Extractive distillation of butadiene

The principal direct appHcation of furfural is as a selective solvent. It is used for separating saturated from unsaturated compounds in petroleum refining, for the extractive distillation of butadiene and other hydrocarbons in the manufacture of synthetic mbber and for the production of... 

Furfural is obtained commercially by mealing pentosan-rich ugricullural residues (corncobs, oat hulls, cottonseed hulls, hagasse. rice hulls) with a dilute acid and removing the furfural by steam distillation. Major industrial uses of furfuraldehyde include (1) the production of t urnns and tetrahydrofurans where the compound is an intermediate (2) Ihc solvent refining of petroleum and rosin products (3) the solvent binding of bonded phenolic products and (4) the extractive distillation of butadiene from other C4 hydrocarbons. 

There are a dozen different ways to handle the C4 stream in a petrochemical plant if you follow all the combinations possible in Figure 6-2. Simple fractionation wont do it because the boiling temperatures are so close together. Generally the first step is to remove the butadienes by extractive distillation, of the kind shown in Chapter 3. 

Today, more butadiene (BD) is produced from butene (another C4) through steam cracking of naphtha gas oil (a byproduct of ethylene/propylene production). Through extractive distillation of this C4 cracker stream, the butadiene is obtained. Com-... 

Today more butadiene is produced from butene (another C4) through steam cracking of naphtha gas oil from ethylene/propylene production (it is a byproduct of eth-ylene/propylene production). Through extractive distillation of this C4 cracker stream, the butadiene is obtained. Commonly the yield achieved forBD is dependent on the quality of the feedstocks used for ethylene production. Usually the heavier the feedstock, the greater the BD production. Reportedly, the lighU feedstock only yields about one-fifth the yield of butadiene compared to the heavy feedstock. 

Butadiene Separation. Solvent extraction is used in the separation of butadiene (qv) [106-99-0] from other C-4 hydrocarbons in the manufacture of synthetic mbber. The butadiene is produced by catalytic dehydrogenation of butylene and the Hquid product is then extracted using an aqueous cuprammonium acetate solution with which the butadiene reacts to form a complex. Butadiene is then recovered by stripping from the extract. Distillation is a competing process. 

Economic considerations in the 1990s favor recovering butadiene from by-products in the manufacture of ethylene. Butadiene is a by-product in the C4 streams from the cracking process. Depending on the feedstocks used in the production of ethylene, the yield of butadiene varies. Eor use in polymerization, the butadiene must be purified to 994-%. Cmde butadiene is separated from C and C components by distillation. Separation of butadiene from other C constituents is accomplished by salt complexing/solvent extraction. Among the solvents used commercially are acetonitrile, dimethyl acetamide, dimethylform amide, and /V-methylpyrrolidinone (13). Based on the available cmde C streams, the worldwide forecasted production is as follows 1995, 6,712,000 1996, 6,939,000 1997, 7,166,000 and 1998, 7,483,000 metric tons (14). As of January 1996, the 1995 actual total was 6,637,000 t. 

Separation and Purification. Separation and purification of butadiene from other components is dominated commercially by the extractive distillation process. The most commonly used solvents are acetonitrile and dimethylformarnide. Dimethylacetamide, furfural, and... 

Fig. 3. Separation and purification of butadiene A, first extraction distillation tower B, solvent stripper C, second extraction distillation tower D, topping...

The C4 stream from steam crackers, unlike its counterpart from a refinery, contains about 45% butadiene by weight. Steam crackers that process significant amounts of Hquid feedstocks have satellite faciUties to recover butadiene from the stream. Conventional distillation techniques are not feasible because the relative volatihty of the chemicals in this stream is very close. Butadiene and butylenes are separated by extractive distillation using polar solvents. 

A selection of industrial appHcations of extractive distillation includes (/) the separation of the / -butane—butadiene azeotrope in mixed C -hydrocarbon streams using furfural [98-01-17, as the solvent (36) (2) the dehydration of ethanol using ethylene glycol [107-21-1] (37—39) (J)... 

The principal components of the cut are butene-1, butene-2, isobutylene and butadiene-1,3. Methyl, ethyl, and vinyl acetylenes, butane and butadiene-1,2 are present in small quantities. Butadiene is recovered from the C4 fraction by extraction with cuprous ammonium acetate (CAA) solution, or by extractive distillation with aqueous acetonitrile (ACN). The former process is a liquid-liquid separation, and the latter a vapor-liquid separation. Both take advantage of differences in structure and reactivity of the various C4 components to bring about the desired separation. 

Acetonitrile serves to greatly enlarge the spread of relative volatilities so that reasonably sized distillation equipment can be used to separate butadiene from the other components in the C4 fraction. The polar ACN acts as a very heavy component and is separated from the product without much difficulty.The feed stream is carefully hydrogenated to reduce the acetylene level rerun, and then fed to the single stage extractive distillation unit. Feed enters near the middle of the extractive distillation tower, while (lean) aqueous ACN is added near but not at the top. Butenes and butanes go overhead as distillate, with some being refluxed to the tower and the rest water washed for removal of entrained ACN. 

