Nitrilo triacetate

Organic compound (such as ethylenediamine-tetraacetic acid (EDTA) or nitrilo-triacetic acid (NTA) having the ability to take metal ions in water and produce soluble, coordinate-bond complexes. Chelants are commonly used in BW deposit control treatments and various cleaning formulations. 

Umemura, T., Sai, K., Takagi, A., Hasegawa, R. and Kurokawa, Y. (1991). The effects of exogenous glutathione and cysteine on oxidative stress induced by ferric nitrilo-triacetate. Cancer Lett. 58, 49-56. 

The detergent industry hoped that this story would be repeated. It spent a lot of money on research and found a partial substitute for the phosphate, sodium nitrilo-triacetate (NTA). The chemical industry began to build plants for its production. Monsanto, which had built a plant to produce 75,000,000 lb / yr (35,000,000 kg / yr), planned to double that plant s capacity and to add another one to produce... 

An ionophoretic method was described by Tewari [41] for the study of equilibria in a mixed ligand complex system in solution. This method is based on the movement of a spot of metal ion in an electric field with the complexants added in the background electrolyte at pH 8.5. The concentration of the primary ligand (nitrilo-triacetate) was kept constant, while that of the secondary ligand (penicillamine) was varied. The stability constants of the metal nitrilotriacetate-penicillamine complexes have been found to be 6.26 0.09 and 6.68 0.13 (log K values) for the Al(III) and Th(IV) complexes, respectively, at 35 °C and an ionic strength of 0.1 M. 

With this example we have shown how the mathematical formulations of the processes which are part of the model can be combined into one single linear differential equation. Illustrative Example 21.1 deals with another example, the dynamics of nitrilo-triacetic acid (NTA) in Greifensee. 

Chromatographic System Set up the system with reference to High-Performance Liquid Chromatography under Chromatography, Appendix IIA. The HPLC chromatograph has a 254-nm detector and a 4.6-mm x 15-cm column that contains 5- to 10-mm porous microparticles of silica bonded to octylsilane (Zorbax 8, or equivalent). The flow rate is about 2 mL/min. Chromatograph three replicate injections of the Standard Preparation, and record the peak responses as directed under Procedure. The relative standard deviation is not more than 2.0%, and the resolution factor between nitrilo-triacetic acid and Disodium EDTA is not less than 4.0. 

Rare earths NTA (nitrilo-triacetic acid) Murexide [118]... 

Nitrilo triacetic acid (NTA) also represents a partial replacement of phosphate. However, the US Surgeon General issued a report stating that NTA caused birth defects in rats. The use of NTA was immediately phased out in the United States [4]. 

Chelating agents. The role of the chelating agents is to block the polyvalent ions and to make them undetectable and ineffective. Sodium salts of ethylene diamine tetraacetic acid (EDTA) and of nitrilo triacetic acid (NTA) are members of the group of chelating agents and their use has increased in the last few years. 

Abbreviations ap, antipyrine TBP, tri-(n-butyl)phosphate DMA, NyN-dimethylacetamide jjhen, 1,10-phenanthroUne EDTA, ethylenediamine-i T,iV,iV, iV -tetraacetate on, 8-quinolinolate diket, 1,3-diketonate B, organic amine NTA, nitrilo-triacetate HEDTA, AT -(2-hydroxyethyl)ethylenediamine-iV,iV,iV -triacetate IMDA, iminodiacetate. 

Fig. 14.12 Formation constants at 25 °C for 1 1 chelates of ions with various aminepoly-carboxylate ions (ida, iminodiacetate nta, nitrilo-triacetate , /V-hydroxy-ethylethylenediaminetri-acetate edta, ethylene-diaminetetraacetate cdta, irons-1.2-cyclohexane-diaminetetraacetate dtpa. dicthylenetriaminepenta-acetate). [From Moeller, T. J. Chem. Educ. 1970, 47, 417-430. Reproduced with permission.]...

Derivatives of iminodiacetic acid, NH(CHjCOOH), are most successful sequestering agents (Summersgill, loc. cit.). Two compounds of this class have had commercial success, namely, nitrilo triacetic acid, N(CH,.C00H)3, and ethylenediaminetetra-acetic acid, (COOH.CH,)jN.CH2.CH,.N(CH,.COOH)j. Ethylenediaminetetra-acetic acid, often abbreviated to E.D.T.A., has virtually displaced nitrilo triacetic acid because the complexes which it makes with metallic ions are more stable. The nature of the complex molecules are shown below ... 

Imanari et al. has reported a spectrophotometric detection of many inorganic anions using a post-column reactor [42]. A stream of ferric perchlorate, which is essentially colorless, is mixed with the column effluent. The ferric perchlorate is colorless because perchlorate is a poor complexing anion, but most anions will complex the iron and form colored species that can be detected at 330-340 nm (Table 4.3). A similar detection method works for ions such as orthophosphate, pyrophosphate, nitrilo-triacetic acid (NTA), and ethylenediaminetetraacetic acid (EDTA) [46]. 

A very effective STPP replacement not used in LADD compositions is nitrilo-triacetic acid (NTA), commonly manufactured as the monohydrate. Its stmcture... 

Fig. 7 Molecular structures of selected active constituents of personal care products, washing agents or polymers 1 - N,N-Diethyltoluamide, DEET, 2 - Triclosan, 3 - Nitrilo triacetate, NTA, 4 - Ethylenediaminetetraacetic acid, EDTA, 5 - Galaxolide, 6 - Tonalide, 7 - Phthalates, 8 - Phosphates...

Neirinckx RD, Canning LR, Piper IM, Nowotnik DP, Pickett RD, Holmes RA, Volkert WA, Forster AM, Weisner PS, Mariott JA, Chaplin SB (1987) Technetium-99m d,l-HM-PAO a new radiopharmaceutical for SPECT imaging of regional cerebral blood perfusion. J Nucl Med 28 191-202 Noll B, Seifert S, Muenze R (1980) New Tc(IV) compounds with nitrilo-triacetic acid. Radiochem Radioanal Lett 43 215-218... 

It may be noted finally that 7Li (92.7%) gives nuclear magnetic resonance signals comparable to those given by so that complex formation in aqueous solutions can be studied in this way it was shown24 that nitrilo-triacetic acid, N(CH2COOH)3 (NTA), probably forms a complex ion, [Li(NTA)2]5, in solution. 

Nitrilo triacetic acid (NTA), ethylene diamine tetraacetic acid (EDTA), ethylene diamine (C2H8N2), and citric acid (2-hydroxypropane-l,2,3-tricarboxylic acid) are the most frequently used organic additives. A clear aqueous impregnation solution can be prepared by ... 

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