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Ligand-bridged

This book is a highly readable introduction to the reactions of coordinated ligands. Bridging the gap between the traditional fields, this text presents the basic concepts of ligand reactivity as well as many synthetic applications of these reactions. [Pg.799]

The interaction of a complex anion SbY5Z with excessive Lewis acid SbX5 leads to the formation of a ligand-bridged (conjugated 1)) anion (see part 4.2.2) according to... [Pg.224]

Finally, we consider the alternative mechanism for electron transfer reactions -the inner-sphere process in which a bridge is formed between the two metal centers. The J-electron configurations of the metal ions involved have a number of profound consequences for this reaction, both for the mechanism itself and for our investigation of the reaction. The key step involves the formation of a complex in which a ligand bridges the two metal centers involved in the redox process. For this to be a low energy process, at least one of the metal centers must be labile. [Pg.194]

Another prefix used for complexes is p (mu), which indicates that the ligand bridges two metal atoms. [Pg.119]

Fig. 6.1b) in which twelve inner ligands bridge the edges of the Me octahedron, and six outer ligands occupy apical positions, predominate. These units are found in reduced zirconium, niobium, tantalum, and rare-earth halides, and niobium, tantalum, molybdenum and tungsten oxides [la, 6, 10]. [Pg.81]

Kiindig EP, Dupre C, Bourdin B, Cunningham A Jr, Pons D (1994) New C2-chiral bidentate ligands bridging the gap between donor phosphine and acceptor carbonyl ligands. Helv Chim Acta 77 421 28... [Pg.171]

The niobium phosphate complex ( Pr0)4Nb[02P(0 Bu)2] 2 was produced by the reaction of Nb(0 Pr)5 with H0P(0)(0 Bu)2 in pentane [71]. Although crystals of sufficient quality for an X-ray crystallographic analysis were not obtained, spectroscopic evidence suggests that the phosphate ligands bridge the two Nb centers. [Pg.85]

Scheme 1.57 Test reaction with bis(thiazolines) ligands bridged by a dibenzo[a,c]-cycloheptadiene backbone. Scheme 1.57 Test reaction with bis(thiazolines) ligands bridged by a dibenzo[a,c]-cycloheptadiene backbone.
Another illustration of the structural changes that may result as a consequence of alkyl substitution at the 3-position of the pyrazolyl group is provided by the structures of the dimeric copper(I) complexes [Tp]Cu 2 (36), [TpMe2]Cu 2 (36), [TpPh2]Cu 2 (37), and [TpBut]Cu 2 (37), which differ in the manner in which the tris(pyrazo-lyDhydroborato ligand bridges the two copper centers (Fig. 16). [Pg.306]

Secondly, the molecular structure of [TpPr 2]Zn 2(/u,-7)1,7)2-C03), as determined by x-ray diffraction (151,153), reveals that the carbonate ligand is coordinated in an asymmetric manner, with unidentate coordination to one zinc center and bidentate coordination to the other zinc center, i.e., fi-ri1,ri2-C03 (Scheme 24). Such coordination is noticeably distinct from that of [TpBut Me]Zn 2(/x.-r)1,7 1-C03), in which the carbonate ligand bridges in a symmetric unidentate mode. [Pg.360]

When a bidentate ligand bridges two metalloporphyrins, a linear polymeric chain is formed. This arrangement has been dubbed shish... [Pg.249]

Diphosphinoamines (X2P-NR-PX2) are examples of a more unusual potentially chelating diphosphine. The dimer Co2(F2PN(CH3)PF2)3(CO)2 has three of these ligands bridging symmetrically between the two tetrahedral Co centers, which also carry a terminal CO group this molecule can undergo reduction with LiEt3BH in THF to form a stable mixed valence (d9—d10) radical anion.163... [Pg.15]


