Of coordinated ligands

This book is a highly readable introduction to the reactions of coordinated ligands. Bridging the gap between the traditional fields, this text presents the basic concepts of ligand reactivity as well as many synthetic applications of these reactions. 

Lewis Acid Catalysis and the Reactions of Coordinated Ligands... 

Minghetti, G., Bonati, F. and Banditelli, G. (1976) Carhene Complexes Of Gold (III) And Reactions Of Coordinated Ligand. Inorganic Chemistry, 15(7), 1718-1720. 

The species absorbed on the unprotected metal nanoclusters, i.e. EG and the simple anions, can be easily replaced by many kinds of coordination ligands or protective agents. This character makes it possible to prepare various metal nanoclusters with the same metal core and different modifying or protective shells. The metal... 

Reactions such as this are electrophilic substitutions, and other electrophiles such as N02 , Cl l3CO, or Cl IO can be substituted on the rings without destroying the complex. Such chemical behavior illustrates the extreme stability of complexes of this type. It is apparent that the nature of the bonding in the chelate rings is as important as is their size. Other reactions of coordinated ligands will be shown in later chapters. 

CH3Mn(CO)4THF has been identified, so the conjecture that THF and DMF behave in a manner that is different from the other solvents is not without some justification. Additional work on the influence of the solvent could yield additional insight regarding the mechanisms of this and other reactions of coordinated ligands. 

Redox Reactivity of Coordinated Ligands in Pentacyano(L)Ferrate Complexes Jose A. Olabe... 

J. E. Backvall, Nucleophilic Attack on Coordinated Alkenes , in Reaction of Coordinated Ligands (Ed. P. S. Braterman), Plenum Press, London 1986, pp. 679-731. 

Schrock RR (1986) In Braterman PR (ed) Reactions of coordinated ligands. Plenum,... 

Hydrolysis of coordinated ligands is a special case of nucleophilic attack. Two examples involving inorganic ligands have already been given in Section II. A on aquation of cobalt(III) complexes. Many further examples will be found in the following Section VII.B on catalysis of hydrolysis of organic substrates by metal ions and complexes. 

Chemisorption Adsorbate Orientation Competitive Chemisorption Adsorbate Exchange Adsorbate Reactivity Electrocatalvsis Synthesis Mode of Coordination Ligand Substitution Ligand Exchange Ligand Reactivity Homoqeneous Catalysis... 

The same type of coordinating ligands will be discussed for other metal complexes. 

Complexes of PyzO with lanthanide perchlorates (2 79) and hexafluorophosphates 180) are eight coordinate. However, La(III) perchlorate gives the complex La(Pyz0)7(C104)3 2 H20 in which both the water molecules are coordinated to La(III). In the case of complexes of PyzO with lanthanide chlorides 180), the number of coordinated ligands increases as the ionic radius of the lanthanide ion decreases. These complexes probably contain bridging ligands. 

B35. G. Wilkinson, R. D. Gillard and J. A. McCleverty (eds) Comprehensive Coordination Chemistry, Vol. 1. Theory and Background, Pergamon, Oxford, 1987. Chapter 7.1, M. L. Tobe (Substitution) Chapter 7.2, T. J. Meyer and H. Taube (Electron Transfer) Chap. 7.4 D. St. C. Black (Reactions of Coordinated Ligands). 

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