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Electron transfer bridging ligand effects

In systems such as [A... A ]+ where an electron (or a hole) hesitates or oscillates between two equivalent positions on subsystems A or A, symme breakings may occur when the effective transfer integral between the two sites is weak. Hiis will be the case when A and A are far apart, when they are bridged by an "insulating" ligand, or when the two localized MOs concerned by the electron transfer have a very we spatial overlap. [Pg.109]

The electronic structure of oxidant and reductant, nature of bridging ligand, formation as well as fission of complex are the factors which can effect the rate of the inner sphere electron transfer mechanism. [Pg.141]

See other pages where Electron transfer bridging ligand effects is mentioned: [Pg.617]    [Pg.84]    [Pg.73]    [Pg.22]    [Pg.26]    [Pg.340]    [Pg.190]    [Pg.191]    [Pg.373]    [Pg.260]    [Pg.166]    [Pg.408]    [Pg.311]    [Pg.281]    [Pg.308]    [Pg.429]    [Pg.605]    [Pg.606]    [Pg.632]    [Pg.429]    [Pg.243]    [Pg.62]    [Pg.599]    [Pg.110]    [Pg.178]    [Pg.145]    [Pg.377]    [Pg.378]    [Pg.378]    [Pg.183]    [Pg.284]    [Pg.167]    [Pg.167]    [Pg.175]    [Pg.162]    [Pg.22]    [Pg.303]    [Pg.222]    [Pg.546]    [Pg.852]    [Pg.285]    [Pg.300]    [Pg.302]    [Pg.303]    [Pg.607]    [Pg.407]    [Pg.1185]   
See also in sourсe #XX -- [ Pg.274 ]



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Bridged electron transfer

Bridging effects

Bridging ligands

Electron ligand transfer

Electron transfer effect

Ligand effect

Ligand effective

Ligand-bridged

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