Ozone ground level

Perfluorinated ethers and perfluorinated tertiary amines do not contribute to the formation of ground level ozone and are exempt from VOC regulations (32). The commercial compounds discussed above have an ozone depletion potential of zero because they do not contain either chlorine or bromine which take part in catalytic cycles that destroy stratospheric ozone (33). 

Tide 1 of the CAAA of 1990 focuses on utiHty units located in ozone nonattainment regions of the United States, which include approximately 100 different areas where national standards for ground-level ozone (O ) are exceeded. More than 900 utiHty boilers are located within the nonattainment zones, including 90 units impacted by Phase I of Tide 4. These boilers represent approximately 400,000 MW of installed capacity and 60% of the country s UtiHty boilers. 

Because of the necessity to comply with national standards for ground-level ozone, some states are planning another phase of more stringent NO emissions limits which may take place in the eady 2000s. These additional post-RACT reductions may affect plants of all sizes and types, but are likely to focus on major sources. The deadline for compliance in the most extreme areas is 2010. For severe nonattainment areas (O levels 0.181—0.280 ppm), including many coastal areas in the Northeast, from northern Virginia to southern Maine, compliance must be achieved by November 2005 to November 2007. Serious ozone nonattainment areas (O levels 0.161—0.180 ppm) are expected to be in compliance by November 1999. Moderate noncompHance areas must comply by November 1996. 

Since ground-level ozone is formed by the photochemical reaction of nitrogen oxides and certain hydrocarbons, abatement strategies should focus not only on... 

Environmental Fate. A portion of releases of toluene to land and water will evaporate. Toluene may also be degraded by microorganisms. Once volatilized, toluene in the lower atmosphere will react with other atmospheric components contributing to the formation of ground-level ozone and other air pollutants. 

Smog a mixture of air pollutants, principally ground-level ozone, produced by chemical reactions involving smog-forming chemicals. See also haze. 

For example, exposure to the air toxin benzene catr increase the risk of getting myelogenous leukemia or aplastic anemia, while exposure to ground-level ozone can cause a 15 to 20 percent decrease in lung capacity in some healthy adults. 

Public concerns about air quality led to the passage of the Clean Air Act in 1970 to amendments to that act in 1977 and 1990. The 1990 amendments contained seven separate titles covering different regula-toiy programs and include requirements to install more advanced pollution control equipment and make other changes in industrial operations to reduce emissions of air pollutants. The 1990 amendments address sulfur dioxide emissions and acid rain deposition, nitrous oxide emissions, ground-level ozone, carbon monoxide emissions, particulate emissions, tail pipe emissions, evaporative emissions, reformulated gasoline, clean-fueled vehicles and fleets, hazardous air pollutants, solid waste incineration, and accidental chemical releases. 

Direct exposure to NO can cause respiratory problems. VOCs and NOjj are catalyzed by sunlight to form ground level ozone, often referred to as smog. NO can be generated from either stationary sources or mobile sources. In 1997, the EPA changed the ambient standard for ozone from 0.12 ppm to 0.08 ppm and the applicable test period was increased from I to 8 hours. 

VOCs - A VOC is any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metal carbides or carbonates and ammonium carbonate, which participate in atmospheric photochemical reactions1. VOCs are precursors to ground-level ozone production and various photochemical pollutants and are major components in the formation of smog through photochemical reactions2,3. There are many sources of VOCs, as will be discussed later. 

N02 plays a major role in the chemical reactions which generate photochemical smog and ground-level ozone, as well as contributes to the acid rain effect. Nitrogen dioxide is a strong oxidizing agent, which reacts in the air to form corrosive nitric acid, as well as... 

The revealed preference method is an indirect approach that is used in order to monetize use values. This method observes the real choice between money and the environmental goods. Methods often include observations of consumers or producers behaviour or actions, such as the hedonic price method and the production function method. The hedonic price method determines values from actual market transactions. These transactions are used to see how the price of a market commodity varies when a related environmental good changes, such as the effects of noise or air pollution on house prices. The production function method is used to estimate the value of the environmental effects on production. This method is suitable when consumption or production of a private good is affected by the environmental good. An example is the valuation of ground-level ozone levels by valuing the impact on the production of wheat or timber, which has market prices. The problem with the revealed preference method is that it does not contain all the individuals values that affect the WTP. 

Research dating back to the mid 1950 s has shown that volatile orgamc compounds (VOC s) photochemically react m the atmosphere and contribute to the formation of ground level ozone, a precursor to smog [1]. Medical studies have shown that human exposure to ozone can result in eye and smus tract irritation, and can lead to respiratory related illnesses [2]. Due to the unique and severe smog problems that affected many cities in the state of California, studies of the causes of ah pollution were initiated m the 1950 s [3]. Based on its findings, California formed the Motor Vehicle Pollution Control Board m 1960 to regulate pollution from automobiles. 

Ozone, O3, is an essential molecule in the ozone layer. It filters out some of the UV radiation that would otherwise destroy life on Earth. At ground level, ozone is a component in photochemical smog. Draw the Lewis structure for ozone, and indicate whether or not ozone is polar. Can ozone exist in resonance forms ... 

FoUowing are the chemical reactions for the production of ozone at ground level. Ozone can be formed when a mixture of and NO is exposed to sunhght. Given that this reaction is very slow at normal temperatures, it is not a problem until hot gases in the cylinders of automobiles internal combustion engines cause the foUowing more rapid reactions. 

Fiore, A. M., D. J. Jacob, J. A. Logan, and J. H. Yin, Long-Term Trends in Ground Level Ozone over the Contiguous United States, 1980-1995, / Geophys. Res., 103, 1471-1480(1998). 

Fuentes, J. D and T. F. Dann, Ground-Level Ozone in Eastern Canada Seasonal Variations, Trends, and Occurrences of High Concentrations, / Air Waste Manage. Assoc., 44, 1019-1026 (1994). 

Kasibhatla, P., W. L. Chameides, B. Duncan, M. Houyoux, C. Jang, R. Mathur, T. Odman, and A. Xiu, Impact of Inert Organic Nitrate Formation on Ground-Level Ozone in a Regional Air Quality Model Using the Carbon Bond Mechanism 4, Geophys. Res. Lett., 24, 3205-3208 (1997). 

Environmental Protection Agency Real-time images of ground-level ozone levels throughout the Midwest and the Northeast... 

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