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Ethers perfluorinated

Perfluorinated ethers and perfluorinated tertiary amines do not contribute to the formation of ground level ozone and are exempt from VOC regulations (32). The commercial compounds discussed above have an ozone depletion potential of zero because they do not contain either chlorine or bromine which take part in catalytic cycles that destroy stratospheric ozone (33). [Pg.298]

Uses. Besides polymerizing TFE to various types of high PTEE homopolymer, TEE is copolymerized with hexafluoropropylene (29), ethylene (30), perfluorinated ether (31), isobutylene (32), propylene (33), and in some cases it is used as a termonomer (34). It is used to prepare low molecular weight polyfluorocarbons (35) and carbonyl fluoride (36), as well as to form PTEE m situ on metal surfaces (37). Hexafluoropropylene [116-15-4] (38,39), perfluorinated ethers, and other oligomers are prepared from TEE. [Pg.349]

Peifluoioalkoxy (PFA) fluoiocaibon lesins aie designed to meet industry s needs in chemical, electrical, and mechanical appHcations. These melt processible copolymers contain a fluorocarbon backbone in the main chain and randomly distributed perfluorinated ether side chains ... [Pg.373]

Table 2.1 lists a number of dioxole monomers and indicates their ability to homopolymerize and/or copolymerize with TFE in CFC-113 solution. The copolymerization of dioxoles with chlorine in the 4 and 5 position of the dioxole ring further demonstrates the very high reactivity of this ring system. Thus an almost infinite number of dioxole polymers can be prepared with one or more comonomers in varying proportions. We have chosen to focus our present work on copolymers of TFE and PDD to preserve the outstanding thermal and chemical properties of perfluorinated polymers. At this point it should be noted that fully fluorinated ethers are nonbasic and effectively possess the same chemical inermess as fluorinated alkanes. Perfluorinated ether groups in polymers are even less reactive as a result of their inaccessibility to chemical reagents. [Pg.27]

The products of the electrochemical perfluorination of aliphatic or cyclic ethers are the corresponding perfluorinated ethers. Byproducts are perfluorinated ethers with shorter carbon chains, perfluoroalkanes, perfluorocarboxylic acid fluorides and oxygen difluoride. Cyclic perfluorinated ethers can be produced by electrochemical fluorination of alcohols,32 aliphatic carboxylic acids33 or of their acid halides34 containing not less than four carbon atoms in the chain. [Pg.311]

The largest proportion of TFE is used for the polymerization into a variety of PITH homopolymers. It is also used as comonomer in the copolymerization with hexaflu-oropropylene, ethylene, perfluorinated ether, and other monomers and also as a comonomer in a variety of terpolymers. Other uses of TFE are to prepare low-molecular-weight polyfluorocarbons, carbonyl fluoride oils, as well as to form PTFE in situ on metal surfaces,13 and in the synthesis of hexafluoropropylene, perfluorinated ethers, and other oligomers.14... [Pg.18]

Teflon (polytetrafluoroethylene) is a chemically inert polymer used to create nonstick frying pans. Polytetrafluoroethylene can be modified to form a coating, Gore-Tex, which allows the passage of water vapor, but not liquid water, and is used in many articles of clothing. Polymeric perfluorinated ethers are widely used as high performance oils and lubricants. [Pg.105]

An alternative reaction is that of C1F with C1N3 at 25°C or of C1F with NaN3 in a perfluorinated ether at 25°C. The boiling point lies in the range —10 to 0°C. It is more reactive than Cl2 and will react with either H20 or dilute NaOH. [Pg.170]

The low-temperature chlorination of FC(0)NF2 is also a convenient method for the synthesis of C12NF. Alternatively, FNCI2 can be obtained from CIF and CIN3 in perfluorinated ether. Irradiation of FNCI2 with a high-pressure Hg lamp leads to the formation of m-N2F2. [Pg.3081]

Formation of perfluorinated ethers by cobalt trifluoride is generally a low-yielding process, because of fragmentation and partial fluorination. However, incorporation into the substrate of electron-withdrawing polyfluoroalkyl groups moderates the fluorination and allows high yields to be obtained [78]. [Pg.33]

