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Trivial or trade namc.s can be stored and searched as character strings. Their use is the simplest and most intuitive way of storing chemical information. However, being not subject to strict rules, their formation does not reflect accurately the molecular composition. Hence, the structure of the searched compound cannot be derived from them. Thus, a name such as "Flexricin does not tell the user very much. Furthermore, many more than one trivial or trade name for a given compound usually exist. [Pg.293]

X-ray photoelectron spectroscopy (XPS) is currently the most widely used surface-analytical technique, and is therefore described here in more detail than any of the other techniques. At its inception hy Sieghahn and coworkers [2.1] it was called ESCA (electron spectroscopy for chemical analysis), hut the name ESCA is now considered too general, because many surface-electron spectroscopies exist, and the name given to each one must be precise. The name ESCA is, nevertheless, still used in many places, particularly in industrial laboratories and their publications. Briefly, the reasons for the popularity of XPS are the exceptional combination of compositional and chemical information that it provides, its ease of operation, and the ready availability of commercial equipment. [Pg.6]

A principal disadvantage of conventional XPS was lack of spatial resolution the spectral information came from an analyzed area of several square millimeters and was, therefore, an average of the compositional and chemical analysis of that area. Many technological samples are, on the other hand, inhomogeneous on a scale much smaller than that of conventional XPS analysis, and obtaining chemical information on the same scale as the inhomogeneities would be very desirable. [Pg.14]

The relationship between what is recorded in a SSIMS spectrum and the chemical state of the surface is not as straightforward as in XPS and AES (Chap. 2). Because of the large number of molecular ions that occur in any SSIMS spectrum from a multi-component surface (e. g. during the study of a surface reaction), much chemical information is obviously available in SSIMS, potentially more than in XPS. The problem in using the information from a molecular ion lies in the uncertainty of knowing whether or not the molecule represents the surface composition. For some materials. [Pg.94]

The information contained in ESCA (Electron Spectroscopy for Chemical Analysis) spectra [331] makes the method particularly suitable for determinations of surface compositions, chemical bonding of surface atoms and changes which occur at solid surfaces during reaction [312], Applications of this technique to the study of reactions of and between solids are awaited with interest. [Pg.30]

AES is a useful element-specific technique for quantitative determination of the elemental composition of a surface. Although some chemical information is available in principle, the technique is used largely for elemental analysis. Electron beam damage can decompose organic adsorbates and cause damage, particularly on insulating surfaces. In some cases, the beam can reduce metal oxides. [Pg.510]

The data chain of the collected atoms can be converted to a one-dimensional composition-depth profile. The depth profile shows an average concentration of solute within the aperture, and there is always a possibility that the chemical information from the selected area is a convolution of more than one phase, as indicated diagrammatically in Figure 1.5, which represents the analysis of a FIM specimen containing second phase particles and also an interface across which there is a change of composition. [Pg.8]

The analytical process is a procedure of gaining information. At first, samples contain only latent information on the composition and structure, namely by their intrinsic properties (Malissa [1984] Eckschlager and Danzer [1994]). By interactions between the sample and the measuring system this information is transformed step by step into signals, measured results and useful chemical information. [Pg.69]

The shape and energy of the resulting Auger peaks are thus useful in identifying the elemental composition of the sample surface as well as obtaining useful chemical information. [Pg.396]

The preparation and study of nanoparticles has attracted a remarkable academic and industrial research effort because of their potential applications, ranging from fundamental studies in quantum physics, fabrication of composite materials, information storage/optoelectronics, immunoassays, to catalysts. The precise control of size and chemical behavior (stabihty and reactivity) by means of the synthesis itself is still one of the main targets because the direct correlation of the new intriguing properties with the particle size which is just between a molecule and a bulk material [140]. [Pg.395]

The greatest benefit of RACHEL S component extraction method is that a massive property index of the entire corporate database is created. Along with the atomic coordinates of each component, a wealth of chemical information characterizing each building block is stored. Data such as the size of the component, atom composition, connectivity, ring structure, and electrostatic charges are included. As such, a means of rapidly cross-referencing chemical components on demand is available. [Pg.203]

