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Thiolate ligands bridging metal centers

Reaction of ZrBn4 with PhSH in the presence of BnMgCl afforded the disordered salt [MgTHF6] [Zr2(SPh)7.2(Bn)1.8]2.597 The anion contains three bridging thiolate groups between the octahedral metal centers. Thiolate ligands have also been employed to replace the halides in OEP complexes. For example, the related dithiolate derivative Hf(OEP)(l,2-S2C6H4) has been reported.603... [Pg.143]

See other pages where Thiolate ligands bridging metal centers is mentioned: [Pg.437]    [Pg.419]    [Pg.368]    [Pg.66]    [Pg.444]    [Pg.445]    [Pg.446]    [Pg.605]    [Pg.1192]    [Pg.715]    [Pg.198]    [Pg.567]    [Pg.262]    [Pg.40]    [Pg.279]    [Pg.602]    [Pg.606]    [Pg.614]    [Pg.672]    [Pg.602]    [Pg.606]    [Pg.614]    [Pg.672]    [Pg.21]    [Pg.2523]    [Pg.2670]    [Pg.4172]    [Pg.6445]    [Pg.165]    [Pg.424]    [Pg.440]    [Pg.386]    [Pg.387]    [Pg.1585]    [Pg.279]    [Pg.98]    [Pg.139]    [Pg.762]    [Pg.567]    [Pg.122]    [Pg.135]    [Pg.265]    [Pg.276]    [Pg.2522]    [Pg.2669]    [Pg.4171]    [Pg.6444]    [Pg.304]    [Pg.13]   
See also in sourсe #XX -- [ Pg.139 ]



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Bridging ligands

Ligand-bridged

Metal bridged

Metal center

Metal thiolate

Metal thiolates

Thiolate

Thiolate bridges

Thiolates

Thiolates bridging ligands

Thiolation

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