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Sulfonation aromatic

Among the variety of electrophilic species present m concentrated sulfuric acid sulfur tnoxide (Figure 12 4) is probably the actual electrophile m aromatic sulfonation We can represent the mechanism of sulfonation of benzene by sulfur tnoxide by the sequence of steps shown m Figure 12 5... [Pg.479]

Most phenohc foams are produced from resoles and acid catalyst suitable water-soluble acid catalysts are mineral acids (such as hydrochloric acid or sulfuric acid) and aromatic sulfonic acids (63). Phenohc foams can be produced from novolacs but with more difficulty than from resoles (59). Novolacs are thermoplastic and require a source of methylene group to permit cure. This is usually suppHed by hexamethylenetetramine (64). [Pg.406]

H. Cerfontain, Mechanisticdspects in Aromatic Sulfonation and Desulfonation, Wiley-Interscience, New York, 1968. [Pg.506]

The aromatic sulfone polymers are a group of high performance plastics, many of which have relatively closely related stmctures and similar properties (see Polymers containing sulfur, polysulfones). Chemically, all are polyethersulfones, ie, they have both aryl ether (ArOAr) and aryl sulfone (ArS02Ar) linkages in the polymer backbone. The simplest polyethersulfone (5) consists of aromatic rings linked alternately by ether and sulfone groups. [Pg.331]

The first aromatic sulfone polymer produced commercially was introduced as Bakelite polysulfone but now is sold by Union Carbide under the trade name Udel. It is made by reaction of the disodium salt of bisphenol A (BPA) with 4,4 -dichIorodiphenyl sulfone in a mixed solvent of chlorobenzene and dimethyl sulfoxide (eq. 12). [Pg.331]

PoIysuIfonyIa.tlon, The polysulfonylation route to aromatic sulfone polymers was developed independendy by Minnesota Mining and Manufacturing (3M) and by Imperial Chemical Industries (ICI) at about the same time (81). In the polymerisation step, sulfone links are formed by reaction of an aromatic sulfonyl chloride with a second aromatic ring. The reaction is similar to the Friedel-Crafts acylation reaction. The key to development of sulfonylation as a polymerisation process was the discovery that, unlike the acylation reaction which requires equimolar amounts of aluminum chloride or other strong Lewis acids, sulfonylation can be accompHshed with only catalytic amounts of certain haUdes, eg, FeCl, SbCl, and InCl. The reaction is a typical electrophilic substitution by an arylsulfonium cation (eq. 13). [Pg.332]

SolubiHty of the three commercial polysulfones foUows the order PSF > PES > PPSF. At room temperature, all three of these polysulfones as weU as the vast majority of other aromatic sulfone-based polymers can be readily dissolved in a few highly polar solvents to form stable solutions. These solvents include NMP, DMAc, pyridine, and aniline. 1,1,2-Trichloroethane and 1,1,2,2-tetrachloroethane are also suitable solvents but are less desirable because of their potentially harmful health effects. PSF is also readily soluble in a host of less polar solvents by virtue of its lower solubiHty parameter. [Pg.467]

WU low cost reactions not stoichio-metric 3—4 mol dyes, alkylated aromatic sulfonation ... [Pg.76]

Batch Stirred Tank H2SO /Oleum Aromatic Sulfonation Processes. Low molecular weight aromatic hydrocarbc... [Pg.85]

H. Cerfontain, Mechanistic A.spects in Aromatic Sulfonation and Desufonation, Interscience Pubhshers, New York, 1965. [Pg.90]

Sulfonic acids are prone to reduction with iodine [7553-56-2] in the presence of triphenylphosphine [603-35-0] to produce the corresponding iodides. This type of reduction is also facile with alkyl sulfonates (16). Aromatic sulfonic acids may also be reduced electrochemicaHy to give the parent arene. However, sulfonic acids, when reduced with iodine and phosphoms [7723-14-0] produce thiols (qv). Amination of sulfonates has also been reported, in which the carbon—sulfur bond is cleaved (17). Ortho-Hthiation of sulfonic acid lithium salts has proven to be a useful technique for organic syntheses, but has Httie commercial importance. Optically active sulfonates have been used in asymmetric syntheses to selectively O-alkylate alcohols and phenols, typically on a laboratory scale. Aromatic sulfonates are cleaved, ie, desulfonated, by uv radiation to give the parent aromatic compound and a coupling product of the aromatic compound, as shown, where Ar represents an aryl group (18). [Pg.96]

Sulfonic acids may be subjected to a variety of transformation conditions, as shown in Figure 2. Sulfonic acids can be used to produce sulfonic anhydrides by treatment with a dehydrating agent, such as thionyl chloride [7719-09-7J. This transformation is also accomphshed using phosphoms pentoxide [1314-56-3J. Sulfonic anhydrides, particulady aromatic sulfonic anhydrides, are often produced in situ during sulfonation with sulfur trioxide. Under dehydrating conditions, sulfonic acids react with substituted aromatic compounds to give sulfone derivatives. [Pg.96]

