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Nomenclature substituted

Note. In carbohydrate nomenclature, substitution at a heteroatom is normally indicated by citing the locant of the attached carbon atom, followed by a hyphen, and then the italicized heteroatom element symbol, e.g. 2-0-methyl, 5-N-acetyl. Substituents on the same kind of heteroatom are grouped (e.g. 2,3,4-tri-0-methy 1), and substituents of the same kind are cited in alphabetical order of heteroatoms (e.g. 5-N-acetyl-4,8,9-tri-0-acetyl). The alternative format with superscript numerical locants (e.g, N5,(/,(), ( -tetraacetyl), used in some other areas of natural product chemistry, is unusual in carbohydrate names. [Pg.117]

In the common system of nomenclature, substituted aldehydes are named as derivatives of the straight-chain parent compoimd (see Table 14.1). Greek letters... [Pg.395]

In contrast, epoxides, ozonides, and certain halogen derivatives are characterized by anionized name forms of the added atoms (or groups of atoms) placed behind the stem terms. It should be noted, though, that retention of this method is not recommended when other types of nomenclature (substitutive or heterocycle nomenclature) permit unambiguous simpler names. [Pg.86]

The lUPAC rules permit alkyl halides to be named m two different ways called func twnal class nomenclature and substitutive nomenclature In functional class nomencla ture the alkyl group and the halide (fluoride chloride bromide or iodide) are desig nated as separate words The alkyl group is named on the basis of its longest continuous chain beginning at the carbon to which the halogen is attached... [Pg.144]

Substitutive nomenclature of alkyl halides treats the halogen as a halo—(fluoro chloro bromo or lodo ) substituent on an alkane chain The carbon chain is numbered m the direction that gives the substituted carbon the lower number... [Pg.144]

Name each of the following compounds according to substitutive lUPAC nomenclature... [Pg.182]

Substitutive lUPAC nomenclature names epoxides as epoxy derivatives of alkanes According to this system ethylene oxide becomes epoxyethane and propylene oxide becomes 1 2 epoxypropane The prefix epoxy always immediately precedes the alkane ending it is not listed m alphabetical order like other substituents... [Pg.260]

Diols are almost always given substitutive lUPAC names As the name of the prod uct m the example indicates the substitutive nomenclature of diols is similar to that of alcohols The suffix dwl replaces ol and two locants one for each hydroxyl group are required Note that the final e of the parent alkane name is retained when the suffix begins with a consonant ( diol) but dropped when the suffix begins with a vowel ( ol)... [Pg.634]

Ethers are named m substitutive lUPAC nomenclature as alkoxy derivatives of alkanes Functional class lUPAC names of ethers are derived by listing the two alkyl groups m the general structure ROR m alphabetical order as separate words and then adding the word ether at the end When both alkyl groups are the same the prefix di precedes the name of the alkyl group... [Pg.665]

Section 16 1 Ethers are compounds that contain a C—O—C linkage In substitutive lUPAC nomenclature they are named as al/coxy derivatives of alkanes In functional class lUPAC nomenclature we name each alkyl group as a separate word (m alphabetical order) followed by the word ether... [Pg.691]

Although substitutive names of the type just described are preferred the lUPAC rules also permit ketones to be named by functional class nomenclature The groups attached to the carbonyl group are named as separate words followed by the word ketone The groups are listed alphabetically... [Pg.705]

In substitutive lUPAC nomen clature cyanohydrins are named as hydroxy deriva tives of nitriles Because ni trile nomenclature will not be discussed until Section 20 1 we will refer to cyanohydrins as derivatives of the parent aldehyde or ketone as shown in the ex amples This conforms to the practice of most chemists... [Pg.719]

Ketones may also be named using functional class lUPAC nomenclature by citing the two groups attached to the carbonyl m alphabetical order followed by the word ketone Thus 3 methyl 2 butanone (substitutive) becomes isopropyl methyl ketone (functional class)... [Pg.741]

Substitutive nomenclature (Section 4 2) Type of lUPAC nomenclature in which a substance is identified by a name ending in a suffix charactenstic of the type of compound 2 Methylbutanol 3 pentanone and 2 phenylpropanoic acid are examples of substitutive names... [Pg.1294]

