of adhesive-type transdermal drug delivery systems containing silicone-based pressure-sensitive adhesives. Int. J. Pharmaceut. 76 77-89. 

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