Corrosive storage

Toxicology Causes eye damage and skin irritation harmful if swallowed Precaution Corrosive Storage Keep tightly closed Metasol CB-225A.D. [ONDEO Nalco]... 

Properties Fine needles or Ig. plates sol. in water, alcohol si. sol. in benzene m.w. 158.18 m.p. 43-44 C avail, as the sesquihydrate Toxicology LD50 (oral, rat) 890 mg/kg LDLo (skin, cat) 10 g/kg highly toxic poison by ing., skin contact severe skin and eye irritant irritating to mucous membranes TSCA listed Precaution Oxidizer corrosive Storage Deliq. 

Precaution Flamm. corrosive Storage Light-sensitive Uses Adhesion promoter Manuf./Distrib. Aldrich http //www.sigma-aldrich.com... 

Toxicology LD (skin, rabbit) > 300 mg/kg nuisance dust TSCA listed Precaution Corrosive Storage Hygroscopic, deliq. 

Let s first consider how corrosive storage cabinets should be made. You might think there are some kinds of rules about this, such as regulations, but it turns out there are none for corrosives. Cabinets made of metal are not best for corrosives, since acids react with metals however, metal cabinets are sometimes painted with a corrosion-resistant epoxy paint that protects the metal from acid attack. Still... 

Petrochemical Gas pipelines, heat exchangers, cooling-water systems, atmospheric corrosion, storage tanks... 

Storage Negligible corrosivity storage at normal temps, will not affect prod., but extended storage should be avoided Struktol TR 131 [Struktol]... 

Toxicology Causes severe eye and skin damage harmfui orfatai if swaiiowed Precaution Corrosive Storage Store in dry piace 10-50 C Clough PHF 320 [Boehme Filatex Canadas]... 

For jet fuels, the elimination of free water using filters and coalescers by purging during storage, and the limit of 5 ppm dissolved water are sufficient to avoid incidents potentially attributable to water contamination formation of micro-crystals of ice at low temperature, increased risk of corrosion, growth of micro-organisms. 

In the 1950 s, crude oils were either corrosive (sour), or non-corrosive (sweet). Crudes containing more than 6 ppm of dissolved H2S were classed as sour because, beyond this limit, corrosion was observed on the walls of storage tanks by formation of scales of pyrophoric iron sulfides. 

The end product specification of a process may be defined by a customer (e.g. gas quality), by transport requirements (e.g. pipeline corrosion protection), or by storage considerations (e.g. pour point). Product specifications normally do not change, and one may be expected to deliver within narrow tolerances, though specification can be subject to negotiation with the customer, for example In gas contracts. 

Zinc is also used extensively to galvanize other metals such as iron to prevent corrosion. Zinc oxide is a unique and very useful material for modern civilization. It is widely used in the manufacture of paints, rubber products, cosmetics, pharmaceuticals, floor coverings, plastics, printing inks, soap, storage batteries, textiles, electrical equipment, and other products. Lithopone, a mixture of zinc sulfide and barium sulfate, is an important pigment. 

Bronze disease necessitates immediate action to halt the process and remove the cause. For a long time, stabilization was sought by removal of the cuprous chloride by immersing the object in a solution of sodium sesquicarbonate. This process was, however, extremely time-consuming, frequentiy unsuccesshil, and often the cause of unpleasant discolorations of the patina. Objects affected by bronze disease are mostiy treated by immersion in, or surface appHcation of, 1 H-henzotriazole [95-14-7] C H N, a corrosion inhibitor for copper. A localized treatment is the excavation of cuprous chloride from the affected area until bare metal is obtained, followed by appHcation of moist, freshly precipitated silver oxide which serves to stabilize the chloride by formation of silver chloride. Subsequent storage in very dry conditions is generally recommended to prevent recurrence. 

Vapors emitted from the materials of closed storage and exhibit cases have been a frequent source of pollution problems. Oak wood, which in the past was often used for the constmction of such cases, emits a significant amount of organic acid vapors, including formic and acetic acids, which have caused corrosion of metal objects, as well as shell and mineral specimens in natural history collections. Plywood and particle board, especially those with a urea—formaldehyde adhesive, similarly often emit appreciable amounts of corrosive vapors. Sealing of these materials has proven to be not sufficiently rehable to prevent the problem, and generally thek use for these purposes is not considered acceptable practice. 

In this pyrolysis, sub atmospheric partial pressures are achieved by employing a diluent such as steam. Because of the corrosive nature of the acids (HE and HCl) formed, the reactor design should include a platinum-lined tubular reactor made of nickel to allow atmospheric pressure reactions to be mn in the presence of a diluent. Because the pyrolysate contains numerous by-products that adversely affect polymerization, the TFE must be purified. Refinement of TFE is an extremely complex process, which contributes to the high cost of the monomer. Inhibitors are added to the purified monomer to avoid polymerization during storage terpenes such as t7-limonene and terpene B are effective (10). 

In unalloyed steel containers formamide discolors slowly during shipment and storage. Both copper and brass are also subject to corrosion, particularly in the presence of water. Lead is less readily attacked. Aluminum and stainless steel are resistant to attack by formamide and should be used for shipping and storage containers where the color of the product is important or when metallic impurities must be minimized. Formamide attacks natural mbber but not neoprene. As a result of the solvent action of formamide, most protective paints and finishes are unsatisfactory when in contact with formamide. Therefore, formamide is best shipped in containers made of stainless steel or in dmms made of, or coated with, polyethylene. Formamide supphed by BASF is packed in Lupolen dmms (230 kg) or Lupolen canisters (60 kg) both in continental Europe and overseas. 

Many stabilizer systems have been tailored to a particular industry need or for particular areas where dilution water quaUty is poor. These grades are heavily stabilized and may contain organic sequestering agents, ie, staimate, phosphates, and nitrate ions, so that the weak solutions produced by dilution from hard water retain acceptable stabihty. The nitrate is not a stabilizer, but it inhibits corrosion of aluminum storage tanks by chloride ion. 

Commercial-grade nitroparaftins are shipped and stored ia ordinary carbon steel. However, wet nitroparaftins containing more than 0.1—0.2% water may become discolored when stored ia steel for long periods, even though corrosion is not excessive. Aluminum and stainless steel are completely resistant to corrosion by wet nitroparaftins. Storage ia contact with lead (qv), copper, or alloys containing these metals should be avoided. Polymeric materials for gaskets, hoses, and connections should be tested for thek suitabiHty before exposure to nitroparaftins. 

---