Chambers, R.D. Grievson, B. Drakesmith, F.G. Powell, R.L. Free radical chemistry. Part 5. A new approach to the synthesis of perfluorinated ethers. J. Fluorine Chem. 1985, 29, 323-339. [Pg.217]

It is worth of mentioning that the cross-coupling of 16 and acid derived from hexafluoropropene oxide trimer leads to clean formation of 18 in relatively high yield (Fig. 9.4). More data on the synthesis of five-membered perfluorinated ethers can be found in Chapter 4. [Pg.328]

Perfluorinated lactones are usually synthesized by selective hydrolysis of poly-fluorinated cyclic ethers. Since perfluorinated ethers are resistant to hydrolysis, usually cyclic ethers, containing CCI2 fragment are used as feedstock. Tiers was... [Pg.328]

As it was mentioned above, perfluorinated ethers are resistant toward hydrolysis, however, activated CF2 group can be converted into carbonyl using SO3 and boron catalyst.For example, both F-dihydrofurane 27 and F-dihydrothiophene 28 were converted into 29 using the reaction shown in Fig. 9.8. " ... [Pg.330]

Redistribution of the electron density in perfluorinated heterocycles leads to the signihcant increase in the basicity of the fluorine substituent, resulting in an unusual reactivity toward strong electrophiles. This effect makes possible reactions, which are virtually unknown for cyclic hydrocarbons, such as reactions of perfluorinated ethers or amines with strong Lewis (AICI3, SbFs, SO3) or protic acids. Short summaries on these reactions can be found in two reviews... [Pg.337]

The ability of perfluorinated ethers to react with anhydrous AICI3 at elevated temperatures was discovered by Tiers. While the reaction of alicychc perfluorinated ethers results in the cleavage with the formation of acyl chloride and chloro-fluoroalkanes, perfluorinated a-aUcyl tetrahydrofuranes undergo replacement of all three a-fluorines with the formation of cyclic a,a,a-trichloro derivatives. Later, this reaction was extensively studied by Abe (Fig. 9... [Pg.337]

This study is divided into two parts the first involves electron beam exposures on COj isolated in rare gas solids to investigate the role of an inert solvent on radiation chemistry further experiments were conducted on diazoketones mixed into polymers to investigate the role of reactive solvents. The second part of the study deals with electron beam exposure of fluorinated acrylates and perfluorinated ethers. These reveal that highly fluorinated acrylates when mixed with non-fluorinated acrylic monomers may be used to produce radiation cured films with a broad range of contact angles. [Pg.498]

Perfluormated oligoethers with the acetylacetonate group at the end of the polymer formed complexes 56 with nickel(I), which catalyzed ethylene oligomerization. The turnover number in the reaction reached 2460 in a perfluorinated ether-toluene two-phase system, and the catalyst, which was in the fluorine-containing phase, was readily separable [169]. [Pg.480]

Thanawala, S.K., Chaudhury, M.K. Surface modification of silicone elastomer using perfluorinated ether. Langmuir 16,1256-1260 (2000)... [Pg.141]

Synthesis copolymerization of perfluorinated ethylene monomer with SO2F containing perfluorinated ether monomer [88,91] m = 6 —12. Nafion 120 (DuPont) means 1200 g polymer per mole of H , there are Nafion 117, 115, 105, etc. [Pg.13]

Oligomerization of Ethene. The success of the SHOP prompted further research to find new solvents for similar applications. The perfluorinated ether solvent Hostinert 216 (Scheme 52) was conceived as a possible alternative since... [Pg.514]


See other pages where Ethers perfluorinated is mentioned: [Pg.296]    [Pg.304]    [Pg.563]    [Pg.253]    [Pg.168]    [Pg.312]    [Pg.313]    [Pg.294]    [Pg.114]    [Pg.251]    [Pg.1349]    [Pg.329]    [Pg.1348]    [Pg.495]    [Pg.503]    [Pg.503]    [Pg.141]    [Pg.499]    [Pg.281]    [Pg.273]    [Pg.563]    [Pg.515]   


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