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Feedstock atomization

A better AE value (59wt%) is obtained with the coproduction of ethylene glycol from the methanolysis of ethylene carbonate (entry 2). The AE value is higher when water is coproduced (83 wt %, entries 4—5). The use of urea as a feedstock (entry 3) may also lead to AE = 83 wt%, by coupling the urea synthesis equation. The complete use of feedstock atoms (AE = 100 wl%) has been demonstrated commercially for cyclic carbonate synthesis, but as yet no real case has been reported for unstrained ethers (entry 6). [Pg.173]

Total (15) reports that operation of their pilot plant is not satisfactory for feedstocks with a viscosity greater than 80 cSt at 100 C. They state that thermal shock simulation and feedstock atomizing and evaporation are unsatisfactory in their laboratory scale unit. [Pg.315]

Song and co-workers developed a set of exercises that allows students the opportunity to analyze a series of reactions and judge them based on choice of feedstock, atom economy, reaction conditions, environmental exposure, and resource conservation (77). One example asks the students to consider the following two series of reactions and then decide how to synthesize eight moles of aluminum hydroxide (Figure 1). [Pg.82]

Liquid feedstock atomized and sprayed into the flame... [Pg.22]

A considerable amount of carbon is formed in the reactor in an arc process, but this can be gready reduced by using an auxiUary gas as a heat carrier. Hydrogen is a most suitable vehicle because of its abiUty to dissociate into very mobile reactive atoms. This type of processing is referred to as a plasma process and it has been developed to industrial scale, eg, the Hoechst WLP process. A very important feature of a plasma process is its abiUty to produce acetylene from heavy feedstocks (even from cmde oil), without the excessive carbon formation of a straight arc process. The speed of mixing plasma and feedstock is critical (6). [Pg.386]

Process Technology Evolution. Maleic anhydride was first commercially produced in the early 1930s by the vapor-phase oxidation of benzene [71-43-2]. The use of benzene as a feedstock for the production of maleic anhydride was dominant in the world market well into the 1980s. Several processes have been used for the production of maleic anhydride from benzene with the most common one from Scientific Design. Small amounts of maleic acid are produced as a by-product in production of phthaHc anhydride [85-44-9]. This can be converted to either maleic anhydride or fumaric acid. Benzene, although easily oxidized to maleic anhydride with high selectivity, is an inherently inefficient feedstock since two excess carbon atoms are present in the raw material. Various compounds have been evaluated as raw material substitutes for benzene in production of maleic anhydride. Fixed- and fluid-bed processes for production of maleic anhydride from the butenes present in mixed streams have been practiced commercially. None of these... [Pg.453]

The 0x0 process is employed to produce higher alcohols from linear and branched higher olefins. Using a catalyst that is highly selective for hydroformylation of linear olefins at the terminal carbon atom. Shell converts olefins from the Shell higher olefin process (SHOP) to alcohols. This results in a product that is up to 75—85% linear when a linear feedstock is employed. Other 0x0 processes, such as those employed by ICI, Exxon, and BASE (all in Europe), produce oxo-alcohols from a-olefin feedstocks such alcohols have a linearity of about 60%. Enichem, on the other hand, produces... [Pg.441]

Naphthalene (qv) from coal tar continued to be the feedstock of choice ia both the United States and Germany until the late 1950s, when a shortage of naphthalene coupled with the availabihty of xylenes from a burgeoning petrochemical industry forced many companies to use o-xylene [95-47-6] (8). Air oxidation of 90% pure o-xylene to phthaUc anhydride was commercialized ia 1946 (9,10). An advantage of o-xylene is the theoretical yield to phthaUc anhydride of 1.395 kg/kg. With naphthalene, two of the ten carbon atoms are lost to carbon oxide formation and at most a 1.157-kg/kg yield is possible. Although both are suitable feedstocks, o-xylene is overwhelmingly favored. Coal-tar naphthalene is used ia some cases, eg, where it is readily available from coke operations ia steel mills (see Steel). Naphthalene can be produced by hydrodealkylation of substituted naphthalenes from refinery operations (8), but no refinery-produced napthalene is used as feedstock. Alkyl naphthalenes can be converted directiy to phthaUc anhydride, but at low yields (11,12). [Pg.482]

