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Ferf-Butyl methyl ether formation

Outline a reasonable mechanism for the formation of ferf-butyl methyl ether according to the preceding equation. [Pg.693]

In Table 9 the results of the preparation of (5)-cyanohydrins starting from both aldehydes and ketones with HCN and recombinant HbHNL as catalyst are summarized [9,29]. The reactions with HbHNL were performed normally in a biphasic system consisting of a concentrated aqueous enzyme solution and an organic solvent not miscible with water, e.g., ferf-butyl methyl ether. It must be noted that the reactions and optical yields in the HbHNL-catalyzed cyanohydrin formation (Table 9) were achieved by using the 10-fold higher amount of enzyme, in comparison to MeHNL-catalyzed reactions (Tables 7 and 8) (see notes to Tables 7 and 9). [Pg.330]

It was found possible to measure the kinetics of cleavage of protonated sec-butyl methyl ether 24 by following the disappearance of the methoxy doublet in the NMR spectrum with simultaneous formation of protonated methanol and ferf-butyl cation. The cleavage shows pseudo-first-order kinetics. Presumably, the rate-determining step is the formation of sec-butyl cation followed by rapid rearrangement to the more stable ferf-butyl cation... [Pg.321]

AI3-00040, see Cyclohexanol AI3-00041, see Cyclohexanone AI3-00045, see Diacetone alcohol AI3-00046, see Isophorone AI3-00050, see 1,4-Dichlorobenzene AI3-00052, see Trichloroethylene AI3-00053, see 1,2-Dichlorobenzene AI3-00054, see Acrylonitrile AI3-00072, see Hydroquinone AI3-00075, see p-Chloro-rrr-cresol AI3-00078, see 2,4-Dichlorophenol AI3-00085, see 1-Naphthylamine AI3-00100, see Nitroethane AI3-00105, see Anthracene AI3-00109, see 2-Nitropropane AI3-00111, see Nitromethane AI3-00118, see ferf-Butylbenzene AI3-00119, see Butylbenzene AI3-00121, see sec-Butylbenzene AI3-00124, see 4-Aminobiphenyl AI3-00128, see Acenaphthene AI3-00134, see Pentachlorophenol AI3-00137, see 2-Methylphenol AI3-00140, see Benzidine AI3-00142, see 2,4,6-Trichlorophenol AI3-00150, see 4-Methylphenol AI3-00154, see 4,6-Dinitro-o-cresol AI3-00262, see Dimethyl phthalate AI3-00278, see Naphthalene AI3-00283, see Di-rj-butyl phthalate AI3-00327, see Acetonitrile AI3-00329, see Diethyl phthalate AI3-00399, see Tributyl phosphate AI3-00404, see Ethyl acetate AI3-00405, see 1-Butanol AI3-00406, see Butyl acetate AI3-00407, see Ethyl formate AI3-00408, see Methyl formate AI3-00409, see Methanol AI3-00520, see Tri-ocresyl phosphate AI3-00576, see Isoamyl acetate AI3-00633, see Hexachloroethane AI3-00635, see 4-Nitrobiphenyl AI3-00698, see IV-Nitrosodiphenylamine AI3-00710, see p-Phenylenediamine AI3-00749, see Phenyl ether AI3-00790, see Phenanthrene AI3-00808, see Benzene AI3-00867, see Chrysene AI3-00987, see Thiram AI3-01021, see 4-Chlorophenyl phenyl ether AI3-01055, see 1.4-Dioxane AI3-01171, see Furfuryl alcohol AI3-01229, see 4-Methyl-2-pentanone AI3-01230, see 2-Heptanone AI3-01231, see Morpholine AI3-01236, see 2-Ethoxyethanol AI3-01238, see Acetone AI3-01239, see Nitrobenzene AI3-01240, see I idine AI3-01256, see Decahydronaphthalene AI3-01288, see ferf-Butyl alcohol AI3-01445, see Bis(2-chloroethoxy)methane AI3-01501, see 2,4-Toluene diisocyanate AI3-01506, see p,p -DDT AI3-01535, see 2,4-Dinitrophenol AI3-01537, see 2-Chloronaphthalene... [Pg.1457]

Degradation of methyl terf-butyl ether by bifunctional aluminum in the presence of oxygen was investigated by Lien and Wilkin (2002). Bifunctional aluminum was synthesized by sulfating aluminum metal with sulfuric acid. When the initial methyl terf-butyl ether concentration was 14.4 mg/L, 90% of methyl ferf-butyl ether degraded within 24 h forming acetone, methyl acetate, tert-hniyX alcohol, and ferf-butyl formate. Carbon disulfide was tentatively identified as a reaction product by GC/MS. Product yields were 27.6% for acetone, 18.4% for methyl acetate, 21% for tert-hniyX alcohol, and 6.1% ferf-butyl formate. When the initial concentration of methyl tert-butyl ether was reduced to 1.4 mg/L, 99.5% of methyl terCbutyl ether reacted. Yields of acetone, methyl acetate, and /erf-butyl alcohol were 54.7,17.2, and 13.2, respectively. [Pg.1595]

