Plasticizers, description

A range of complex, elastic-plastic behaviors are observed experimentally they are perhaps the most widely encountered and most typical of shock behaviors, but they are perhaps the least understood of the materials responses. Unfortunately, nonspecialists seldom consider realistic elastic-plastic descriptions of shock processes. This section summarizes the very large body of information available in this area. The metallurgical mud is most viscous in this area. 

Eye bums are a process that develops during a chemical or thermal exposure that is of exceeding mass, contact time, chemical reactivity, and temperature until the exhaustion of the protective mechanisms of the eye. The most plastic description of this process can be given in images that are obtained by optical coherence tomography [5]. 

This section includes the following mechanism of the specific actions of plasticizers on the PU, the analysis of material properties affected by plasticizers, description of chemically inert liqttids applied as PU plasticizers, and discussion of selection principles of plasticizers for the segmerrled polyrrrethanes. 

A suspension of 0.40 mol of sodium amide in 300 ml of liquid ammonia was prepared as described in Chapter II, Exp. 11. To the suspension was added with swirling a mixture of 0.25 mol of CHgCeC-S-Ph (see Chapter IV, Exp. 14) and 40 ml of THE in about 2 min (note 1). Swirling was continued after the addition. Three minutes later (note 1) the stopper with glass tube was placed on the flask. The brown solution was forced through the glass tube and the plastic tube, connected to it under 400 g of finely crushed ice, which was contained in a 3-1 conical flask (see Chapter I, Fig. 3, and accompanying description of this operation). The flask was placed for... 

Plasticizer Range Alcohols. Commercial products from the family of 6—11 carbon alcohols that make up the plasticizer range are available both as commercially pure single carbon chain materials and as complex isomeric mixtures. Commercial descriptions of plasticizer range alcohols are rather confusing, but in general a commercially pure material is called "-anol," and the mixtures are called "-yl alcohol" or "iso...yl alcohol." For example, 2-ethyIhexanol [104-76-7] and 4-methyl-2-pentanol [108-11-2] are single materials whereas isooctyl alcohol [68526-83-0] is a complex mixture of branched hexanols and heptanols. Another commercial product contains linear alcohols of mixed 6-, 8-, and 10-carbon chains. 

The General Tests and Assays. This section of the USP gives methods for tests that are general in nature and apply to a number of the substances. Procedures are iacluded for such tests as heavy metals, melting point, chloride, sulfate, sterility, bacterial endotoxins, and pyrogens. Also iacluded are descriptions of various analytical techniques, such as spectrophotometry, chromatography, and nmr, and descriptions of tests to be used on glass or plastic containers, mbber closures, etc. 

Polymer Composition. The piopeities of foamed plastics aie influenced both by the foam stmctuie and, to a gieatei extent, by the piopeities of the parent polymer. The polymer phase description must include the additives present in that phase as well. The condition or state of the polymer phase (orientation, crystallinity, previous thermal history), as well as its chemical composition, determines the properties of that phase. The polymer state and cell geometry are intimately related because they are determined by common forces exerted during the expansion and stabilization of the foam. 

Plaspec Material Selection Database Data Resources, Inc. Dialog, STN detailed engineering and design data, chemical descriptions, and trade names for over 11,500 grades of plastics materials... 

W. Kampfer, and E. Stieg, Jr., Color Eng. 44, 35—40, 44 (1967). A description of the manufacture, properties, and uses of titanium dioxide as a colorant for paint, food, plastics, and other materials. 

Personnel who must work in areas in which tritium contamination exceeds permitted levels are safeguarded by protective clothing, such as ventilated plastic suits. Detailed descriptions of laboratories suitable for manipulation of tritium can be found in Reference 9. 

The choice (5.77) for the evolution equation for the plastic strain sets the evolution equations for the internal state variables (5.78) into the form (5.11) required for continuity. The consistency condition in the stress space description may be obtained by differentiating (5.73), or directly by expanding (5.29)... 

Casey, J. and Naghdi, P.M., On the Relationship between the Eulerian and Lagrangian Descriptions of Finite Rigid Plasticity, Arch. Rational Mech. Math. 102, 351-375 (1988). 

