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Effects inductive

The quatemization reaction of the thiazole nitrogen has been used to evaluate the steric effect of substituents in heterocyclic compounds since thiazole and its alkyl derivatives are good models for such study. In fact, substituents in the 2- and 4-positions of the ring only interact through their steric effects (inductive and resonance effects were constant in the studied series). The thiazole ring is planar, and the geometries of the ground and transition states are identical. Finally, the 2- and 4-positions have been shown to be different (259. 260). [Pg.386]

Substituent Reactivity Orienting effect Inductive effect Resonance effect... [Pg.569]

Li C., Kaba H. and Seto K. (1994). Effective induction of pregnancy block by electrical-stimulation of the mouse accessory olfactory-bulb coincident with prolactin surges. Neurosci Lett 176, 5-8. [Pg.224]

Current data suggest little benefit on clinical outcomes beyond symptom relief for calcium channel blockers in the setting of ACS.43 Moreover, the use of first-generation shortacting dihydropyridines, such as nifedipine, should be avoided because they appear to worsen outcomes through their negative inotropic effects, induction of reflex sympathetic activation, tachycardia, and increased myocardial ischemia.43 Therefore, calcium channel blockers should be avoided in the acute management of MI unless there is a clear symptomatic need or a contraindication to p-blockers. [Pg.99]

Author s Comments That is again commensurate with the original D > 0.5 theory. By paralleling an extra inductor, the customer has reduced the effective inductance—closer to the 22 rl I suggested on page 12 of the datasheet. So why not suggest the customer simply try a single 22 rl I and be done with it Why beat around the bush ... [Pg.303]

Li WM, Dragowska WH, Bally MB, Schutze-Redelmeier MP. Effective induction of CD8+ T-cell response using CpG oligodeoxynucleotides and HER-2/ neu-derived peptide co-encapsulated in liposomes. Vaccine 2003 21(23) 3319-3329. [Pg.220]

POLAR EFFECT INDUCTIVE EFFECT FIELD EFFECT... [Pg.772]

Fluorine in organic compounds is associated with a set of electronic effects inductive and mesomeric, stabilizing and destabilizing, pulling or pushing electrons, which are convincingly... [Pg.22]

III. In vitro biological activity specificity and efficiency Cell culture Demonstrate specific antisense effect by various bioassays such as anti-viral and anti-proliferation effect, induction of apoptosis... [Pg.37]

The highest induction effect should be expected in the case of inequality w3 vv2 fulfillment at nq > w2. In this regard, accumulation of final products by the overall reaction (2.15b), No. 2 under the condition of effective induction performance must proceed at an incommensurately higher rate than the primary one. As mentioned above, the induction effect at w2 w3 will be insignificant, approaching the limit I = 0. In this consideration, it is assumed that rate constants ku k2 and k2 characterize elementary reactions of the same kinetic order otherwise, concentration factors would also have to be taken into account which would necessarily complicate the analysis. [Pg.29]

The changes in the pAia values associated with different carboxylic acids are the result of inductive effects. Inductive effects occur when electronegative groups pull electron density away from acidic centers, rendering these centers more acidic. Conversely, inductive effects... [Pg.27]

The RF SQUID is based on the AC Josephson effect, uses only one Josephson junction, and is less sensitive than the DC SQUID, but is cheaper and easier to manufacture its SQUID is inductively coupled to a resonant tank circuit. Depending on the external magnetic field, as the SQUID operates in the resistive mode, the effective inductance of the tank circuit changes, thus changing the resonant frequency of the tank circuit. These frequency measurements can be easily done, and thus the losses that appear as the voltage across the load resistor in the circuit are a periodic function of the applied magnetic flux with a period of 0. [Pg.640]

III. Gastrointestinal Effects Induction of Ulcers in Rats Submitted to Cold Stress Ulcerogenic effects at a gastrointestinal level of the experimental agents were determined after oral administration according to the method of Rainsford (3). Testing results are provided in Table 5. [Pg.146]

ST JOHN S WORT OESTROGENS Marked 1 contraceptive effect Induction of metabolism of oestrogens Avoid co-administration... [Pg.195]

CARBAMAZEPINE CNS STIMULANTS -MODAFINIL L plasma concentrations of modafinil, with possibility of 1 therapeutic effect Induction of CYP3A4, which has a partial role in the metabolism of modafinil Be aware... [Pg.218]

MERCAPTOPURINE ANTICOAGULANTS-WARFARIN Possible 1 anticoagulant effect Induction of metabolism of warfarin Monitor INR closely... [Pg.317]


See other pages where Effects inductive is mentioned: [Pg.10]    [Pg.323]    [Pg.436]    [Pg.205]    [Pg.233]    [Pg.368]    [Pg.37]    [Pg.49]    [Pg.10]    [Pg.556]    [Pg.85]    [Pg.471]    [Pg.348]    [Pg.348]    [Pg.158]    [Pg.117]    [Pg.998]    [Pg.17]    [Pg.722]    [Pg.251]    [Pg.77]    [Pg.10]   
See also in sourсe #XX -- [ Pg.170 ]

