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Bridging H-ligands

H3RU6(CO)i8] 0.057 Octahedron of Ru atoms. Suggest triply bridging H ligands in trans sites. f... [Pg.367]

Terminal M-H bonds in metal cluster complexes are occasionally found (see Table 3). Some of them are noteworthy in that they contain both terminal and bridging H ligands on the same metal atom. Examples include H2Os3(CO)n 78>... [Pg.17]

Fig. 14. The structure of H2Osn(CO)11, a rather uncommon example of a cluster complex containing both terminal and bridging H ligands attached to the same metal atom (Ref. 78)... Fig. 14. The structure of H2Osn(CO)11, a rather uncommon example of a cluster complex containing both terminal and bridging H ligands attached to the same metal atom (Ref. 78)...
Fig. 3.3. The structure of H20s3(C0)n. Both terminal and bridging H-ligands are attached to the same metal atom. Reproduced with permission from Churchill MR, De Boer BG (1977) Inorg. Chem. 16 878... Fig. 3.3. The structure of H20s3(C0)n. Both terminal and bridging H-ligands are attached to the same metal atom. Reproduced with permission from Churchill MR, De Boer BG (1977) Inorg. Chem. 16 878...
From the point of view of bonding, terminal H-ligands form two-center/two-electron bonds meanwhile edge-bridging and face-bridging H-ligands are... [Pg.185]

Zhang, H.-X. and Che, C.-M. (2001) Aurophilic Attraction and Luminescence of Binuclear Gold(I) Complexes with Bridging Phosphine Ligands ah initio Study. Chemistry - A European Journal, 7, 4887-4893. [Pg.233]


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See also in sourсe #XX -- [ Pg.183 ]




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Bridging ligands

H-bridge

Ligand-bridged

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