Cheaper

The preference is for a process based on ethylene rather than the more expensive acetylene and chlorine rather than the more expensive hydrogen chloride. Electrolytic cells are a much more convenient and cheaper source of chlorine than hydrogen chloride. In addition, we prefer to produce no byproducts. 

Similarly, instead of installing vacuum relief valves the vessels can be made strong enough to withstand vacuum. In addition, if the vessel contains flammable gas or vapor, vacuum relief valves will often need to admit nitrogen to avoid flammable mixtures. A stronger vessel often may be safer and cheaper. 

When synthesizing a fiowsheet, the designer should consider carefully the problems associated with operation under extreme conditions. Attenuation will result in a safer plant, providing the attenuation does not increase the inventory of hazardous materials. If the inventory does not increase, then attenuation not only will make the process safer but also will make it cheaper, since cheaper materials of construction and thinner vessel walls can be used and it is not necessary to add on so much protective equipment. 

Relief systems. Relief systems are expensive and may bring significant environmental problems with them. Strengthening vessels may be a cheaper option. 

Kletz, T. A., Cheaper, Safer Plants, IChemE Hazard Workshop, 2d., IChemE, Rugby, U.K., 1984. 

The amount of detail input, and the type of simulation model depend upon the issues to be investigated, and the amount of data available. At the exploration and appraisal stage it would be unusual to create a simulation model, since the lack of data make simpler methods cheaper and as reliable. Simulation models are typically constructed at the field development planning stage of a field life, and are continually updated and increased in detail as more information becomes available. 

Providing the land surfaoe above a reservoir is relatively flat, it is generally cheaper to drill and maintain a vertical well than to access a reservoir from a location that requires a deviated borehole. In unpopulated areas such as desert or jungle looations It is common to find that the pattern of wellheads at surface closely reflects the pattern In which wells penetrate the reservoir. However, in many eases constraints will be planed on drill site availability as a result of housing, environmental concerns or topography. In such conditions wells may be drilled in clusters from one or a number of sites as elose as possible to the surface location of the reservoir. 

On a land site where space and weight are not normally constraints, advantage can be taken of tank type separation equipment such as wash tanks and settling tanks, and batch processing methods. Such equipment is generally cheaper to maintain than continuous throughput vessels, though a combination of both may be required. 

Steel piled jackets are the most common type of platform and are employed in a wide range of sea conditions, from the comparative calm of the South China Sea to the hostile Northern North Sea. Steel jackets are used in water depths of up to 150 metres and may support production facilities a further 50 metres above mean sea level. In deep water all the process and support facilities are normally supported on a single jacket, but in shallow seas it may be cheaper and safer to support drilling, production... 

In 1986 when the oil price crashed to 10 a barrel, operators began to look very hard at the requirements for offshore developments and novel slimline, reduced facilities platforms began to be considered. The reduced capital outlay and early production start up capability, coupled with the added flexibility, ensured that all companies now consider subsea systems as an important field development technique. Although the interest and investment in subsea systems increased dramatically, subsea systems still had to compete with the new generation of platforms, which were becoming lighter and cheaper. 

Wang J, Tian B, Wang J, Lu J, Olsen C, Yarnitzky C, Olsen K, Hammerstrom D and Bennett W 1999 Stripping analysis Into the 21st century faster, smaller, cheaper, simpler and better Tina/. Chim. Acta 385 429... 

Pig. 4. Photo dissociation of ArHCl. Left hand side the number of force field evaluations per unit time. Right hand side the number of Fast-Fourier-transforms per unit time. Dotted line adaptive Verlet with the Chebyshev approximation for the quantum propagation. Dash-dotted line with the Lanczos iteration. Solid line stepsize controlling scheme based on PICKABACK. If the FFTs are the most expensive operations, PiCKABACK-like schemes are competitive, and the Lanczos iteration is significantly cheaper than the Chebyshev approximation. 

In particular, in silico methods are expected to speed up the drug discovery process, to provide a quicker and cheaper alternative to in vitro tests, and to reduce the number of compounds with unfavorable pharmacological properties at an early stage of drug development. Bad ADMET profiles are a reason for attrition of new drug candidates during the development process [9, 10]. The major reasons for attrition of new drugs are ... 

The complete filtration apparatus is shown in Fig. 5, p. 11. A simpler and cheaper apparatus is shown in Fig. 45. This consists of a boiling-tube A having a side-arm for connection to the pump the tube A is conveniently held in a wooden or cork block B or in a clamp. The funnel F may be fitted into A through a pliable rubber disc D the latter is more useful than a cork since it covers tubes of various diameters. The filtrate is collected in the centrifuge-tube T. 

Sodium dichromate is used instead of the potassium salt because it is far more soluble in water, and is not precipitated from its aqueous solution by addition of the ethanol. It is also cheaper than the potassium salt, but has the disadvantage of being deliquescent. 

CCI3COCH3 Ca(OH), -- 2CHCI3 -i- (Cll3COO)j.Ca The acetone method clearly gives a much cheaper product than the ethanol method. 

