Corrosion from

Gas leaving the converter is normally cooled to 180—250°C using boiler feedwater in an "economizer." This increases overall plant energy recovery and improves SO absorption by lowering the process gas temperature entering the absorption tower. The process gas is not cooled to a lower temperature to avoid the possibiUty of corrosion from condensing sulfuric acid originating from trace water in the gas stream. In some cases, a gas cooler is used instead of an economizer. 

Evaluate potential for external corrosion from environmental factors such as chloride bearing insulation, chemical spills, sea mist, road salt, etc. 

Table 4-3 Data on local corrosion from field experiments (after 12 years [11] and 6 years [ 12]).

Aluminum appears to be resistant to corrosion from SO2 at ambient air concentrations. Aluminum alloys tend to form a protective surface film... 

Dehydration to dew points below the temperature to which the gas will be subjected will prevent hydrate formation and corrosion from condensed water. The latter consideration is especially important in gas streams containing CO2 or H2S where the acid gas components will form an acid with the condensed water. 

Consideration must be given to possible equipment corrosion from such external sources as a corrosive atmosphere, spills, insulation, or gland leakage. For example, insulation containing trace quantities of chlorides can cause stress corrosion failure of 18-8 stainless steel vessels and piping. ... 

Solar water heating declined in Southern California in the 1920s due to the development of natural gas, but it continued in Florida where natural gas was very expensive. In 1941 more than half Miami s population had solar water heaters, and more than 80 percent of new homes built then were equipped with solar water heaters. By the end of the 1950s in Florida, solar water heating was displaced by electricity as the price dropped and the storage tanks of solar water heaters failed because of galvanic corrosion from connecting steel tanks to copper collectors. 

Figure 4-431. Ringworm corrosion—at the inside of the tubing where grain structure near edge of upset portion makes metal susceptible to rapid corrosion. (From Ref. [219].)...

Selection of fans and ducting for local extract must be more rigorous than for other systems. The fan must be capable of withstanding abrasion or corrosion from the contaminants, and if they are flammable must have a flameproof or out-of-air stream motor. The ducting also must be able to withstand abrasion or corrosion and must be fully sealed to prevent escape of contaminants within the building. For specialist applications such as fume cupboard extract, ducting and fans are often of plastic construction. 

Rabald, E. Resistance of Lead lo Corrosives, from Corrosion Guide, (1951)... 

The reaction of lead with concrete differs from that of aluminium and of zinc in that it is not normally rapid during the early wet stage. It is, however, progressive in damp conditions, and this is said to be due to the fact that the concrete prevents the formation of a protective basic lead carbonate film on the surface of the lead. The packing of lead cables in plaster of Paris is reported to be of doubtful value in preventing corrosion from surrounding concrete. 

Morgan, P. D. and Double, E. W. W., /4 Critical Resume of a.c. Corrosion from the Standpoint of Special Methods of Sheath Bonding of Single Conductor Cables, British Electrical and Allied Industries Research Association Technical Report F/T 73 (1934)... 

Test method for porosity in gold platings on metal substrates by gas exposures Test method for half-cell potentials of uncoated reinforcing steel in concrete Method for detection of copper corrosion from petroleum products by the copper strip tarnish test... 

Problems with heating coils Internal coil corrosion Note corrosion debris is green hydrated copper carbonate Cu[11IC03 nH20 red cuprous oxide Cu20 /ntemal coil deposition Acid corrosion from soft water. Pinhole corrosion from 02 and C02. Erosion corrosion over 6 ft/s flow. Hard water scale from hard water. 

Other forms of concentration-cell corrosion include Caustic gouging Saline corrosion Combination of free caustic and concentrating effect causes severe metal wastage. High chlorides and sulfates, result in corrosion from depolarization and depassivation effects... 

High levels of chelant or oxygen affect the redox tendencies of iron-oxygen reactions and permit the liberation of Fe2+ ions (corrosion) from a metal surface and their subsequent chelation, thus preventing the formation or repair of blanketing ferric oxides, hydroxides, or a passivated magnetite film. 

Corrosion (from Latin corrodere, gnaw to pieces ) of metals is the spontaneous chemical (oxidative) destruction of metals under the elfect of their environment. Most often it follows an electrochemical mechanism, where anodic dissolution (oxidation) of the metal and cathodic reduction of an oxidizing agent occur as coupled reactions. Sometimes a chemical mechanism is observed. 

Process locations containing large volumes or high pressure hydrocarbon gases which might be susceptible to extreme effects of erosion or corrosion from the process activity. 

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