Powder, high density

Density. The density of the drilling fluid is adjusted using powdered high density soHds or dissolved salts to provide a hydrostatic pressure against exposed formations in excess of the pressure of the formation fluids. In addition, the hydrostatic pressure of the mud column prevents coUapse of weak formations into the borehole. Fluid densities may range from that of air to >2500 kg/m (20.8 Ib/gal). Most drilling fluids have densities >1000 kg/m (8.33 lb/gal), the density of water. The hydrostatic pressure imposed by a column of drilling fluid is expressed as follows ... 

CHAPTER 8 In direct fluorination of powdered high-density polyethylene with the gas, diluted with helium... 

In direct fluorination of powdered high-density polyethylene with the gas, diluted with helium or nitrogen, the accompanying exotherm causes partial fusion. In addition, there is some destruction of the crystalline regions [137]. On the other hand, fluorination of single crystals of polyethylene can result in fluorine atoms being placed on the carbon skeleton without disruption of the crystal structure. The extent of cross-linking, however, is hard to assess [138]. The reaction has all the characteristics of free-radical mechanism [139] ... 

Fractional precipitation of crystalline polymers must be conducted above the melting point of the crystals to eliminate the effects of crystallinity on solubility. In addition, with polypropylene branching and tacticity differences can cause a reversal in the order of fractionation. In most cases polyolefins are fractionated from dilute solutions in poor solvents to eliminate these effects. However, the direct extraction of powdered high density polyethylene with solvents has been reported [94]. 

Miscellaneous Natural Abrasives. Powdered feldspar [68476-25-5] is used as a mild abrasive in cleansing powders, and clays are sometimes used in polishing powders. StauroHte [12182-56-8] is a complex hydrated aluminosiHcate of kon, of high density (3.74—3.83 g/mL) and a hardness of 7 to 8 on Mohs scale. It is primarily used as a sandblasting grit, but siHcosis hazards had cut production in 1987 about 25% compared to that... 

Liquid-Ph se Sintering. Sintering ia the Hquid state refers to the sintering of a powder mixture of two or more components, of which at least one has a melting temperature lower than the others. The sintering temperature is then selected ia such a manner that a Hquid phase is formed ia which the soHd powder particles of the other components rearrange. A high density powder compact is the result. 

Both zirconium hydride and zirconium metal powders compact to fairly high densities at conventional pressures. During sintering the zirconium hydride decomposes and at the temperature of decomposition, zirconium particles start to bond. Sintered zirconium is ductile and can be worked without difficulty. Pure zirconium is seldom used in reactor engineering, but the powder is used in conjunction with uranium powder to form uranium—zirconium aUoys by soHd-state diffusion. These aUoys are important in reactor design because they change less under irradiation and are more resistant to corrosion. 

High density tungsten alloy machine chips are recovered by oxidation at about 850°C, foUowed by reduction in hydrogen at 700—900°C. Typically, the resultant powders are about 3-p.m grain size and resinter readily. There can be some pickup of refractory materials used in furnace constmction, which must be controUed. This process is important commercially. Eor materials that may be contaminated with other metals or impurities, the preferred recovery process is the wet chemical conversion process used for recovery of tungsten from ores and process wastes. Materials can always be considered for use as additions in alloy steel melting. 

Average Particle Size A powder has many average sizes hence it is essential that they be well specified. The median is the 50 percent size half the distribution is coarser and half finer. The mode is a high-density region if there is more than one peak in the frequency cui ve, the distribution is said to be multimodal. The mean is the center of gravity of the distribution. The center of gravity of a mass (volume) distribution is defined by. Xyw = X XdV/X dV where dV = X dN dV is the volume of dN particles of size X This is defined as the volume-moment mean diameter and differs from the mean for a number or surface distribution. 

Although the above applications consume over 90% of the polyethylene produced there are a number of other important end-uses. Filament for ropes, fishing nets and fabrics are an important outlet for high-density polyethylene powdered polymers are used for dip coating, flame spraying, rotational moulding and other outlets, whilst fabricated sheet is important in chemical plant. 

Prior studies of dynamic compaction of powders to achieve high density compacts have devoted effort to development of models of localization of mechanical energy on the surfaces of powders to explain observations of local melting. Unfortunately, the models that have been developed are too narrowly focused and do not realistically consider basic materials response aspects of shock-compression processes. The models fail to account for the substantial observations that show results demonstrating that melting is not the universal, dominant process. 

Shock-synthesis experiments were carried out over a range of peak shock pressures and a range of mean-bulk temperatures. The shock conditions are summarized in Fig. 8.1, in which a marker is indicated at each pressure-temperature pair at which an experiment has been conducted with the Sandia shock-recovery system. In each case the driving explosive is indicated, as the initial incident pressure depends upon explosive. It should be observed that pressures were varied from 7.5 to 27 GPa with the use of different fixtures and different driving explosives. Mean-bulk temperatures were varied from 50 to 700 °C with the use of powder compact densities of from 35% to 65% of solid density. In furnace-synthesis experiments, reaction is incipient at about 550 °C. The melt temperatures of zinc oxide and hematite are >1800 and 1.565 °C, respectively. Under high pressure conditions, it is expected that the melt temperatures will substantially Increase. Thus, the shock conditions are not expected to result in reactant melting phenomena, but overlap the furnace synthesis conditions. 

Recently, sheets of high density polyethylene extruded on to the pipe surface over an adhesive have become available and the use of polyethylene or epoxy powders sintered on to the steel surface is becoming more frequent. 

The introduction of concentrated laundry detergent powders in Japan during 1986-1987 produced a substantial increase in the consumption of LAB in the subsequent 3-4 years as the market changed from low-density, spray-dried powders to the concentrated (compact) products. In these products, which may contain up to 40% surfactant, the cost/performance advantages of LAS are of significance. In addition, LAB sulfonic acid is well suited for the production of high-active, high-density (about 1.0 g/cm3) laundry powders by routes other... 

Gas phase olefin polymerizations are becoming important as manufacturing processes for high density polyethylene (HOPE) and polypropylene (PP). An understanding of the kinetics of these gas-powder polymerization reactions using a highly active TiCi s catalyst is vital to the careful operation of these processes. Well-proven models for both the hexane slurry process and the bulk process have been published. This article describes an extension of these models to gas phase polymerization in semibatch and continuous backmix reactors. 

Sol-gel techiuques are of interest because they can be used to prepare powders with a narrow distribution of particle size. These small particles undergo sintering to high density at temperatures lower by several hundred degrees centigrade than those used in conventional ceramic processing. Sol-gel processes may also be used to prepare novel glasses and ceramics such as... 

Higuchi et al. [98] postulated that an additional increase in surface area occurs after this point and that this effect may cause lamination of the tablet due to extensive rebound at decompression. In other words, at the tablet punch powder interface, there may be zones of high density during compression, but upon decompression these zones have elastic rebound and are pulled apart from the rest of the tablet that did not contain this high density. 

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