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Lithium salt

Thus o-hydroxyphenyl-llthium cannot be obtained from o-bromophenol and lithium but, under proper conditions, o-bromophenol reacts with n-butyl-lithium to give a good yield of the lithium salt of o-hydroxyphenyl-hthium. An interesting application is to the preparation from m-bromochlorobenzene and M-butyl-lithlum of w-chlorobenzoic acid—an expensive chemical ... [Pg.929]

Some di-p-tolyl ketone is produced as a by-product, presumably by Interaction of the lithium salt of the carboxylic acid with the aryl lithium ... [Pg.930]

Stereoselectivities of 99% are also obtained by Mukaiyama type aldol reactions (cf. p. 58) of the titanium enolate of Masamune s chired a-silyloxy ketone with aldehydes. An excess of titanium reagent (s 2 mol) must be used to prevent interference by the lithium salt formed, when the titanium enolate is generated via the lithium enolate (C. Siegel, 1989). The mechanism and the stereochemistry are the same as with the boron enolate. [Pg.62]

The second molar equivalent of the alkyllithium adds to the alkylcopper to give a neg atively charged dialkyl substituted derivative of copper(I) called a dialkylcuprate It is formed as its lithium salt a lithium dialkylcuprate... [Pg.603]

Ionic polymers may exist as undissociated, unsolvated ion pairs undissociated ion pairs solvated to some extent solvated ions dissociated to some extent or some combination of these. The propagation rate constant kp and the dissociation equilibrium constant K of the lithium salt of anionic... [Pg.420]

Manufacture. Lithium fluoride is manufactured by the reaction of lithium carbonate or lithium hydroxide with dilute hydrofluoric acid. If the lithium carbonate is converted to the soluble bicarbonate, insolubles can be removed by filtration and a purer lithium fluoride can be made on addition of hydrofluoric acid (12). High purity material can also be made from other soluble lithium salts such as the chloride or nitrate with hydrofluoric acid or ammonium bifluoride (13). [Pg.206]

CH2(CF2CH2 2,4, been synthesized by the reaction of PCl and the lithium salt of the respective polyfluoroalkyl alcohols followed by... [Pg.227]

The metallic salts of trifluoromethanesulfonic acid can be prepared by reaction of the acid with the corresponding hydroxide or carbonate or by reaction of sulfonyl fluoride with the corresponding hydroxide. The salts are hydroscopic but can be dehydrated at 100°C under vacuum. The sodium salt has a melting point of 248°C and decomposes at 425°C. The lithium salt of trifluoromethanesulfonic acid [33454-82-9] CF SO Li, commonly called lithium triflate, is used as a battery electrolyte in primary lithium batteries because solutions of it exhibit high electrical conductivity, and because of the compound s low toxicity and excellent chemical stabiUty. It melts at 423°C and decomposes at 430°C. It is quite soluble in polar organic solvents and water. Table 2 shows the electrical conductivities of lithium triflate in comparison with other lithium electrolytes which are much more toxic (24). [Pg.315]

Table 2. Comparative Electrical Conductivity of Lithium Salts... Table 2. Comparative Electrical Conductivity of Lithium Salts...
Several excellent review articles (28—31) cover the chemistry of the acid and its derivatives in great detail. Trifluoromethanesulfonic acid is available from the 3M Co. as Fluorochemical Acid FC-24 the lithium salt is available as Fluorochemical Specialties FC-122, FC-123, and FC-124 (32). [Pg.315]

Lithium borohydride is a more powerful reducing agent than sodium borohydride, but not as powerful as lithium aluminum hydride (Table 6). In contrast to sodium borohydride, the lithium salt, ia general, reduces esters to the corresponding primary alcohol ia refluxing ethers. An equimolar mixture of sodium or potassium borohydride and a lithium haUde can also be used for this purpose (21,22). [Pg.301]

Reaction with Carbon Nucleophiles. Unactivated a2iddines react with the lithium salts of malonates or p-keto esters in the presence of lithium salts to yield 3-substituted pyttohdinones (56—59), where R = alkyl and aryl, and R = alkoxyl, alkyl, and aryl. [Pg.3]

Acrylic acid, polymer with ethylene, lithium salt, (0 11 02 C2H xLi. [Pg.406]

Miscellaneous. Both whiting and hydrated lime are used as diluents and carriers of pesticides, such as lime—sulfur sprays, Bordeaux, calcium arsenate, etc. The most widely used bleach and sterilizer, high test calcium hypochlorite, is made by interacting lime and chlorine (see Bleaching AGENTS). Calcium and magnesium salts, such as dicalcium phosphate, magnesium chloride, lithium salts, etc, are made directly from calcific and dolomitic lime and limestone. [Pg.178]

Lithium is used in metallurgical operations for degassing and impurity removal (see Metallurgy). In copper (qv) refining, lithium metal reacts with hydrogen to form lithium hydride which subsequendy reacts, along with further lithium metal, with cuprous oxide to form copper and lithium hydroxide and lithium oxide. The lithium salts are then removed from the surface of the molten copper. [Pg.224]

