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Molybdenum complexes reaction with bridging ligands

For mononuclear complexes, reactions at coordinated ligands is a topic of major study, and numerous reviews and even books have been written on this topic. At the time of writing this review, the authors could find no major review articles in this area for dinuclear compoimds. The best examples are probably those on the reactions of coordinated molybdenum sulfides discussed earlier. A related observation is the reaction of metal carbonyls with Lewis acids. It has been observed by Shriver and coworkers that carbonyl ligands bridging metal-metal bond atoms show increased tendency to coordinate Lewis acids (equation 96). [Pg.1157]

Dithiocarbamates, in Ru and Os half-sandwiches, 6, 493 Dithiocarbenes, Pt complexes, 8, 439 Dithiocarboxy ligands, in molybdenum carbonyls, 5, 447 Dithiolate-bridged compounds in dinuclear iron compounds with Fe-Fe bonds, 6, 238 as iron-only hydrogenase biomimetic models, 6, 239 Dithiolate diamides, with Zr(IV), 4, 784 Dithiolene—uranium complexes, synthesis and characterization, 4, 212 Ditopic receptors, characteristics, 12, 489 Ditungsten complexes, associated reactions, 5, 748 Divinyllead diacetates... [Pg.99]

PhS, p-tolS) initially yields the bis(nitrile) complexes [MI2(CO) (NCMe)2(i72-RC2R )]. which dimerize to yield the iodo-bridged complexes [ M(/t-I)I(CO)(NCMe)(T)2-RC2R ) 2].245 The reactions of the diphenylacet-ylene molybdenum complex with donor ligands and alkynes are shown in Scheme 6. [Pg.78]


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See also in sourсe #XX -- [ Pg.1313 ]




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Bridging ligands

Complexes with //-ligands

Ligand-bridged

Ligand-bridged complexes

Molybdenum complexes reactions

Molybdenum complexes, with

Molybdenum ligand complexes

Molybdenum reactions

Molybdenum reactions with

Reactions with ligands

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