Sulfonic acids may be hydrolytically cleaved, using high temperatures and pressures, to drive the reaction to completion. As would be expected, each sulfonic acid has its own unique hydrolytic desulfonation temperature. Lower alkane sulfonic acids possess excellent hydrolytic stability, as compared to aromatic sulfonic acids which ate readily hydrolyzed. Flydrolytic desulfonation finds use in the separation of isomers of xylene sulfonic acids and other substituted mono-, di-, and polysulfonic acids. [Pg.96]

The cleavage products of several sulfonates are utilized on an industrial scale (Fig. 3). The fusion of aromatic sulfonates with sodium hydroxide [1310-73-2J and other caustic alkalies produces phenohc salts (see Alkylphenols Phenol). Chlorinated aromatics are produced by treatment of an aromatic sulfonate with hydrochloric acid and sodium chlorate [7775-09-9J. Nitriles (qv) (see Supplement) can be produced by reaction of a sulfonate with a cyanide salt. Arenesulfonates can be converted to amines with the use of ammonia. This transformation is also rather facile using mono- and dialkylamines. [Pg.96]

Miscellaneous Reactions. Aromatic sulfonic acid derivatives can be nitrated using nitric acid [52583-42-3] HNO, ia H2SO4 (19). Sultones may be treated with hydrazine derivatives to give the corresponding ring-opened sulfonic acid (20). [Pg.97]

Fast Color Salts. In order to simplify the work of the dyer, diazonium salts, in the form of stable dry powders, were introduced under the name of fast color salts. When dissolved in water they react like ordinary diazo compounds. These diazonium salts, derived from amines, free from solubilizing groups, are prepared by the usual method and are salted out from the solutions as the sulfates, the metallic double salts, or the aromatic sulfonates. The isolated diazonium salt is sold in admixture with anhydrous salts such as sodium sulfate or magnesium sulfate. [Pg.445]

The term novolac refers to the early use of phenolic to replace expensive shellac-based coatings. Novolacs are now those resins made at formaldehyde-to-phenol molar ratios of less than one-to-one. They are generally, though not always, manufactured under acidic conditions. Sulfuric or oxalic acids are most often chosen as catalyst though aromatic sulfonic acids and phosphoric acid are also quite common. Many other acids are used for special purposes. The finished novolac resin is incapable of further polymerization or crosslinking and therefore... [Pg.873]

Recently, the pyrazole group containing bisphenols have been synthesized from activated aromatic dihalides and 3,5-bis (4-hydroxy phenyl)-4-phenyl pyrazole or 3,5-bis(4-hydroxy phenyl)-1,4-diphenyl pyrazole. A novel synthesis of imido aryl containing bisphenols has been reported [32]. N-substituted l,4-bis(4-hydroxy phenyl)-2,3-naphthalimides were prepared from phenolphthalein and copolymerized with aromatic sulfone or ketone difluorides to obtain the poly(imidoaryl ether) sulfones/ ketones. [Pg.37]

Methyl esters of aromatic sulfonic acids (S020CH3)... [Pg.149]

Dapsone, an aromatic sulfone, is administered in combination with a proguanil derivative. Dapsone... [Pg.172]


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Alkyl sulfonates with aromatic rings

Aromatic amines sulfonated

Aromatic compounds benzene sulfonic acid

Aromatic compounds from aryl sulfonic acids

Aromatic compounds sulfonated

Aromatic compounds sulfonation

Aromatic compounds sulfonations, sulfur trioxide

Aromatic compounds sulfone

Aromatic compounds sulfones

Aromatic compounds, fused sulfonation

Aromatic poly sulfonates

Aromatic poly(ether sulfone)

Aromatic rings sulfonation

Aromatic substitution reactions sulfonation

Aromatic sulfonates, alkyl

Aromatic sulfonation by halosulfuric acids and other sulfonating agents

Aromatic sulfonation by sulfuric acid or oleum

Aromatic sulfonations

Aromatic sulfonations

Aromatic sulfonic acids

Aromatic sulfonic acids, synthesis

Aromatics Sulfonic acids

Aromatics sulfonation

Aromatics sulfonation

Detergents sulfonated aromatic

Electrophilic aromatic substitution Nitration Sulfonation

Electrophilic aromatic substitution of sulfonation

Electrophilic aromatic substitution reactions sulfonation

Electrophilic aromatic substitution sulfonation

Mechanism aromatic sulfonation

Sulfonate aromatic

Sulfonate aromatic

Sulfonate group reactive aromatic

Sulfonated Aromatic

Sulfonated Aromatic

Sulfonated Aromatic Polymers

Sulfonated aromatic polymer membranes

Sulfonation of aromatic compounds

Sulfonation of aromatic hydrocarbons and

Sulfonation, electrophilic aromatic

Sulfonation, of aromatic amines

Sulfonation, of aromatic rings

Sulfonation, of aromatics

Sulfone aromatic

Sulfone aromatic substitution

Sulfones aromatic

Sulfones diaryl, from aromatic compounds

Sulfones from aromatic compounds

Sulfones, alkylation aryl, from aromatic

Sulfonic acids from aromatic compounds

Sulfonic acids from aromatic sulfonation

Sulfonic acids with aromatic rings

Sulfonic aromatic

Sulfonic aromatic

Toluene-p-sulfonic anhydride, acetylFriedel-Crafts reaction bimolecular aromatic

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