Temperature, °C Lithium salt, wt % SoHd-phase formula... [Pg.225]

Lithium hydroxide can be used for preparation of numerous lithium salts. The dominant use is the preparation of lithium stearate [4485-12-5], which is added to lubricating greases in amounts up to about 10% by weight. This salt has very low water solubiHty and extends the acceptable viscosity for the grease to both low and high temperatures (see Lubrication and lubricants). Lithium hydroxide is also used in production of dyes (62) and has been proposed as a source of lithium ion for inhibition of alkaH-aggregate expansive reactivity in concrete (63). [Pg.226]

Poly(ethylene oxide) associates in solution with certain electrolytes (48—52). For example, high molecular weight species of poly(ethylene oxide) readily dissolve in methanol that contains 0.5 wt % KI, although the resin does not remain in methanol solution at room temperature. This salting-in effect has been attributed to ion binding, which prevents coagulation in the nonsolvent. Complexes with electrolytes, in particular lithium salts, have received widespread attention on account of the potential for using these materials in a polymeric battery. The performance of soHd electrolytes based on poly(ethylene oxide) in terms of ion transport and conductivity has been discussed (53—58). The use of complexes of poly(ethylene oxide) in analytical chemistry has also been reviewed (59). [Pg.342]

Refractive Index. The effect of mol wt (1400-4000) on the refractive index (RI) increment of PPG in ben2ene has been measured (167). The RI increments of polyglycols containing aUphatic ether moieties are negative drj/dc (mL/g) = —0.055. A plot of RI vs 1/Af is linear and approaches the value for PO itself (109). The RI, density, and viscosity of PPG—salt complexes, which maybe useful as polymer electrolytes in batteries and fuel cells have been measured (168). The variation of RI with temperature and salt concentration was measured for complexes formed with PPG and some sodium and lithium salts. Generally, the RI decreases with temperature, with the rate of change increasing as the concentration increases. [Pg.354]

Treatment of Manic—Depressive Illness. Siace the 1960s, lithium carbonate [10377-37-4] and other lithium salts have represented the standard treatment of mild-to-moderate manic-depressive disorders (175). It is effective ia about 60—80% of all acute manic episodes within one to three weeks of adrninistration. Lithium ions can reduce the frequency of manic or depressive episodes ia bipolar patients providing a mood-stabilising effect. Patients ate maintained on low, stabilising doses of lithium salts indefinitely as a prophylaxis. However, the therapeutic iadex is low, thus requiring monitoring of semm concentration. Adverse effects iaclude tremor, diarrhea, problems with eyes (adaptation to darkness), hypothyroidism, and cardiac problems (bradycardia—tachycardia syndrome). [Pg.233]

Sulfonic acids are prone to reduction with iodine [7553-56-2] in the presence of triphenylphosphine [603-35-0] to produce the corresponding iodides. This type of reduction is also facile with alkyl sulfonates (16). Aromatic sulfonic acids may also be reduced electrochemicaHy to give the parent arene. However, sulfonic acids, when reduced with iodine and phosphoms [7723-14-0] produce thiols (qv). Amination of sulfonates has also been reported, in which the carbon—sulfur bond is cleaved (17). Ortho-Hthiation of sulfonic acid lithium salts has proven to be a useful technique for organic syntheses, but has Httie commercial importance. Optically active sulfonates have been used in asymmetric syntheses to selectively O-alkylate alcohols and phenols, typically on a laboratory scale. Aromatic sulfonates are cleaved, ie, desulfonated, by uv radiation to give the parent aromatic compound and a coupling product of the aromatic compound, as shown, where Ar represents an aryl group (18). [Pg.96]

Lithium. In the lithium carbonate treatment of certain psychotic states, a low incidence (3.6%) of hypothyroidism and goiter production have been observed as side effects (6,36) (see Psychopharmacologicalagents). It has been proposed that the mechanism of this action is the inhibition of adenyl cyclase. Lithium salts have not found general acceptance in the treatment of hyperthyroidism (see Lithiumand lithium compounds). [Pg.53]

Products from aminoalcohols and TYZOR TPT were obtained by a2eotropiag the isopropyl alcohol with ben2ene (121,122). From trimethylethylenediamine, dimethylethanolamine, and dimethylisopropanolamine with TYZOR TPT, the orange (11), the yellow (12), and the pale-green (13) were obtained, respectively. The lithium salt of the ligand, derived from C H Li, combiaed with (RO)2TiCl ia hexane has also been used (123). [Pg.149]

Various lithium salts and butyrolactone or PC—DME mixtures are usually used as electrolytes. The close competitive performance of CF and MnO cathodes is evidenced in Table 3. The constmction of cells is also similar for the two systems. In addition to uses mentioned for the lithium manganese dioxide system, some unique apphcations such as lighted fishing bobbers have been developed for the Japanese market. [Pg.535]

