2-Ethylhexyl phosphate

Tris(2-ethylhexyl) phosphate shows good compatibiUty with PVC and also imparts good low temperature performance in addition to good fire retardancy. 2-Ethyhexyl diphenyl phosphate has widespread use in dexible PVC appHcations due to its combination of properties of plasticizing efficiency, low temperature performance, migration resistance, and fire retardancy. 

Many organic reagents have been used successfully in Pu separation processes. The reagents include tri- -butyl phosphate (TBP) methyl isobutyl ketone thenoyl ttifluoroacetone (TTA) ethers, eg, diethyl ether, di- -butyl ether, tetraethylene glycol dibutyl ether trdaurylamine (TT,A) trioctylamine (TOA) di- -butyl phosphate (DBP) hexyl-di(2-ethylhexyl) phosphate (HDEHP) and many others. Of these, TBP is by far the most widely used (30,95). 

A beryUium concentrate is produced from the leach solution by the counter-current solvent extraction process (10). Kerosene [8008-20-6] containing di(2-ethylhexyl)phosphate [298-07-7] is the water-immiscible beryUium extractant. The slow extraction of beryUium at room temperature is accelerated by warming. The raffinate from the solvent extraction contains most of the aluminum and aU of the magnesium contained in the leach solution. 

Many of the surfactants made from ethyleneamines contain the imidazoline stmcture or are prepared through an imidazoline intermediate. Various 2-alkyl-imidazolines and their salts prepared mainly from EDA or monoethoxylated EDA are reported to have good foaming properties (292—295). Ethyleneamine-based imida zolines are also important intermediates for surfactants used in shampoos by virtue of their mildness and good foaming characteristics. 2- Alkyl imidazolines made from DETA or monoethoxylated EDA and fatty acids or their methyl esters are the principal commercial intermediates (296—298). They are converted into shampoo surfactants commonly by reaction with one or two moles of sodium chloroacetate to yield amphoteric surfactants (299—301). The ease with which the imidazoline intermediates are hydrolyzed leads to arnidoamine-type stmctures when these derivatives are prepared under aqueous alkaline conditions. However, reaction of the imidazoline under anhydrous conditions with acryflc acid [79-10-7] to make salt-free, amphoteric products, leaves the imidazoline stmcture essentially intact. Certain polyamine derivatives also function as water-in-oil or od-in-water emulsifiers. These include the products of a reaction between DETA, TETA, or TEPA and fatty acids (302) or oxidized hydrocarbon wax (303). The amidoamine made from lauric acid [143-07-7] and DETA mono- and bis(2-ethylhexyl) phosphate is a very effective water-in-od emulsifier (304). 

Tris-(2-ethylhexyl)phosphate (TEHP, tri-isooctylphosphate, "trioctyl" phosphate, [78-42-2 25103-23-5] M 434.6, b 186"/lmm, 219"/5mm, d 0.92042, n 1.44464. TEHP, in an equal volume of diethyl ether, was shaken with aqueous 5% HCl and the organic phase was filtered to remove... 

Chemical Designations - Synonyms Bis-(2-ethylhexyl) Hydrogen Phosphate Di-(2-ethylhexyl) Phosphate Di-(2-ethylhexyl) Acid Phosphate Chemical Formula [CH3CH2CHiCH2CH(CiH3)CHiO]2POOH. 

Examples of other frequently used surfactants that able to form reversed micelles without the addition of cosurfactants are didodecyldimethyl ammonium bromide [17], do-decylammonium propionate, benzyldimethylhexadecyl ammonium chloride [18], lecithin [19], tetraethyleneglycol monododecylether (C12E4) [20], decaglycerol dioleate [21], do-decylpyridinium iodide [22], and sodium bis(2-ethylhexyl) phosphate [23],... 

In many cases, under changing experimental conditions, water-containing reversed micelles evolve, exhibiting a wide range of shapes such as disks, rods, lamellas, and reverse-vesicular aggregates [15,107,108], Nickel and copper bis(2-ethylhexyl) sulfosucci-nate and sodium bis(2-ethylhexyl) phosphate, for example, form rod-shaped droplets at low water contents that convert to more spherical aggregates as the water content is increased [23,92,109,110],... 