Nitrile rubbers are sometimes used in conjunction with plastics. Blends with PVC provide an early example of polyblends. (In fact this word has been used by one company as a trade description for such blends for over 25 years.)... 

Technology Descriptions The use of thermoplastic solidification systems in radioactive waste disposal has led to the development of waste containment systems that can be adapted to industrial waste. In processing radioactive waste with bitumen or other thermoplastic material (such as paraffin or polyethylene), the waste is dried, heated and dispersed through a heated, plastic matrix. The mixture is then cooled to solidify the mass. 

Many thermoplastics are now accepted as engineering materials and some are distinguished by the loose description engineering plastics. The term probably originated as a classiflcation distinguishing those that could be substituted satisfactorily for metals such as aluminium in small devices and structures from those with inadequate mechanical properties. This demarcation is clearly artificial because the properties on which it is based are very sensitive to the ambient temperature, so that a thermoplastic might be a satisfactory substitute for a metal at a particular temperature and an unsatisfactory substitute at a different one. 

Flammability. The fire hazard associated with plastics has always been difficult to assess and numerous tests have been devised which attempt to grade materials as regards flammability by standard small scale methods under controlled but necessarily artificial conditions. Descriptions of plastics as selfextinguishing, slow burning, fire retardant etc. have been employed to describe their behaviour under such standard test conditions, but could never be regarded as predictions of the performance of the material in real fire situations, the nature and scale of which can vary so much. 

To develop a terse, broad description of mechanical, physical, and chemical processes in solids, this book is divided into five parts. Part I contains one chapter with introductory material. Part II summarizes aspects of mechanical responses of shock-compressed solids and contains one chapter on materials descriptions and one on experimental procedures. Part III describes certain physical properties of shock-compressed solids with one chapter on such effects under elastic compression and one chapter on effects under elastic-plastic conditions. Part IV describes work on chemical processes in shock-compressed solids and contains three chapters. Finally, Part V summarizes and brings together a description of shock-compressed solids. The information contained in Part II is available in much better detail in other reliable sources. The information in Parts III and IV is perhaps presented best in this book. 

It is instructive to describe elastic-plastic responses in terms of idealized behaviors. Generally, elastic-deformation models describe the solid as either linearly or nonlinearly elastic. The plastic deformation material models describe rate-independent behaviors in terms of either ideal plasticity, strainhardening plasticity, strain-softening plasticity, or as stress-history dependent, e.g. the Bauschinger effect [64J01, 91S01]. Rate-dependent descriptions are more physically realistic and are the basis for viscoplastic models. The degree of flexibility afforded elastic-plastic model development has typically led to descriptions of materials response that contain more adjustable parameters than can be independently verified. 

This statement represents an apt, terse description of the elastic-plastic shock-deformation process within the catastrophic shock paradigm. 

Detailed strength studies made by reloading and release of metals from high pressure provide more evidence that ideal elastic-plastic behaviors are not descriptive. An example of such a study by Lipkin and Asay [77L02] on an aluminum alloy is shown in Fig. 2.11. In this case, there is considerable... 

With nanosecond time resolution, sensitive, accurate detectors, studies of these release waves have proven to be particularly revealing. First-order descriptions of release properties were obtained with rudimentary instrumentation from the earliest studies [65A01] it has required the most sophisticated modern instrumentation to provide the necessary detail to obtain a clear picture of the events. Characteristically different profiles are encountered in the strong-shock, elastic, and elastic-plastic regimes. 

Release waves for the elastic-plastic regime are dominated by the strength effect and the viscoplastic deformations. Here again, quantitative study of the release waves requires the best of measurement capability. The work of Asay et al. on release of aluminum as well as reloading, shown in Fig. 2.11, demonstrates the power of the technique. Early work by Curran [63D03] shows that limited time-resolution detectors can give a first-order description of the existence of elastic-plastic behavior on release. 

Among the newer probes now being developed, spectroscopic observations of crystals in the elastic-plastic regime hold promise for limited development of atomic level physical descriptions of local defects [91S02]. It is yet to be determined how generally this probe can be applied to solids. The electrochemical probe appears to have considerable potential to describe shock-compressed matter from a radically different perspective. 

Equipment Description PIPING SYSTEMS -RIGID PLASTIC-STRAIGHT SECTIONS... 

---