Church, C.D., Pankow, J.F., and Tratnyek, P.G. Hydrolysis of ferf-butyl formate kinetics, products, and implications for the environmental impact of methyl ferf-butyl ether. Environ. Toxicol. Chem., 18(12) 2789-2796, 1999. [Pg.1644]

The formal isomerization enthalpies of methyl n-butyl ether to methyl terf-butyl ether and of di-n-butyl ether to n-butyl ferf-butyl ether are about —24kJmoU (Iq) and —26.5 kJmol (g), respectively. From these, and the experimental enthalpy of formation of di-ferf-butyl peroxide, the enthalpies of formation of di-n-butyl peroxide are ca —333 kJmol (Iq) and —288 kJmol (g), wildly divergent from the reported values. [Pg.151]

A selective, sensitive, and rapid hydrophilic interaction liquid chromatography with electrospray ionization tandem mass spectrometry was developed for the determination of donepezil in human plasma [32], Donepezil was twice extracted from human plasma using methyl-ferf-butyl ether at basic pH. The analytes were separated on an Atlantis HILIC Silica column with the mobile phase of acetonitrile ammonium formate (50 mM, pH 4.0) (85 15, v/v) and detected by tandem mass spectrometry in the selective reaction monitoring mode. The calibration curve was linear (r = 0.9994) over the concentration range of 0.10-50.0 ng/ ml and the lower limit of quantification was 0.1 ng/ml using 200 /d plasma sample. The CV and relative error for intra- and inter-assay at four quality control levels were 2.7% to 10.5% and —10.0% to 0.0%, respectively. There was no matrix effect for donepezil and cisapride. The present method was successfully applied to the pharmacokinetic study of donepezil after oral dose of donepezil hydrochloride (10 mg tablet) to male healthy volunteers. [Pg.141]

In practice, short-chain alkanes and alkenes are normally used as feedstock for shape-selective catalytic formation of isooctanes at relatively low temperatures. Until the 1980s, lead alkyls (Section 18.1) were added to most automotive fuels to help suppress engine knock, but they have been phased out in North America because of the chronic toxicity of lead and lead compounds. The most commonly used nonlead antiknock additive is now methyl ferf-butyl ether [MTBE CH30C(CH3)3], which is made by the reaction of methanol with 2-methylpropene, (CH3)2C=CH2 (see Section 7.4). The latter is obtained by catalytic cracking of petroleum fractions to give 1-butene, which is then shape-selectively isomerized on zeolitic catalysts. [Pg.140]

Olah et al. reported the triflic acid-catalyzed isobutene-iso-butylene alkylation, modified with trifluoroacetic acid (TEA) or water. They found that the best alkylation conditions were at an acid strength of about Ho = —10.7, giving a calculated research octane number (RON) of 89.1 (TfOH/TFA) and 91.3 (TfOH/HzO). Triflic acid-modified zeolites can be used for the gas phase synthesis of methyl ferf-butyl ether (MTBE), and the mechanism of activity enhancement by triflic acid modification appears to be related to the formation of extra-lattice Al rather than the direct presence of triflic acid. A thermally stable solid catalyst prepared from amorphous silica gel and triflic acid has also been reported. The obtained material was found to be an active catalyst in the alkylation of isobutylene with w-butenes to yield high-octane gasoline components. A similar study has been carried out with triflic acid-functionalized mesoporous Zr-TMS catalysts. Triflic acid-catalyzed carbonylation, direct coupling reactions, and formylation of toluene have also been reported. Triflic acid also promotes transalkylation and adaman-tylation of arenes in ionic liquids. Triflic acid-mediated reactions of methylenecyclopropanes with nitriles have also been investigated to provide [3 + 2] cycloaddition products as well as Ritter products. Triflic acid also catalyzes cyclization of unsaturated alcohols to cyclic ethers. ... [Pg.579]


See other pages where Ferf-Butyl methyl ether formation is mentioned: [Pg.180]    [Pg.178]    [Pg.24]    [Pg.26]    [Pg.1521]    [Pg.600]    [Pg.378]    [Pg.700]    [Pg.192]    [Pg.311]    [Pg.59]    [Pg.203]    [Pg.88]    [Pg.63]   
See also in sourсe #XX -- [ Pg.378 ]




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Butyl ether

Butyl formate

Butyl methyl ether

Butyl-methyl

Ethers formation

Ferf-Butyl ethers

Ferf-Butyl formate

Methyl ferf-butyl ether

Methyl formate

Methyl formate, formation

Methyl formation

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