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Features of Flow Analysis

In view of the wide acceptance of flow analysis [10] and the increasing availability of flow-based procedures for real sample analysis [11], the situation hinted at in Fig. 1.2 (upper) has undergone a significant improvement, approaching that shown in Fig. 1.2 (lower), which depicts a laboratory exploiting flow analysis for in vivo assays at the beginning of the third millennium. Nowadays, modern spectropkotometric flow-based techniques are a competitive alternative to other modem analytical techniques and are also amenable to miniaturisation [12]. [Pg.5]

Flow analysis has often been referred to as an analytical technique, but this is not strictly true, as it is an advanced procedure for carrying out automated chemical assays. The cornerstone features inherent to flow injection analysis, namely sample insertion, controlled dispersion and reproducible timing [5], are considered here in a broader context, in order to encompass the different modes of flow analysers. [Pg.5]

A 5—500 pi aliquot of the aqueous sample is precisely selected (Fig. 1.3a) and introduced into the flow manifold. This is especially relevant for the analysis of biological fluids, cell tissues, blood sera, dew and other volume-limited samples, as well as for in vivo assays. Moreover, sampling strategies relying on mini-probes become more practical. In spite of the low sample volume, reliable results are obtained even for very low analyte concentrations. [Pg.5]

The characteristic mass (analyte mass yielding 0.01 absorbance), often considered in atomic absorption spectrometry and related techniques as an indicator of sensitivity, is also relevant in the context of flow-based analytical procedures involving UV—visible spectrophotometry [7]. [Pg.5]

The selected sample aliquot is inserted into a flow manifold (Fig. 1.3b) and pushed forwards by the carrier/wash stream flowing through narrow-bore (typically 0.3—1.0 mm i.d.) tubing. During sample handling inside the analytical path, there is no physical contact between the sample and the external environment (and vice versa). Analyte losses leading to biased results and/or to indoor environmental pollution are therefore [Pg.5]


A common feature of flow analysis is that during sample transport toward the detector, the combined effects of dilution and dispersion decrease the sample concentration, and the extent of these processes is very important for system design. Dilution occurs instantly at every confluence point due to mixing of the sample with the confluent stream. Under ideal mixing conditions, the concentration C of a chemical species in a fluid slice immediately before a confluence point is modified to C according to... [Pg.1254]

McKelvie, I. D. Cardwell, T. J. Cattrall, R. W. A Microconduit Flow Injection Analysis Demonstration Using a 35-mm Slide Projector, /. Chem. Educ. 1990, 67, 262-263. Directions are provided for constructing a small-scale FIA system that can be used to demonstrate the features of flow injection analysis. For another example see Grudpan, K. Thanasarn, T. Overhead Projector Injection Analysis, Anal. Proc. 1993, 30, 10-12. [Pg.660]

The HAZOP analysis technique uses a systematic process to (1) identify possible deviations from normal operations and (2) ensure that safeguards are in place to help prevent accidents. The HAZOP uses special adjectives (such as speed, flow, pressure, etc. see table 5.5) combined with process conditions (such as more, less, no, etc. see table 5.6) to systematically consider all credible deviations from normal conditions. The adjectives, called guide words, are a unique feature of HAZOP analysis. [Pg.91]

In order to illustrate the main features of the analysis of turbulent flow, attention will be restricted to two-dimensional boundary layer flows and to axially symmetric pipe flows. It will also be assumed that the fluid properties are constant and that the mean flow is steady. [Pg.227]

A unique characteristic of flow analysis is the low susceptibility to instrumental drift, and this is a consequence of considering the transient signals as the basis for measurement [20]. This is evident in Fig. 1.5, where recorded peak heights (and areas) are maintained regardless of the pronounced baseline drift. This feature is especially relevant in process analysis where continuous monitoring of the same environment is usually required. [Pg.9]

In the past, some features, such as turbulent mixing and the presence of air bubbles, were considered to be a problem due to inherent technological challenges but are now useful in certain situations [159]. In view of the progress of flow analysis one can predict that future flow analysers will be very different from those in current use and emerging technologies may well allow old ideas to be harnessed in new analyser designs. [Pg.33]

In the next sections will be described the main features and characteristics of flow analysis methodologies proposed for the determination of AA. [Pg.300]

An additional feature of ELECTRAS is a module which provides an introduction to various data analysis techniques One part of this module provides a typical work flow for data analysis. It explains the important steps when conducting a data analysis and describes the output of the data analysis methods. The second part gives a description of the methods offered. This modvJe can be used both as a guideline for novice users and as a reference for experts. [Pg.452]

The quasi-one-dimensional model of flow in a heated micro-channel makes it possible to describe the fundamental features of two-phase capillary flow due to the heating and evaporation of the liquid. The approach developed allows one to estimate the effects of capillary, inertia, frictional and gravity forces on the shape of the interface surface, as well as the on velocity and temperature distributions. The results of the numerical solution of the system of one-dimensional mass, momentum, and energy conservation equations, and a detailed analysis of the hydrodynamic and thermal characteristic of the flow in heated capillary with evaporative interface surface have been carried out. [Pg.374]

Since the middle of the 1990s, another computation method, direct simulation Monte Carlo (DSMC), has been employed in analysis of ultra-thin film gas lubrication problems [13-15]. DSMC is a particle-based simulation scheme suitable to treat rarefied gas flow problems. It was introduced by Bird [16] in the 1970s. It has been proven that a DSMC solution is an equivalent solution of the Boltzmann equation, and the method has been effectively used to solve gas flow problems in aerospace engineering. However, a disadvantageous feature of DSMC is heavy time consumption in computing, compared with the approach by solving the slip-flow or F-K models. This limits its application to two- or three-dimensional gas flow problems in microscale. In the... [Pg.96]

Wilson et al. [662-665] have described various prototype systems for total organic analysis devices. It has proved technically feasible to obtain UV, IR, NMR and MS spectra (together with atomic composition based on accurate mass determination) following RPLC separation. The fully integrated approach offers the benefit that one chromatographic run is required, thus ensuring that all of the spectrometers observe the same separation. Such multiple hyphenations might favour the analysis of complex mixtures for both confirmation of identity and structure determination (should this represent a cost-effective approach). Table 7.72 illustrates the main features of on-flow multiple LC hyphenation. [Pg.522]

Since the flowing-afterglow method is quite well established, a brief review of the basic features of this technique should be sufficient. The experiments of Gougousi et al.46 on H3 recombination and those of Adams et al.18 and of Smith and Spanel24 used nearly the same experimental method, but there are significant differences in the data analysis and in the interpretation of the results. [Pg.66]


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