Tungsten complexes bridging ligands

Bishomoallyl alcohols, via allyindium reagents, 9, 703 Bis(hydrostannation), in tin-carbon bond formation, 3, 814 Bis(imidazolyl) ligands, chromium complexes, 5, 359 Bis(imido) systems, with chromium(VI), as models, 5, 377 Bis(imido)tungsten complexes, synthesis, 5, 749 Bis(imido)uranium(VI) complexes, synthesis, 4, 216-217 Bis(imino)carbenes, with Zr(IV), 4, 798 Bis(iminooxazolidine) complexes, biaryl-bridged, with Zr(IV) and Hf(IV), 4, 811-812... 

Treatment of 7 with DMD leads to the short-lived bis-silanol A. However, this intermediate undergoes intramolecular condensation, resulting immediately in the formation of the tungsten complex 8 bearing a disiloxane unit bridging the cyclopentadienyl ligand and the metal center. 8 is... 

Many tungsten(III) complexes have been reported as W-W triple-bonded derivatives, which are described in Chapter 4.9. The other compounds are discussed here, including dimeric tungsten (III) complexes containing bridging ligands are described. 

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