See also in sourсe #XX -- [ Pg.58 , Pg.124 ]




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7r-Inductive effect

Acetic acid inductive effects

Acetone induction effect

Acid-base reactions inductive effects

Acid-base strength inductive effects

Acidity inductive effects

Acids inductive effect

Additivity of Inductive Substituent Effects

Additivity, inductive effects

Additivity, inductive effects effective charge

Alcohols inductive effect

Alkenes inductive effects

Alkenes, addition reactions inductive effects

Alkyl group inductive effect

Amine inductive effects

Amino group inductive effect

Aniline, basicity inductive effect

Anisole inductive effects

Asymmetric induction solvent effect

Azines—continued inductive effects, transmission

Basicity inductive effects

Benzene derivatives inductive effects

Benzene rings substituents inductive effects

Boronate inductive effect

Carbocation inductive effects

Carbocations inductive effect

Carbonyl group inductive effect

Carboxylic acid aliphatic, inductive effects

Carboxylic acid inductive effects

Chiral Inductive Effect of Resolved Templates

Chirality Induction The Adam Effect

Chlorine inductive effect

Classical inductive effect

Cyclopropyl inductive effect

Defined inductive effects

Deuterium, “inductive effect

Direct inductive effect

Effect induction

Effect induction

Effect, alternation induction

Electrical effects inductive effect

Electrical induction effects

Electron-donating inductive effect

Electron-releasing inductive effect

Electronegativity effect induction

Electronic effects, inductive

Electronic effects, inductive conjugation

Electrophilic addition inductive effect

Electrophilic aromatic substitution reaction inductive effects

Electrophilic substitution, aromatic inductive effect

Fluorine inductive effect

Glycoside synthesis inductive effects

Halo group, inductive effect

Halogen, inductive effect

Hammett Induction effects

Hydrogen isotopes inductive effects

Hydrolysis kinetics inductive effects

INDUCTIVE EFFECTS ATOMIC CHARGES

Imidazolines inductive effect

Induction effects polarization

Induction motors loading effects

Induction period defect effect

Induction pharmacokinetic effects

Induction substitutent effect

Induction time effects

Induction, dispersion multipole interactions, penetration effects

Inductive Effects and Relative Acidities

Inductive Effects on Lewis Acidity and Basicity

Inductive and field effects

Inductive and hyperconjugative effects

Inductive and solvent effects

Inductive effect Electronegativity

Inductive effect alcohol acidity and

Inductive effect and acidity

Inductive effect as component of substituent effects

Inductive effect carbonyl substituents

Inductive effect carboxylic acid strength and

Inductive effect definition

Inductive effect electronegativity and

Inductive effect electrophilic substitution and

Inductive effect from functional groups, Table

Inductive effect in aldehydes and ketones

Inductive effect in alkenes

Inductive effect in alkynes

Inductive effect in carbocations

Inductive effect models

Inductive effect of a substituent

Inductive effect of alcohols

Inductive effect of alkyl groups

Inductive effect of carboxylic acids

Inductive effect of chlorine

Inductive effect of halogens

Inductive effect on electrophilic aromatic substitutio

Inductive effect on ester electrophilicity

Inductive effect parameter

Inductive effect silicon alkoxides

Inductive effect trifluoromethyl group

Inductive effect, acid strength

Inductive effect, of deuterium

Inductive effect, on acid

Inductive effective

Inductive effects Resonance effect)

Inductive effects benzene substituents

Inductive effects carbonyls

Inductive effects compounds

Inductive effects electron-withdrawing

Inductive effects hydration reactions

Inductive effects in aliphatic carboxylic acids

Inductive effects in aromatic substitution

Inductive effects interconversions

Inductive effects of other groups

Inductive effects on acidity

Inductive effects origin

Inductive effects shifts

Inductive effects structure

Inductive effects substituents

Inductive effects, carbonyl compounds

Inductive effects, fluorine-substitution

Inductive effects, silyl groups

Inductive versus steric effects

Inductive/field effects

Inductively coupled plasma memory effects

Ir-inductive effect

Lead wire inductance effect

Lewis acidity inductive effects

Methyl group inductive effect

Negative inductive effect

Nitrobenzene inductive effects

Nucleophilic reaction inductive effects

Organosilanes inductive effects

Perfluoroalkyl group, inductive effect

Pi-inductive effect

Polarized bonds underlie inductive effects

Reaction inductive effect

Resonance and inductive effects

Rifampin inductive effect

Secondary isotope effects inductive effect

Separation of inductive, steric and resonance effects

Steric and Inductive Effects

Substituent effects, inductive

Substituent effects, inductive Steric

Substituent effects, inductive mesomeric

Substituents, electron withdrawing Inductive effects from

Sugar moieties, inductive effects

The 7r-Inductive Effect

The Induction Effect

The Inductive Effects

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