Concerning the volume properties of the various polymorphs with respect to their chemical compositions, existing information on Pbca and P2 /c structures indicates linear dependence of mean Ml and M2 site dimensions on the ionic radii of the occupying cations (algebraic mean). As figure 5.21 shows, this linearity is more marked for Ml than for M2, which has distorted symmetry. [Pg.274]

Certainly, the inherent lack of depth resolution of the BMP techniques minimizes the utility of sputter profiling combined with BMP analysis. However, gross comparisons of the exterior versus interior composition can be obtained by recording X-ray spectra before and after a minimum of several thousand angstroms of material are sputtered from the particle surface (13,44). Similarly, BSCA is not very suitable when used in conjunction with sputter profiling for reasons that include a) data acquisition rates are very slow, b) potential chemical information is lost since sputtering may alter the chemical forms of the elements present, and c) individual particles cannot be depth profiled (11, 14, 26). [Pg.151]

Also, there might be absorptions in the IR spectra which are characteristic for syn- or isotacticity (such as in PMMA) or for branching points of nonlinear polymer chains (such as in polyethylene). Using data pools and programs which simulate IR spectra it is possible nowadays to characterize nearly all kinds of polymers very quickly using IR spectroscopy with respect to their constitution and their composition. Also, IR spectroscopy can be coupled with polymer chromatography (SEC, HPLC). Then it provides detailed chemical information on each individual chromatographic fraction. [Pg.83]

According to the vendor, this project could provide a compact, low-cost reactor to treat aqueous mixed waste streams containing nitrates or nitrites, eliminate the need for chemical reagents, and minimize or eliminate secondary wastes such as nitrous oxide and secondary products such as ammonia, H2, and O2 that are prevalent with other nitrate destruction processes. By removing nitrates and nitrites from waste streams before they are sent to high-temperature thermal destruction and vitrification, production of NO can be decreased with the attendant decrease in off-gas system requirements. Biocatalytic nitrate destruction is applicable to a wide range of aqueous wastes with a highly variable composition. All information is from the vendor and has not been independently verified. [Pg.371]

During the last twenty years, food chemists have been using an increasing number of analytical instruments to analyse several samples quickly and obtain, in a short time, a great deal of chemical information from each sample. At the same time, they have increased their knowledge of the chemical composition of natural foods and of the changes due to storage and treatments, and also of market and customer requirements. [Pg.93]

Cosmochemistry is the study of the chemical composition of the universe and the processes that produced those compositions. This is a tall order, to be sure. Understandably, cosmochemistry focuses primarily on the objects in our own solar system, because that is where we have direct access to the most chemical information. That part of cosmochemistry encompasses the compositions of the Sun, its retinue of planets and their satellites, the almost innumerable asteroids and comets, and the smaller samples (meteorites, interplanetary dust particles or IDPs, returned lunar samples) derived from them. From their chemistry, determined by laboratory measurements of samples or by various remote-sensing techniques, cosmochemists try to unravel the processes that formed or affected them and to fix the chronology of these events. Meteorites offer a unique window on the solar nebula - the disk-shaped cocoon of gas and dust that enveloped the early Sun some 4.57 billion years ago, and from which planetesimals and planets accreted (Fig. 1.1). [Pg.1]

RIS theory is used to predict values of the optical-configuration parameter Aa for ethylene - propylene copolymers as a function of chemical composition, chemical sequence distribution, and stereochemical structure of the propylene sequences. The calculations are based on information available for ethylene and propylene homopolymers, and on the model used to interpret the unperturbed dimensions of these copolymers. Values of Aa are generally found to decrease significantly with increase in the fraction of propene units, but to be relatively insensitive to chemical sequence distribution and stereochemical structure. Geometries and conformational energies are the same as those used for the interpretation of the unperturbed dimensions of these chains. The conformational energies used are E(q) = 0, EM 2.09, and E a>) = 0.37 kJ mol-1. [Pg.366]

Size-resolved chemical information is much more difficult to obtain. The many applications of the differential mobility analyzer in measuring properties of size-classified particles are important tools for the characterization of aerosol systems, but the approaches demonstrated to date yield limited data. Vapor pressures, surface tension, and optical absorption have been measured on mobility-classified aerosols. Direct measurements of the distribution of chemical composition with particle size are needed. Elemental... [Pg.218]


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See also in sourсe #XX -- [ Pg.632 , Pg.633 , Pg.634 , Pg.635 , Pg.636 ]




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