Substitution polymerization, chloroarene complexes

Phosphino)amines and their complexes have been shown to be efficient catalysts for the palladium-catalyzed Suzuki coupling reaction of chloroarenes,449 rhodium-catalyzed hydroformy-lations458 and asymmetric hydrogenations,463,466 allylic substitution reactions,47, 472 conversion of isocyanates to isocyanurates,478 and as ethylene polymerization catalysts.479... 

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