There are several types of nomenclature systems that are recognized. Which type to use is sometimes obvious from the nature of the compound. Substitutive nomenclature, in general, is preferred because of its broad applicability, but radicofunctional, additive, and replacement nomenclature systems are convenient in certain situations. [Pg.17]

Substitutive Nomenclature. The first step is to determine the kind of characteristic (functional) group for use as the principal group of the parent compound. A characteristic group is a recognized combination of atoms that confers characteristic chemical properties on the molecule in which it occurs. Carbon-to-carbon unsaturation and heteroatoms in rings are considered nonfunctional for nomenclature purposes. [Pg.17]

Substitution means the replacement of one or more hydrogen atoms in a given compound by some other kind of atom or group of atoms, functional or nonfunctional. In substitutive nomenclature, each substituent is cited as either a prefix or a suffix to the name of the parent (or substituting radical) to which it is attached the latter is denoted the parent compound (or parent group if a radical). [Pg.17]

In Table 1.8 are listed characteristic groups that are cited only as prefixes (never as suffixes) in substitutive nomenclature. The order of listing has no significance for nomenclature purposes. [Pg.17]

Systematic names formed by applying the principles of substitutive nomenclature are single words except for compounds named as acids. First one selects the parent compound, and thus the suffix, from the characteristic group listed earliest in Table 1.7. All remaining functional groups are handled as prefixes that precede, in alphabetical order, the parent name. Two examples may be helpful ... [Pg.17]

TABLE 1.7 Characteristic Groups for Substitutive Nomenclature Continued)... [Pg.19]

TABLE 1.8 Characteristic Groups Cited Only as Prefixes in Substitutive Nomenclature... [Pg.19]

Characteristic groups will now be treated briefly in order to expand the terse outline of substitutive nomenclature presented in Table 1.7. Alternative nomenclature will be indicated whenever desirable. [Pg.23]

Organic ring systems are named by replacement nomenclature. Three- to ten-membered mono-cyclic ring systems containing uncharged boron atoms may be named by the specialist nomenclature for heterocyclic systems. Organic derivatives are named as outlined for substitutive nomenclature. The complexity of boron nomenclature precludes additional details the text by Rigaudy and Klesney should be consulted. [Pg.29]

Ethers (R —O—R ). In substitutive nomenclature, one of the possible radicals, R—O—, is stated as the prefix to the parent compound that is senior from among R or R. Examples are methoxyethane for CH3OCH2CH3 and butoxyethanol for C4Hc,0CH2CH20H. [Pg.31]

Partial ethers of polyhydroxy compounds may be named (1) by substitutive nomenclature or (2) by stating the name of the polyhydroxy compound followed by the name of the etherifying radical(s) followed by the word ether. For example. [Pg.31]


See other pages where Nomenclature substituted is mentioned: [Pg.82]    [Pg.137]    [Pg.415]    [Pg.452]    [Pg.82]    [Pg.137]    [Pg.415]    [Pg.452]    [Pg.178]    [Pg.220]    [Pg.432]    [Pg.433]    [Pg.648]    [Pg.666]    [Pg.1]    [Pg.18]    [Pg.22]    [Pg.23]   
See also in sourсe #XX -- [ Pg.5 ]




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Characteristic groups for substitutive nomenclature

Electrophilic aromatic substitution benzene derivatives, nomenclature

Functional compounds substitutive nomenclature

Groups Cited Only as Prefixes in Substitutive Nomenclature

Groups for Substitutive Nomenclature

Ligands substitutive-type nomenclature

Name construction substitutive nomenclature

Nomenclature parent-substitutive

Nomenclature phenyl substituted

Nomenclature substitution mechanisms

Nomenclature types for substituted

Nomenclature types for substituted systems

Nucleophilic substitution—continued nomenclature for, 394 (footnote

Organic compounds substitutive-type nomenclature

PARENT HYDRIDE NAMES AND SUBSTITUTIVE NOMENCLATURE

Parent hydride-based nomenclature substitution

Radicals substitutive-type nomenclature

Skeletal replacement nomenclature substitution

Substituent groups Substitutive nomenclature

Substituted Derivatives of Benzene and Their Nomenclature

Substitution IUPAC nomenclature

Substitutive nomenclature

Substitutive nomenclature

Substitutive nomenclature INDEX

Substitutive-type nomenclature

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