Tower bottoms-ACN, butadiene, with some butenes and acetylenes - are fed to a recovery/stripping column. The hydrocarbons are taken overhead and then rerun to meet product specifications. The stripping column bottoms, (ACN) is then remrned near the top of the extractive distillation tower. A small slipstream goes to the ACN recovery tower, where solvent is also recovered from the water wash streams. 

CAA [Cuprous ammonium acetate] A general process for separating alkenes, di-alkenes, and alkynes from each other by extraction of their cuprous complexes from aqueous cuprous ammonium acetate into an organic solvent. Exxon used it for separating C4 fractions containing low concentrations of butadiene. The liquid-liquid extraction processes for butadiene have all been replaced by extractive distillation processes. 

Distex A family of extractive distillation processes used in the petroleum industry from 1940. In one such process, furfural is used as the extracting agent for separating butadiene from other C4 hydrocarbons. 

When butadiene is produced in olefins plants or in refinery crackers, they come mixed with relatively large volumes of the other C4 family. Sometimes the other C4S need not be separated from each other, for example if they are going to be used for allcylation plant feed. In that case, the butadiene can be separated from the other C4S by extractive distillation. This process uses a solvent that will preferentially dissolve butadiene, ignoring the other components in the stream. 

The C4 stream is fed to the middle of a fractionator, and a high boiling point solvent is fed at the top. The solvent, as it works its way down, strips out the butadiene as the C4 vapor works its way up the column. The solvent and butadiene come out the bottom and can easily be split in a second column. Two popular high boiling point solvents are N-methylpyrrolidone (NMP) and Dimethylformamide (DMF). The chapter on benzene has more details on the extractive distillation process. 

The source of these compounds is varied. The butanes are found naturally in crude oils and natural gas. They, plus the olefins, are products of various refinery processes and of olefins plants. They are separated by fractionation, except for butadiene and isobutylene, which are sometimes recovered by extractive distillation. They all vaporize at room temperature, so they are handled in closed, pressurized systems.. 

Extractive distillation is used to remove butadiene from a C4 stream fractionation can be used to separate out butene-1 adsorption is also sometimes used to separate out butene-1 polymerization is sometimes used to pull out the isobutylene dehydrogenation can be used to convert some of the butylenes and normal butane to butadiene and alkylation is used to convert the butylenes to alkylate. 

The straight-chain 1- and 2-butenes can be converted into more butadiene when they are preheated in a furnace, mixed with steam as a diluent to minimize carbon formation, and passed through a reactor with a bed of iron oxide pellets. The material is cooled and purified by fractional distillation or extraction with solvents such as furfural, acetonitrile, dimethylformamide (DMF), and N-methylpyrrolidone (NMP). The conjugated n system of butadiene is attracted to these polar solvents more than the other C4 compounds. Extractive distillation is used, where the C4 compounds other than butadiene are distilled while the butadiene is complexed with the solvent. The solvent and butadiene pass from the bottom of the column and are then separated by distillation. 

The usual procedures of fractional, azeotropic, or extractive distillation under inert gases, crystallization, sublimation, and column chromatography, must be carried out very carefully. For liquid, water-insoluble monomers (e.g., styrene, Example 3-1), it is recommended that phenols or amines which may be present as stabilizers, should first be removed by shaking with dilute alkali or acid, respectively the relatively high volatility of many of these kinds of stabilizers often makes it difficult to achieve their complete removal by distillation. Gaseous monomers (e.g., lower olefins, butadiene, ethylene oxide) can be purified and stored over molecular sieves in order to remove, for example, water or CO2. 

Two important extractive distillation processes were placed in commercial operation during World War II the recovery of butadiene from a C4 fraction using furfural as the entrainer (7, 22) and the segregation of toluene from petroleum fractions by means of phenol (14-16). 

Because of their very similar boiling points and azeotrope formation, the components of the C4 fraction cannot be separated by distillation. Instead, other physical and chemical methods must be used. 1,3-Butadiene is recovered by complex formation or by extractive distillation.143-146 Since the reactivity of isobutylene is higher than that of n-butenes, it is separated next by chemical transformations. It is converted with water or methyl alcohol to form, respectively, tert-butyl alcohol and tert-butyl methyl ether, or by oligomerization and polymerization. The remaining n-butenes may be isomerized to yield additional isobutylene. Alternatively, 1-butene in the butadiene-free C4 fraction is isomerized to 2-butenes. The difference between the boiling points of 2-butenes and isobutylene is sufficient to separate them by distillation. n-Butenes and butane may also be separated by extractive distillation.147... 

---