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Carbonyl ligand face-bridging

Fig. 15.10 The Rh (CO)1 Fig. 15.10 The Rh (CO)1<v molecule. Note ihat four of the faces of the octahedron formed by the Rh atoms have carbonyl ligands bridging three rhodium atoms. [From Johnson. B...
Pd7(CO)7(PMe3)7] has been isolated from the reaction of (23) with CO.115 This cluster has a monocapped octahedral structure with one phosphine attached to each Pd atom. Four of the carbonyl ligands bridge the octahedral faces, while the other carbonyls edge bridge (Pd—Pd 2.79(2) A). [Pg.1111]

For similar compounds, the order of carbonyl basicity is face-bridging CO > edge-bridging CO > terminal CO (Section II). These trends in carbonyl basicity reflect the degree of delocalization of electron density onto the CO ligand. Carbonyl stretching frequencies provide a guide to the extent... [Pg.221]

See other pages where Carbonyl ligand face-bridging is mentioned: [Pg.440]    [Pg.1140]    [Pg.89]    [Pg.16]    [Pg.47]    [Pg.899]    [Pg.224]    [Pg.251]    [Pg.440]    [Pg.9]    [Pg.22]    [Pg.24]    [Pg.38]    [Pg.43]    [Pg.381]    [Pg.704]    [Pg.62]    [Pg.269]    [Pg.645]    [Pg.3956]    [Pg.899]    [Pg.62]    [Pg.373]    [Pg.207]    [Pg.212]    [Pg.213]    [Pg.887]    [Pg.202]    [Pg.1140]    [Pg.727]    [Pg.220]    [Pg.257]    [Pg.258]    [Pg.265]    [Pg.518]    [Pg.644]    [Pg.3955]    [Pg.767]    [Pg.326]    [Pg.449]    [Pg.455]    [Pg.606]    [Pg.609]    [Pg.738]    [Pg.1094]   
See also in sourсe #XX -- [ Pg.35 , Pg.37 , Pg.39 ]



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Bridging ligands

Carbonyl ligands

Carbonyls face bridging

Face-bridging

Face-bridging ligands

Ligand bridging carbonyl

Ligand-bridged

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