Polymeric complexes

Wood is a complex polymeric stmctuie consisting of lignin (qv) and caiboliydiates (qv) [cellulose (qv) and liemiceUuloses], which form the visible... 

It is highly probable that the monomer is first coordinated onto a vacant position of the complex and then pushed between a boron-carbon bond of the catalyst. The following mechanism, proposed by Bawn, can be considered as a prototype of coordinated complex polymerization ... 

New optical (static as well as dynamic) techiuques for the stndy of long-range order in stractured continna are begiiming to appear and can be used to understand the constitutive properties and relations in complex (polymeric, nematic, and other stmctured) fluids. 

Table 1. Solution polymerization results for butadiene usir cobalt(II) pyridyl bis(imine) complexes. Polymerization conditions [l,3-butadiaie]= 1 mol/L [Cal.] = 2.00 x 10" mol/L ...

Melanins are complex polymeric structures, which are usually mixtures of macromolecules. Melanins are classified as eumelanins, phaeomelanins and allomelanins. ... 

Slow, except in presence of alkalis products formed are complex polymeric quaternary ammonium salts dimerizes fairly rapidly in water. 

It is concluded that MALDI-ToFMS is a suitable method for direct analysis of low-MW additives in complex polymeric materials (in dissolution), in particular as a rapid screening technique (within 0.5 h). However, in order to turn this method into a general tool for identification and quantitation, considerably more work needs to be done. Identification of additives in polymeric matrices by means of MALDI-ToFMS would greatly benefit from reference libraries of additives contained in such matrices. This is not unlike the situation observed for ToF-SIMS. 

Mass spectrometry combines exquisite sensitivity with a precision that often depends more on the uncertainties of sampling and sample preparation than on those of the method itself. Mass spectrometry is a supreme identification and recognition method in polymer/additive analysis through highly accurate masses and fragmentation patterns quantitation is its weakness. Direct mass spectrometry of complex polymeric matrices is feasible, yet not often pursued. Solid probe ToF-MS (DI-HRMS) is a breakthrough. Where used routinely, mass spectrometrists are usually still in charge. At the same time, however, costs need to be watched. 

Although the feasibility of direct probe MS for the analysis of additives in complex polymeric matrices has been demonstrated (Section 6.4), application is limited, difficult and requires above-average mass-spectroscopic expertise. Direct desorption in the MS probe is usually limited to screening of volatile components. Direct multicomponent spectroscopic analysis has other hurdles to overcome (UV/VIS lack of spectral discrimination IR/R functional-group recognition only, with no discriminative power for additives with similar functionalities NIRS unsuitable for R D problems NMR sensitivity). 

Aniline black (Cl Oxidation Base 1) is a complex polymeric phenazine that can be produced on cotton fabric by impregnation with aniline hydrochloride and suitable inorganic oxidants, such as sodium chlorate, ammonium vanadate and copper hexacyanoferrate(II). Aniline black is also made directly for use as a pigment (Cl Pigment Black 1). 

A standard Lowry-based protein assay has been adjusted to the special conditions encountered with skin [126], Basically, proteins reduce an alkaline solution of Cu(II)-tartrate to Cu(I) in a concentration-dependent manner. Then, the formation of a blue complex between Folin-Ciocalteau reagent (a solution of complex polymeric ions formed from phosphomolybdic and phosphotungstic heteropoly acids) and Cu(I) can be measured spectrophotometrically at 750 nm. A calibration curve can be obtained by dissolving known amounts of stratum corneum in 1 M sodium hydroxide. A piece of tape that has not been in contact with skin is subjected to an identical procedure and serves as negative control. The method was recently adapted to a 96-well plate format, notably reducing analysis times [129],... 

When alkynes are treated with catalytic amounts of a carbene complex, polymerization instead of metathesis can occur (Figure 3.44) [565,595,597,752-754]. The use of carbene complexes to catalyze alkyne polymerization enables much better control of the reaction than with heterogeneous or multi-component catalysts. Pure acetylene oligomers (n = 3-9) with terminal fcrf-butyl groups have been prepared with the aid of a tungsten carbene complex [755]. 

Suppose we start with a starch-rich meal, say one containing a lot of pasta or bread. The digestion of starches begins in the mouth. Saliva contains an enzyme, salivary amylase (aka ptyalin), which catalyzes the conversion of starch to simple sugars such as glucose. This process is completed in the small intestine under the influence of other enzymes in the amylase class. This completes the first phase of carbohydrate catabolism the conversion of complex, polymeric carbohydrates (e.g., starches) to their simple monomeric units, the sugars. 

Coordination polymers can be prepared by a number of routes, among which the three most common being (1) preformed coordination metal complexes polymerized through functional groups where the actual polymer-forming step may be a condensation or addition reaction ... 

A-Carboxy-a-amino acid anhydrides, also referred to as 4-substituted oxazolidine-2,5-diones, Leuchs s anhydrides, or N-carboxyanhydrides (NCA), are polymerized by bases and transition metal complexes. Polymerization proceeds with simultaneous decarboxylation to produce a polyamide... 

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