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Electronic materials, hydrodynamic

High temperature aerosol decomposition, catalyst synthesis, 3 Hydrodynamic cavitation advanced catalysts, ceramics, and electronic materials, 3, 6-bismuth molybdate, 33-34 Bernoulli effect, 22... [Pg.208]

Once this flux equality condition (7.173) is formulated, one simply works out transport as a Pure transport problem and equates it to 1 InF times the current density across the interface since n faradays per mole are required for the transported material to be electronated. If the transport process consists of pure diffusion (i.e., there is no contribution from either migration or hydrodynamic flow), then the flux is given by Fick s first law (see Section 4.2.2), i.e.,... [Pg.497]

A hindrance to the elucidation of membrane structure is, of course, the material itself. Membranes are rather intractable lipoprotein systems. Their lipid, protein, and carbohydrate contents are variable both quantitatively and qualitatively since they cannot be crystallized, a detailed analysis by x-ray diffraction is impossible, and since they do not form solutions, the use of hydrodynamic or light-scattering techniques is quite limited. Electron microscopy has been the major physical method, but it is becoming increasingly clear that the electron microscope, at least at present, is incapable by itself of clarifying membrane structure on the molecular level (47). Despite an extensive literature, there is no general... [Pg.267]

A reversible one-electron transfer process (19) is initially examined. For all forms of hydrodynamic electrode, material reaches the electrode via diffusion and convection. In the cases of the RDE and ChE under steady-state conditions, solutions to the mass transport equations are combined with the Nernst equation to obtain the reversible response shown in Fig. 26. A sigmoidal-shaped voltammogram is obtained, in contrast to the peak-shaped voltammetric response obtained in cyclic voltammetry. [Pg.53]

The photocrosslinking of polymer materials continues to be attractive in many applications for electronic, electrical, insulation and property enhancements. iV-isopropylacrylamide with di-methylmaleinimidoacrylamide has been crosslinked to produce thermally sensitive nano-gels. These gels, made in micellar media, exhibited major changes in the hydrodynamic diameter in the vicinity of the phase-transition temperature of the polymer, with increases of temperature, micellar concentration and chromophore content all decreasing... [Pg.211]

Of course, Case 3 together with Cases 1 and 2, is an important process in W-value measurements of gaseous materials (16, 31). However, these measurements are indirect, and the data do not correspond directly to each primary process. At present the experimental data are too scant to explain in detail each process which results in electron and ion production. Case 3 may also be important in magneto-hydrodynamic power generation experiments (61). [Pg.197]

The lack of published works on this subject is due to two causes. First, the theory of the electronic structure and electronic transport has only recently become anywhere near adequate to cope with materials as complex as lead azide on the one hand and 1,3,5,7-tetranitro 1,3,5,7-tetraza cyclooctane (HMX) on the other. Second, the hydrodynamic theory of detonations has been remarkably successful in explaining the velocities of detonations, and initiation has been reasonably well explained in most cases as ultimately thermal in origin. ... [Pg.291]

Electrodes for voltammetry can be classified according to the electron conducting material, the geometry and size, the hydrodynamic conditions under which they operate and chemical modifications of their active surfaces. [Pg.275]

With regard to applications, these include mixing, aero- and hydrodynamics, heat dissipation and chemical reactions. One could use the features to, for example, change the location of transition from laminar to turbulent flow, or change the drag characteristics of a surface. Curved protrusions could be used to create swirl, and the holes could function as micro-injectors - even for chemicals - or to increase cooling. Surfl-sculpt could also function as a mechanical interlock. Shape memory alloys could also be improved in their functionality. Many materials could be processed in this manner metals, polymers, ceramics and glass are all feasible. The time to process 5 cm of material is a few seconds, and the equipment needed includes an electron beam machine and a vacuum chamber. [Pg.53]

The molecular structure (chemical structure) of any polymeric substance, that is, its chemical composition and way the atoms are connected in the molecule, does not unambiguously determine the behaviour and properties of biopolymer materials constructed of these macromolecules. The properties of such substances depend also on their supramolecular (physical) structure. This refers to the three-dimensional organization of the macromolecules. The supramolecular structures of the polymeric compounds have various forms that determine the structural and functional properties of biopolymers. It is impossible to observe the structure of biological molecules and their dynamics at the atomic level in vivo, though several different physical research methods could be used including hydrodynamic, optical, low-angle X-rays and neutrons diffraction. X-ray structural and neutron-structural analyses, NMR, electron microscopy and scan micro-calorimetry. [Pg.97]

From light-scattering measurements of hydrodynamic size (expressed in wt%). Descriptions based on scanning electron microscopy (SEM) images of electrospun material. Source. Gupta et al. 2005. [Pg.60]

Important characteristics that describe static mass, conformations, and dimensions of polymer molecules have been surveyed. This has been followed by hydrodynamic properties such as diffusion and viscosity. A separate section has been used to describe the salient aspects of charged polymers and colloids in solution. From there, the collective properties of polymers were briefly introduced in terms of their solution thermodynamics, the relationship of these to the scattering of light, and to phase behavior and transitions. Concentrated polymer solutions and melts become extraordinarily complex, with time response behavior depending on polymer architecture and interactions, and this has been briefly discussed in the area of rheology. In the solid-state limit of rheology, polymers take on myriad applications in materials engineering applications, in electronics, optics, and other areas. [Pg.104]


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