As a general rule esterification by the Fischer-Speier method should be carried out using absolute cthanob in the following preparation of ethyl benzoate, however, the yield is not sensibly affected by the use of the cheaper rectified spirit. 

It should be emphasised that whereas the interaction of a sodium salt and an acid chloride is a convenient general laboratory method for preparing all classes of anhydrides, acetic anhydride is prepared on a large scale by other and cheaper methods. Industrial processes are based on reactions indicated by the equations ... 

The melting points of these esters are usually much lower than those of the corresponding 3 5 dinitrobenzoates their preparation, therefore, offers no advantages over the latter except for alcohols of high molecular weight and for polyhydroxy compounds. The reagent is, however, cheaper than 3 5 dinitrobenzoyl chloride it hydrolyses in the air so that it should either be stored under light petroleum or be prepared from the acid, when required, by the thionyl chloride or phosphorus pentachloride method. 

This is essentially a Dean and Stark tube (employed for determinations of moisture) but uncalibrated the capacity of this receiver is 7-5-10 ml. A tube calibrated in 0 -1 ml. may, of course, be employed, but for large classes the cheaper uncalibrated tube possesses obvious advantages. 

Small quantities of the sjunmetrical ketones (CHjjjCO and (CHjCHjCHjjjCO (di-n-propyl ketone) are formed as by-products these can easily be removed by fractional distillation through an efficient column. An excess of the cheaper reagent, acetic acid, is employed the resulting acetone is readily removed by washing with water and little di-n-propyl ketone is formed under these conditions. 

The complete assembly for carrying out the catalytic decomposition of acids into ketones is shown in Fig. Ill, 72, 1. The main part of the apparatus consists of a device for dropping the acid at constant rate into a combustion tube containing the catalyst (manganous oxide deposited upon pumice) and heated electrically to about 350° the reaction products are condensed by a double surface condenser and coUected in a flask (which may be cooled in ice, if necessary) a glass bubbler at the end of the apparatus indicates the rate of decomposition (evolution of carbon dioxide). The furnace may be a commercial cylindrical furnace, about 70 cm. in length, but it is excellent practice, and certainly very much cheaper, to construct it from simple materials. 

I) A much better yield is obtained if galactose is employed. Lactose is generally preferred, however, as it is much cheaper. 

On the technical scale, the cheaper iron and hydrochloric acid is employed as the reducing agent ... 

Tlie advantages of this catalyst are that it is cheaper and less delicate than platinum, fairly large quantities can be hydrogenated, and the process is reason-aUy rapid. 

It is now obtained commercially by the electrolysis of absolutely dry fused sodium chloride. This method is much cheaper than that of electrolyzing sodium hydroxide, as was used several years ago. 

A is common to all the routes we are considering but it is obviously cheaper to use a mole of cyanide or nitromethane rather than another mole of rnalonate. In fact, though, these contribute relatively httle to the cost, the main part being p-chlorobenzaldehyde. So, use whichever route you hke ... 

Mass-produced workstation-class CPUs are much cheaper than traditional supercomputer processors. Thus, a larger amount of computing power for the dollar can be purchased by buying a parallel supercomputer that might have hundreds of workstation CPUs. 

Ether - Starting fluid (works great - Quaaaaack ) 2. Home made mercuric acetate (Now this stuff can be special ordered from ones chem supplier but there s a delay, may look funny - Quaaaaack , and is more expensive. So what is the solution to this Make it yourself Its easy, quantitative, and cheaper. Strike mentions this in the book and points ducks to a reference. Follow the EXACT same procedure for Mercuric Propionate except use glacial acetic acid...quack ). You ll need to use 20 to 25% more of the home brew mercuric acetate since it is a little contaminated with acetic (ducks can t get it totally dry without a vacuum oven). 3. NaOH washed Brazillian is fine Quack No need to purify further for starting material ... 

Although Pd is cheaper than Rh and Pt, it is still expensive. In Pd(0)- or Pd(ll)-catalyzed reactions, particularly in commercial processes, repeated use of Pd catalysts is required. When the products are low-boiling, they can be separated from the catalyst by distillation. The Wacker process for the production of acetaldehyde is an example. For less volatile products, there are several approaches to the economical uses of Pd catalysts. As one method, an alkyldi-phenylphosphine 9, in which the alkyl group is a polyethylene chain, is prepared as shown. The Pd complex of this phosphine has low solubility in some organic solvents such as toluene at room temperature, and is soluble at higher temperature[28]. Pd(0)-catalyzed reactions such as an allylation reaction of nucleophiles using this complex as a catalyst proceed smoothly at higher temperatures. After the reaction, the Pd complex precipitates and is recovered when the reaction mixture is cooled. 

For coupling, the cheaper aryl fluorosulfonate 713 is used as an alternative to the expensive aryl triflates to give the same results[473]. The arenesulfonates 714 are active for the reaction with vinylstannanes when dppp and LiCI are used in DMSO[583], The bromide 715 attacks the arylstannane moiety selectively without reacting with the organoboron moiety in 716 in the absence of a base[584]. 

---