See other pages where Ligand-bridged is mentioned: [Pg.433]    [Pg.196]    [Pg.138]    [Pg.567]    [Pg.918]    [Pg.1108]    [Pg.216]    [Pg.36]    [Pg.16]    [Pg.47]    [Pg.114]    [Pg.114]    [Pg.402]    [Pg.227]    [Pg.394]    [Pg.388]    [Pg.53]    [Pg.66]    [Pg.74]    [Pg.127]    [Pg.134]    [Pg.270]    [Pg.98]    [Pg.79]    [Pg.85]    [Pg.85]    [Pg.4]    [Pg.26]    [Pg.27]    [Pg.36]    [Pg.47]    [Pg.307]    [Pg.5]    [Pg.245]    [Pg.140]    [Pg.12]    [Pg.29]    [Pg.47]    [Pg.48]   
See also in sourсe #XX -- [ Pg.215 ]




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Alkylidyne ligand bridging

Amidines bridging ligands

And ligands bridging

Aryl-bridged ligands

Bidentate ligands, cyanide-bridged complexes

Binucleating Ligand Bridged Dimers

Blocking ligands, cyanide-bridged complexes

Bond bridging ligands

Bonded Bridging Ligands for Self-Supported Catalysts

Bridge methylene ligands

Bridged by dppm or Related Ligands

Bridged cyclopentadienyl ligands

Bridged dppc Ligands

Bridged surface ligands

Bridging Aryl Ligands

Bridging Bidentate Ligands

Bridging H-ligands

Bridging Ligands with Participating Heteroatoms

Bridging Ligands without Heteroatoms

Bridging Monodentate Ligands

Bridging allyl ligands

Bridging cyanide ligands

Bridging cyano ligands

Bridging diphosphine ligands

Bridging fluoro ligands

Bridging halide ligands

Bridging ligand LUMO)

