Lithium batteries configurations

The electronic circuit of the safety sensor consists of a p-type silicon electrode, an LED, a resistor, two 3 V lithium batteries, and a platinum wire as a counter electrode, connected in series, as shown in the right part of Fig. 10.7. These components are assembled in a pen-like housing, optimized to measure even thin layers of liquid on a flat surface, as shown in the left part of Fig. 10.7. This configuration is advantageous if a puddle, observed for example under a wet bench or other equipment, is to be analyzed. 

Figure 1. Typical battery configurations (a) button cell (b) stack lead acid (c) spiral wound cylindrical lithium ion (d) spiral wound prismatic lithium-ion.

The above discussion provides the context for 3-D batteries. That is, there are a variety of small power applications, typified by MEMS devices, which the most advanced, 2-D lithium battery systems are unable to satisfy. The inability to provide sufficient power is because of configuration and not because of intrinsic energy density. Three-dimensional designs offer the opportunity to achieve milliwatt-hour energies in cubic millimeter packages and, more importantly, with square millimeter footprints. While such power sources may not influence the enormous commercial markets in cell phones and laptop computers, they are certain to impact emerging markets where... 

The lilhium-Uiiouyl chluridc, or die lithium-sulfur dioxide, system is often used in a reserve battery configuration in which the electrolyle is slored in a sealed compartment which upon activation may be forced by a piston or inertial forces into the interelectrode space. Most applications for such batteries arc in mines and fuse applications in military ordnance. 

Miscellaneous hazardous materials in DOT/UN Class 9 are defined as a material which presents a hazard during transportation, but which does not meet the definition of any other hazard class. Other hazards might include anesthetic, noxious (harmful to health), elevated temperature, hazardous substance, hazardous waste, or marine pollutant. They may be encountered as solids of varying configurations, gases, and liquids. Examples include asbestos, dry ice, molten sulfur, and lithium batteries. These materials would be labeled and placarded with the Class 9 Miscellaneous Hazardous Materials placard, which is white with seven vertical black stripes on the top half. 

Li conducting pathways at the ceramic surface [44-46]. Therefore, according to this model, the structural modifications at microscopic levels promote consistent enhancement in the transport properties of the electrolyte. In addition, the all-solid configuration (no addition of liquids) gives to these nanocomposite electrolytes a high compatibility with the lithium metal electrode [47-50], all these properties making them suitable for use as safe and efficient separators in rechargeable lithium batteries [51]. 

One may then conclude that, the gel-type electrolytes, and the PAN-based ones in particular, have electrochemical properties that in principle make them suitable for application in versatile, high-energy lithium batteries. In practice, their use may be limited by the reactivity towards the lithium electrodes induced by the high content of the liquid component. Indeed, severe passivation phenomenon occurs when the lithium metal electrode is kept in contact with the gel electrolytes [60, 69]. This confirms the general rule that if from one side the wet-like configuration is essential to confer high conductivity to a given polymer electrolyte, from the other it unavoidably affects its interfacial stability with the lithium metal electrode. 

Battery safety has been obviously given a special attention in this volume. Commercial lithium-ion cells and batteries are commonly used to power portable equipment, but they are also used to buildup larger batteries for ground (e.g. EVs), space and underwater applications. Chapter 17 provides test data on the safety of commercial lithium-ion cells and recommendations for safe design when these cells are used in much larger battery configurations. Chapter 18 focuses on safety aspects of LIBs at the cell and system level. In particular, abuse tolerance tests are explained with actual cell test data. Furthermore, internal short and lithium deposition occurring in lithium-ion cells and failure mechanism associated with them are discussed. In Chapter 19, the state of the art for safety optimization of all the battery elements is presented. This chapter also reports tests on not yet commercialized batteries, which pass all the security tests without the help of a BMS. 

The belief that lithium batteries may be the best way to power electric vehicles (EVs) has strongly stimulated interest in hthium. New battery configurations continue to be developed. Pyrrole is a suitable electrode material for rechargeable lithium batteries. In a flat cell, polypyrrole and Hthium films are sandwiched together. In a cylindrical cell the two films are wound concentrically. 

The LiMnOj battery is the most popular lithium battery, and it is produced worldwide by more than 14 manufacturers. The battery cells are available in a wide range of sizes, shapes, and capacities. Types of construction features for this battery include coin shape, cylindrical bobbin, cylindrical wound, cylindrical D cell configuration, and prismatic feature. Performance characteristics of commercially available LiMn204 rechargeable batteries are summarized in Table 8.2. 

The solid-cathode lithium batteries are generally used in low- to moderate-drain applications and are manufactured mainly in small flat or cylindrical sizes ranging in capacity from 30 mAh to about 5 Ah, depending on the particular electrochemical system. Larger batteries have been produced in cylindrical and prismatic configurations. A comparison of the performance of solid-cathode lithium batteries and conventional batteries is presented in Chap. 7. 

Figure 3.26 Potential-specific capacity curves between 0 and 2 V versus Li /Li and at cycling of electrodes based on 80HF In lithium metal rate of C/10. (Adapted with permission of battery configuration. Electrochemical tests WIley-VCH Verlag GmbH, Copyright 2009.) were realized using a potential window...

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