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Phosphine bridging ligands

Metal-Metal Bond Making and Breaking in Binuclear Complexes with Phosphine Bridging Ligands... [Pg.167]

Binuclear Complexes with Phosphine Bridging Ligands... [Pg.183]

There already exist examples of significant chemical reactions which demonstrate the unusual reaction characteristic resulting from the presence of two metal centers.Here we examine two, neither of which involves phosphine bridging ligands. The autoxidation of triphenylphosphine catalyzed by four-coordinate iron(II) porphyrins in a noncoordinating solvent like toluene occurs by the mechanism shown in Figure Two... [Pg.168]

Li L, Reginato N et al (2003) The synthesis and structural characterization of linear and macrocyclic bis(dinitrosyliron) complexes supported by bis(phosphine) bridging ligands. J Can Chem 81 468 75... [Pg.53]

Phosphinate groups are solid bridging ligands and metal phosphinates are usually resistant to oxidation and hydrolysis... [Pg.156]


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Bridging ligands

Bridging phosphines

Ligand-bridged

Phosphine bridging ligands binuclear complexes with

Phosphine ligand

Synthesis and Complexation of Ethene Bridged Bis(phosphine) Ligands

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