Bridging ligand adjacent atom attack

Bridging ligand effect

Bridging ligand isomers

Bridging ligand lowest unoccupied molecular orbital

Bridging ligand remote attack

Bridging ligand, strong interactions between metals through

Bridging ligand, weak interaction

Bridging ligand, weak interaction between metals through

Bridging ligands

Bridging ligands

Bridging ligands , supramolecular assembly

Bridging ligands Alkylidene

Bridging ligands alkyl groups

Bridging ligands arsenic

Bridging ligands bipyridine-type

Bridging ligands boron

Bridging ligands bridge index

Bridging ligands coordination compounds

Bridging ligands cyclopentadienyl

Bridging ligands double hydroxide

Bridging ligands doubly bridged polymers

Bridging ligands electron counting

Bridging ligands four-electron

Bridging ligands hydrogen

Bridging ligands hydroxides

Bridging ligands methylene

Bridging ligands multiplicity

Bridging ligands nickel adducts

Bridging ligands oxides

Bridging ligands oxygen

Bridging ligands phosphorus

Bridging ligands polymetallic complexes

Bridging ligands polynuclear species

Bridging ligands stability

Bridging ligands substitution

Bridging ligands synthesis

Bridging ligands tellurium

Bridging ligands water

Bridging ligands xanthate structures

Bridging ligands, in triosmium clusters synthesis

Bridging ligands, lanthanide cyclopentadienyl

Bridging ligands, neutral

Bridging selenido ligands

Carbonyl ligand face-bridging

Catalyst bridging ligand

Catalysts design bridging ligand

Chelation bridging ligands

Chiral bridging ligands

Chirality transfer via resolved bridging ligands

Chromium bridging ligands

Chromium complexes bridging ligands

Cluster bridging alkylidyne ligand

Clusters containing edge-bridging N-donor ligands

Clusters containing face-bridging N-donor ligands

Complexes Containing Bridging PF2 Ligands

Complexes with Chalcogenide and Related Bridging Ligands

Compounds with Ring-bridged Cyclopentadienyl Ligands

Coordination complexes bridging ligand structures

Copper complexes bridging ligands

Covalent bonded bridging ligands

Covalent bonded bridging ligands hydrogenations

Covalently bound bridging ligand

Diaza bridging ligands

Didentate ligands bridging

Dinickel bridging ligands

Diphenylphosphido bridging ligands

Diphosphonate ligands bridging

Double bridging sulfido ligands

Double ligand bridges

Double-ligand bridging

Double-ligand bridging defined

Dpp bridging ligands

Electron transfer bridging ligand

Electron transfer bridging ligand effects

Electron transfer bridging ligand properties

Endogenous Ligand Bridge

Ethylene-bridged ligands

Exogenous Bridging Ligands

Face-bridging hydride ligands

Face-bridging ligands

Hemocyanin bridging ligands

Heterometallic Complexes Derived from Bridging and Multi-compartmental Ligands

Heterometallic complexes bridging ligands

Homo-bridged ligand

Hydride ligands, bridging

Hydrogen-bonded bridging ligands

Imides bridging ligands

Imido complexes bridging ligands

Inner ligand bridged

Introduction of the Ligands as Bridging Units

Involving Bridging Organic Ligands

Iridium complexes bridging ligands

Isonicotinate bridging ligand

Ligand bridged dimers

Ligand bridging carbonyl

Ligand bridging, palladium complexes

Ligand bridging-chelating

Ligand compounds with bridging alkylidene

Ligand containing bridging hydride

Ligand edge-bridging

Ligand exchange processes, bridged

Ligand molecules with bridging hydride

Ligand structures cyanide-bridged complexes

Ligand triple-bridging

Ligand-bridged binuclear complexes

Ligand-bridged complexes

Ligand-bridged processes

Ligands bridges

Ligands bridging hydroxo

Ligands chalcogen bridging

Linear bridging ligands, supramolecular

Linear bridging ligands, supramolecular complexes

Meeting More Metals - Bridging Ligands

Metal-coordinated bridging ligands

Metal-coordinated bridging ligands assemblies

Mixed-valence complexes bridging ligand nature

Molybdenum complexes ligand-bridged carbonyls

Molybdenum complexes reaction with bridging ligands

Molybdenum complexes three bridging ligands

Monoanionic three-atom bridge ligands

Monodentate ligands, cyanide-bridged

Monodentate ligands, cyanide-bridged complexes

Nanofibers Self-Assembled from Lipophilic Bridging Ligands and Metal Ions

Naphthyl, bridging ligand

Nickel complexes bridging ligands

Non-bridging ligands

Organic bridging ligand

Organometallic compounds bridging ligands

Organometallic compounds with bridging ligands

Osmium bridging hydride ligands

Other ligand-bridged compounds

Oxidation-reduction reactions Bridging ligand

Palladium bridging ligand

Perchlorates bridging ligand

Phosphine bridging ligands

Phosphine bridging ligands binuclear complexes with

Platinum complexes bridging ligands

Polyazine bridging ligands

Polymeric Complexes containing Bridging O-Donor Ligands

Polynuclear cations bridging ligands

Polynuclear compounds bridging ligands

Redox active bridging ligands

Rhenium complexes bridging ligands

Rhodium complexes bridging ligands

Rhodium complexes without bridging ligands

Ring-bridged cyclopentadienyl ligands

Ring-bridged cyclopentadienyl ligands lanthanide compounds

Ruthenium ligand-bridged

Samarium complexes ligand-bridged dimers

Semi-bridging carbonyl ligands

Semi-bridging ligands

Silane ligand bridging

Silver complexes bridging ligands

Strong bridging ligands

Subject bridging ligands

Sulfur bridging ligands

Synthesis and Complexation of Ethene Bridged Bis(phosphine) Ligands

Technetium oxygen ligands and oxo-bridged complexes

The Bridging Ligand

The Bridging Ligand in Inner-Sphere Redox Reactions

Thiocyanate, bridging ligand

Thioethers bridging ligands

Thiolate ligands bridging metal centers

Thiolates bridging ligands

Transition metal complexes bridging ligands

Triazines bridging ligands

Triazoles, bridging ligands

Triosmium clusters bridging ligands

Triply bridging sulfido ligands

Tris bridging ligand

Tungsten complexes bridging ligands

Water as a bridging ligand

Zirconium complexes bridging ligands

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