A second class of important electrolytes for rechargeable lithium batteries are soHd electrolytes. Of particular importance is the class known as soHd polymer electrolytes (SPEs). SPEs are polymers capable of forming complexes with lithium salts to yield ionic conductivity. The best known of the SPEs are the lithium salt complexes of poly(ethylene oxide) [25322-68-3] (PEO), —(CH2CH20) —, and poly(propylene oxide) [25322-69-4] (PPO) (11—13). Whereas a number of experimental battery systems have been constmcted using PEO and PPO electrolytes, these systems have not exhibited suitable conductivities at or near room temperature. Advances in the 1980s included a new class of SPE based on polyphosphazene complexes suggesting that room temperature SPE batteries may be achievable (14,15). [Pg.582]

Lithium. Several processes for lithium [7439-93-2], Li, metal production have been developed. The Downs cell with LiCl—KCl electrolyte produces lithium ia much the same manner as sodium is produced. Lithium metal or lithium—aluminum alloy can be produced from a mixture of fused chloride salts (108). Granular Li metal has been produced electrochemically from lithium salts ia organic solvents (109) (see LiTHlUM AND LITHIUM compounds). [Pg.80]

A novel method for preparing amino heterocycles is illustrated by the preparation of 2-amino-5-methylthiophene (159). In this approach vinyl azides act as NH2 equivalents in reaction with aromatic or heteroaromatic lithium derivatives (82TL699). A further variant for the preparation of amino heterocycles is by azide reduction the latter compounds are obtained by reaction of lithio derivatives with p- toluenesulfonyl azide and decomposition of the resulting lithium salt with tetrasodium pyrophosphate (Scheme 66) (82JOC3177). [Pg.73]


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1.4- Dihydrotriazine tris solvate lithium salt, formation

3-Pentanol, 3-ethyl-, lithium salt

4- arenethiolate lithium salt

Acetic acid, lithium salt, dihydrate

Acetylene lithium salt

Alanine bis-lactim ether, lithium salt

Amino acid lithium salt

Azomethine derivatives, lithium salts

Benzene chelated lithium salts

Benzenethiol, lithium salt

Benzenethiol, lithium salt [Thiophenol

Catalysis by Lithium Salts

Copolymerization lithium salts

Copper salts in preparation of lithium dialkylcuprates

Cuprate, bis lithium salt

Cuprate, bis lithium salt conjugate addition to a,(3-unsaturated esters

Cyclohexanones lithium salts

Diisopropylamide, lithium salt

Diisopropylamine, lithium salt

Electrolyte salts lithium halides

Electrolyte salts lithium perchlorate

Enolates, lithium salts, aldol

Enolates, lithium salts, aldol condensation with

Formaldehyde lithium salt complexes

Formic acid, lithium salt

Hexazidocuprate-lithium salt

Hydrazones lithium salts

Imines lithium salts

Inorganic lithium salts

Interface between Transition Metal Oxides-Based Electrodes and Lithium Salts Electrolytes A Physicochemical Approach

Lithium aluminum hydride metal salt systems

Lithium aluminum hydride phosphonium salts

Lithium bromide salts, extraction

Lithium molten-salt electrowinning

Lithium phosphonium salts

Lithium polymer-salt

Lithium salt dissociation

Lithium salt of

Lithium salt of 2- -l,2thiaborolide, reaction with ruthenium

Lithium salt of 2- -l,2thiaborolide, reaction with ruthenium and zinc complexes

Lithium salt solutions

Lithium salt/poly systems

Lithium salt/poly systems ionic conductivity

Lithium salts Lewis acids

Lithium salts anions

Lithium salts catalysts

Lithium salts electrolytic conductivity

Lithium salts epoxide ring opening

Lithium salts in medicine

Lithium salts manufacturing

Lithium salts molecular structures

Lithium salts molecular weight

Lithium salts oxidation potentials

Lithium salts reactions with

Lithium salts species

Lithium salts theoretical studies

Lithium salts with large anions

Lithium salts, NSAIDs and

Lithium salts, Wittig reaction

Lithium salts, aggregation

Lithium salts, complexes with macrocyclic

Lithium salts, complexes with macrocyclic ligands

Lithium salts, in treatment of manicdepressive illness

Lithium salts, role

Lithium salts, role carbonylation

Lithium solid-electrolyte/metal salt batteries

Lithium, crotylconfigurational stability reaction with iminium salts

Lithium/ions/salts

Nonaqueous Electrolytes Advances in Lithium Salts

Nonaqueous lithium salt electrolyte

Nucleophilic addition reactions lithium salts

Oximes lithium salts

Oxygen lithium salt

Passivation and Corrosion Abilities of Lithium Salt Electrolytes

Piperidine 2.2.6.6- tetramethyl-, lithium salt

Pyridinium salts lithium aluminum hydride reduction

Salt cake , lithium

Sulfone, benzyl phenyl lithium salt

Tosylhydrazone lithium salt

Unsaturated carboxylic acids, lithium salts

Uric acid lithium salt

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