Steam Reforming Processes. In the steam reforming process, light hydrocarbon feedstocks (qv), such as natural gas, Hquefied petroleum gas, and naphtha, or in some cases heavier distillate oils are purified of sulfur compounds (see Sulfurremoval and recovery). These then react with steam in the presence of a nickel-containing catalyst to produce a mixture of hydrogen, methane, and carbon oxides. Essentially total decomposition of compounds containing more than one carbon atom per molecule is obtained (see Ammonia Hydrogen Petroleum). [Pg.368]

The Stratford Engineering Company s (Kansas City, Missouri) continuous SO organic mist sulfonation uses a high speed atomizing rotor to horizontally disperse the organic feedstock stream impinging on the reactor walls in the presence of SO gas to effect sulfonation of petroleum feedstocks (290). [Pg.90]

Methane, chlorine, and recycled chloromethanes are fed to a tubular reactor at a reactor temperature of 490—530°C to yield all four chlorinated methane derivatives (14). Similarly, chlorination of ethane produces ethyl chloride and higher chlorinated ethanes. The process is employed commercially to produce l,l,l-trichloroethane. l,l,l-Trichloroethane is also produced via chlorination of 1,1-dichloroethane with l,l,2-trichloroethane as a coproduct (15). Hexachlorocyclopentadiene is formed by a complex series of chlorination, cyclization, and dechlorination reactions. First, substitutive chlorination of pentanes is carried out by either photochemical or thermal methods to give a product with 6—7 atoms of chlorine per mole of pentane. The polychloropentane product mixed with excess chlorine is then passed through a porous bed of Fuller s earth or silica at 350—500°C to give hexachlorocyclopentadiene. Cyclopentadiene is another possible feedstock for the production of hexachlorocyclopentadiene. [Pg.508]

Hydrotreating reduces the sulfur content of all the products. With hydrotreated feeds, more of the feed sulfur goes to coke and heavy liquid products. The same sulfur atoms that were converted to H S in the FCC process are also being removed first in the hydrotreating process. The remaining sulfur compounds are harder to remove. The heavier and more aromatic the feedstock, the greater the level of sulfur in the coke (Table 2-7). [Pg.59]

Telomerisation is an important, atom efficient reaction, which generates functionalised dienes from 1,3-diene feedstocks. The reaction, which typically employs a palladium based catalyst, comprises coupling two molecnles of a conjugated 1,3-diene... [Pg.118]

It is clear from the mass balance that C02 is inevitably produced and that for every mole of product, half a mole of C02 must be produced. In terms of a carbon efficiency (defined as the amount of carbon that ends up in product), this means a 67% carbon efficiency. This is simply the result of the wrong ratio of the atoms (C and H) in the feedstock. [Pg.319]


See other pages where Feedstock atomization is mentioned: [Pg.315]    [Pg.315]    [Pg.236]    [Pg.520]    [Pg.402]    [Pg.273]    [Pg.315]    [Pg.315]    [Pg.236]    [Pg.520]    [Pg.402]    [Pg.273]    [Pg.440]    [Pg.440]    [Pg.457]    [Pg.458]    [Pg.422]    [Pg.249]    [Pg.15]    [Pg.335]    [Pg.544]    [Pg.545]    [Pg.91]    [Pg.1323]    [Pg.54]    [Pg.649]    [Pg.31]    [Pg.156]    [Pg.35]    [Pg.60]    [Pg.273]    [Pg.167]    [Pg.40]    [Pg.86]    [Pg.606]    [Pg.225]    [Pg.30]    [Pg.263]    [Pg.22]    [Pg.45]    [Pg.50]    [Pg.101]   
See also in sourсe #XX -- [ Pg.310 , Pg.312 ]




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