Corrosion inhibition closed systems

Open recirculating systems These are more amenable to inhibition since it is possible to maintain a closer control on water composition. Corrosion inhibition in these systems is closely allied to a number of other problems that have to be considered in the application of water treatment. Most of these arise from the use of cooling towers, ponds, etc. in which the water is subject to constant evaporation and contamination leading to accumulation of dirt, insoluble matter, aggressive ions and bacterial growths, and to variations in pH. A successful water treatment must therefore take all these factors into account and inhibition will often be accompanied by scale prevention and bactericidal treatments. 

Azoles provide effective corrosion inhibition primarily by chemisorption of the molecule on the metal substrate. Several different types of azoles are available for incorporation into formulations used for the corrosion inhibition of closed loop LPHW heating and low MU requirement, LP steam heating systems. 

DEWTL. [Drew Ind. Div.] Chromate/ orgouc blend corrosion inhibit for closed recirculating water systems. 

For control of deposits and scale, closed systems require hardness-free (or preferably mineral-free) makeup water. Microbicides are not required for closed systems, but dispersants to keep metal oxides and other insoluble contaminants in suspension are useful. They aid in preserving clean heat transfer surfaces, which provide maximum response to corrosion inhibition. Long chain ethylene oxide polymers also are being used to improve "wetting" properties of cooling water and minimize turbulence, where impingement and cavitation problems are observed. 

Nitrites are environmentally fiiendly anodic inhibitors. They form a passive film with ferric oxide and inhibit the corrosion of copper, nickel, and tin alloys in alkaline environments (pH levels 9-10), but aggressive ions such as chloride and sulfate ions attack and destroy the barrier film. They reduce the rate of anodic dissolution on steel as shown in Fig. 14.10 [61]. Nitrites are used only in closed systems because they oxidize to nitrates in the presence of oxygen. They are not as efficient inhibitors as chromates. 

Vapor phase inhibitors (VPIs), also called volatile corrosion inhibitors (VCIs), are compounds that are transported in a closed system to the site of corrosion by volatilization from a source. In boilers, volatile basic compounds such as morpholine or octadecylamine are transported with steam to prevent corrosion in condenser tubes by neutralizing acidic carbon dioxide (Boles et al. 2009). Compounds of this type inhibit corrosion by making the environment alkaline. In closed vapor spaces, such as shipping containers, volatile solids such as the nitrite, carbonate, and benzoate salts of dicyclohexylamine, cyclohexylamine, and hexamethyleneimine are used. 

Inhibitors are very important for corrosion of irons and other metals. The corrosion of irons and other metals in aqueous solutions can frequently be minimized or inhibited by the addition of soluble chromates, molybdates, silicates, and amines or other chemicals, singly or in combination. Such materials are called inhibitors and are generally attractive for use in recirculating systems or closed systems. They are also used in neutral or very slightly acid solutions. The concentration of an inhibitor for maximum control depends on the solution, composition, temperature, velocity, metal system, and the presence of dissimilar metals in contact in the solution. Care should be taken in the selection and application of inhibitors, since in some instances they can increase localized attack. 

Chem. Analysis Sodium benzoate (90-92%), sodium nitrite (8-10%) Uses Corrosion inhibitor for antifreeze, closed cycle heating and cooling systems, domestic and industrial heating systems, summer coolants for internal combustion engines, hydraulic systems, emulsion paints, textile emulsions and adhesives corrosion-inhibiting impregnant for wrapping papers... 

The most appropriate system for the plotform wos considered to be on indirect seawater cooling system which uses seawater to cool recirculating inhibited fresh woter in o closed loop system. The fresh water is circulated on the shell side of the process exchangers to minimise corrosion problems ond eliminate the need to use exotic materials which would be... 

It is important not to leave the system empty of water for any long period, as rapid surface rusting will take place. As soon as the closed-loop system is declared free of contamination, sufficient corrosion inhibitor is added to provide long-term corrosion protection. The corrosion inhibitor is usually an anodic, passivating formulation, typically based on nitrite or tannin (and often in combination with phosphate, silicate, borate, or molybdate, etc.). Finally, after confirmation that the entire system is adequately treated (which usually requires the inhibited water in the system to be recirculated for a further 16 to 24 hours), the system is signed off and handed over. 

The efficiency of polymer materials as an anticorrosion mean of protection of metal parts from corrosion can be significantly raised by modification of polymer binders using corrosion inhibitors for metals. In this case it becomes possible to realize both the barrier and inhibition mechanisms for metal protection from corrosion in the anticorrosion element. Anticorrosion polymer elements as a source of electric field can hamper corrosion processes and corrosion-mechanical wear of metal parts by the electrochemical mechanism. Realization of the barrier, inhibition and electrochemical mechanisms of anticorrosion protection with the help of polymers not only allows a profound improvement in the anticorrosion protection of metal parts but comes close to the creation of smart anticorrosion plastics and anticorrosion systems. 

In the case of IRB, the results of a piece of research concluded that the static or nonstatic regime of the environment could have a profound effect on acceleration or inhibition of corrosion. As may be inferred from this research, if the system is closed so that dilution of ferrous ions is not happening, corrosion may be slowed down otherwise, in an open system where dilution of ferrous ions is possible, corrosion acceleration can be expected. 

Before storing the molds, they should cool down, so that no condensation occurs on the mold surface and corrosion is thus inhibited. The temperature control channels are to be kept closed in order to prevent exposure to oxygen. Another possibility is that the temperature control bore holes are completely removed from water before the deposition. Corrosion is not only a problem for the temperature control channels. Oil, as a temperature control medium, forms decomposition products that usually accumulate in the tank of the temperature control system. At some point, it gets into the mold and can clogg riser holes in the mold cores. It is therefore not only essential to replace the temperature control medium, but also to clean the heater tank. 

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