The cobalt, nickel, and copper bis(2-ethylhexyl) phosphate surfactants dissolved in n-heptane lead to quasi-one-dimensional association microstructures, i.e., rodlike reversed micelles that increase in size via water solubilization [111],... 

In sodium bis(2-ethylhexyl) phosphate microemulsions, which are composed of cylindrical micelles in the dilute region, it has been observed that the formation of micellar clusters is characterized by a branched structure as the volume fraction (<1>) of the aggregates increases. At d> > 0.2, these clusters mutually overlap, forming a network expanded overall [283]. 

Synonym(s) Diphenyl-2-ethylhexyl phosphate Isodecyldiphenylphosphate Tributyl phosphate TBP butyl phosphate TNBP No data... 

Flynn [72] has described a solvent extraction procedure for the determination of 54manganese in seawater in which the sample with bismuth, cerium, and chromium carriers, is extracted with a heptane solution of bis(2-ethylhexyl) phosphate and the manganese back-extracted with 1M hydrochloric acid. After... 

Various organic extractants may be used, including butyl and amyl alcohols, di-isopropyl ether, tri-n-butyl phosphate, and tri-2-ethylhexyl phosphate. The fluoride remains with the... 

Aminophenol Bis(2-ethylhexyl)phosphate Silicone/cellulose Citric buffer pH 3.8 12... 

Plasticizers are used in the polymer industry to improve flexibility, workability, and general handling properties. Dibutyl sebacate and phthalates, such as dibutyl phthalate, diethyl phthalate, dicyclohexyl phthalate, butylbenzyl phthalate, and diphenyl-2-ethylhexyl phosphate, serve widely as plasticizers in vinylidene chloride copolymers, nitrocellulose-coated regenerated cellulose film, and cellulose acetate (Castle et ah, 1988a). In PVC, di(2-ethylhexyl)... 

Organophosphate triesters (OPERs) are used as flame retardants and/or plasticizers in a wide range of polymers, in furniture upholstery, insulation, wall coverings, and floor finishing products. Triethyl phosphate (TEP), tri-n-butyl phosphate (TnBP), tri-iso-butyl phosphate (T/BP), tris(2-ethylhexyl) phosphate (TEHP), and tris(2-butoxyethyl) phosphate (TBEP) are commonly used as plasticizers in polymers,... 

World Health Organisation (WHO) (2000) Flame retardants Tris(2-butoxyethyl)phosphate, tris(2-ethylhexyl) phosphate and tetrakis(hydroxymethyl)phosphonium salts. Environmental Health Criteria 218, WHO, Geneva... 

Fig. 22. Selectivity of the cell (37) for Na+ relative to Ca2+ as function of the dielectric constant of the membrane solvent. Membrane solvents (1) dibutyl-sebacate, (2) tris-(2-ethylhexyl)-phosphate, (3) 1-decanol, (4) acetophenone, (5) 2-nitrocymene, (6) p-nitroethylbenzene, (7) nitrobenzene...

Several other processes also are apphed for the commercial production of europium. In general, all processes are based upon the initial steps involving opening the mineral (bastnasite or monazite) with sulfuric acid or sodium hydroxide, often followed by roasting and solubihzation. In one such process after separation of cerium, the soluble rare earth chloride mixture in HCl solution is pH adjusted and treated with bis(2-ethylhexyl)phosphate to obtain europium sesquioxide, EuaOs. 

Di-(2-Ethylhexyl)Acid Phosphate Di-(2 Ethylhexyl)Adipate Di-(2-Ethylhexyl)Phosphate Di-(2-Ediylhexyl)Phosphoric Acid Di(2-Ethylhexyl) Phthalate Di-(2-Ethylhexyl)Sulfosuccinate Sodium Salt 0,0-Diethyl 0-(2-Isopropyl-6-Methyl -4-Pyrimidinyl)Phosphorothioate 0,0-Diethyl-0-(2-Isopropyl-6-Methyl-4-Pyrimidinyl) Phosphorothioate... 

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