Heavy component

Component Heavy raw acid phase Neutralized product... 

Revision Correction made to Degree of Amide Substitution and Total Galacturonic Acid in the Pectin Component Heavy Metals (as Pb) specification and determination deleted. 

Insl-Thane Polyurethane. [Insl-X Prods.] One-component heavy-duty polyurethane. 

The component (Heavy Load) handling procedure guidelines will require the owner-operator to establish the safe load path and perform special handling component inspections prior to lift. 

Chlorine and bromine components, heavy metals and various types of fillers can be identified in plastics, by means of a number of technologies being developed for identification of plastics in post-consumer waste. 

The example of tangential pinch for four-component mixture is quasisharp separation of azeotropic mixture acetone (l)-benzene (2)-chloroform (3)-toluol (4) of composition Xf (0,350 0,250 0,150 0,250) at intermediate split 1,3(2) 2,4(3) (admixture components heavy and light key are in brackets correspondingly) at the following composition the products xd (0,699 0,001 0,300,0) and xb (0 0,500 10 0,500). The same top product composition, as in the previous example (Fig. 5.18b) of separation of three-component mixture in the top section, is accepted for convenience of analysis. In this case, the boundary elements of top section trajectory bundle, located in face 1-2-3, completely coincides with top section trajectory bundle at separation of previously mentioned three-component mixture. 

T and K are the triple (L-G-S) and critical (L = G) points of pure components. Heavy lines are the composition of Uquid phases in monovariant equilibria L-G-S dot-dashed line is the critical curves L = G (originated in Kh2o)> solid lines are the composition of hquid phases in isobaric cross-sections of two-phase equilibrium L-G thin lines are the tie-lines. 

If the light and heavy key components form an azeotrope, then something more sophisticated than simple distillation is required. The first option to consider when separating an azeotrope is exploiting change in azeotropic composition with pressure. If the composition of the azeotrope is sensitive to pressure and it is possible to operate the distillation over a range of pressures without any material decomposition occurring, then this property can be used to... 

Ideally, the K value for the light key component in the phase separation should be greater than 10, and at the same time, the K value for the heavy key should be less than 0.1. Having such circumstances leads to a good separation in a single stage. However, use of phase separators might still be effective in the flowsheet if the K values for the key components are not so extreme. Under such circumstances a more crude separation must be accepted. 

Assuming a sharp separation with only the light key and lighter-than-light key components in the overheads and only the heavy key... 

Because only light key and lighter components go to the distillate and heavy key and heavier components go to the bottoms, Eq. (5.7) can be written in terms of the molar flow rate of each component in the feed ... 

A widening of the temperature differences across columns, since light nonkey components cause a decrease in condenser temperature and heavy nonkey components cause an increase in the reboiler temperature. 

The complexity of petroleum products raises the question of sample validity is the sample representative of the total flow The problem becomes that much more difficult when dealing with samples of heavy materials or samples coming from separations. The diverse chemical families in a petroleum cut can have very different physical characteristics and the homogeneous nature of the cut is often due to the delicate equilibrium between its components. The equilibrium can be upset by extraction or by addition of certain materials as in the case of the precipitation of asphaltenes by light paraffins. 

This method is reserved for heavy fractions. The distillation takes place at low pressure from 1 to 50 mmHg. The results are most often converted into equivalent atmospheric temperatures by using a standard relation that neglects the chemical nature of the components ... 

Hexane is an easy example. The variations in acentric factors are much more pronounced for heavy polar or polarizable components. It comes as no surprise that the values reported from different sources are not identical. 

In the 1970 s, heavy fuel came mainly from atmospheric distillation residue. Nowadays a very large proportion of this product is vacuum distilled and the distillate obtained is fed to conversion units such as catalytic cracking, visbreaking and cokers. These produce lighter products —gas and gasoline— but also very heavy components, that are viscous and have high contaminant levels, that are subsequently incorporated in the fuels. 

The vapor pressure of a crude oil at the wellhead can reach 20 bar. If it were necessary to store and transport it under these conditions, heavy walled equipment would be required. For that, the pressure is reduced (< 1 bar) by separating the high vapor pressure components using a series of pressure reductions (from one to four flash stages) in equipment called separators , which are in fact simple vessels that allow the separation of the two liquid and vapor phases formed downstream of the pressure reduction point. The different components distribute themselves in the two phases in accordance with equilibrium relationships. 

We cite isomerization of Cs-Ce paraffinic cuts, aliphatic alkylation making isoparaffinic gasoline from C3-C5 olefins and isobutane, and etherification of C4-C5 olefins with the C1-C2 alcohols. This type of refinery can need more hydrogen than is available from naphtha reforming. Flexibility is greatly improved over the simple conventional refinery. Nonetheless some products are not eliminated, for example, the heavy fuel of marginal quality, and the conversion product qualities may not be adequate, even after severe treatment, to meet certain specifications such as the gasoline octane number, diesel cetane number, and allowable levels of certain components. 

Gas is produced to surface separators which are used to extract the heavier ends of the mixture (typically the components). The dry gas is then compressed and reinjected into the reservoir to maintain the pressure above the dew point. As the recycling progresses the reservoir composition becomes leaner (less heavy components), until eventually it is not economic to separate and compress the dry gas, at which point the reservoir pressure is blown down as for a wet gas reservoir. The sales profile for a recycling scheme consists of early sales of condensate liquids and delayed sale of gas. An alternative method of keeping the reservoir above the dew point but avoiding the deferred gas sales is by water injection. 

Figure 5.23 shows the phase envelopes for the different types of hydrocarbons discussed, using the same scale on the axes. The higher the fraction of the heavy components in the mixture, the further to the right the two-phase envelope. Typical separator conditions would be around 50 bara and 15°C. 

For a single stage separator i.e. only one separator vessel, there is an optimum pressure which yields the maximum amount of oil and minimises the carry over of heavy components into the gas phase (a phenomenon called stripping). By adding additional separators to the process line the yield of oil can be increased, but with each additional separator the incremental oil yield will decrease. 

To prepare gas for evacuation it is necessary to separate the gas and liquid phases and extract or inhibit any components in the gas which are likely to cause pipeline corrosion or blockage. Components which can cause difficulties are water vapour (corrosion, hydrates), heavy hydrocarbons (2-phase flow or wax deposition in pipelines), and contaminants such as carbon dioxide (corrosion) and hydrogen sulphide (corrosion, toxicity). In the case of associated gas, if there is no gas market, gas may have to be flared or re-injected. If significant volumes of associated gas are available it may be worthwhile to extract natural gas liquids (NGLs) before flaring or reinjection. Gas may also have to be treated for gas lifting or for use as a fuel. 

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