Characteristics of Experiments

This chapter has the following structure in Sect. 3.2 the common characteristics of experiments are discussed. Conditions that are needed for proper comparison of experimental and theoretical results are formulated in Sect. 3.3. In Sect. 3.4 the data of flow of incompressible fluids in smooth and rough micro-channels are discussed. Section 3.5 deals with gas flows. The data on transition from laminar to turbulent flow are presented in Sect. 3.6. Effect of measurement accuracy is estimated in Sect. 3.7. A discussion on the flow in capillary tubes is given in Sect. 3.8. 

For the analysis of flow in micro-channels we use the following experimental data  

Transition from laminar to turbulent flow by Peng and Peterson (1996), Peng and Wang (1998), Pfund et al. (2000), Li et al. (2003) and Sharp and Adrian (2004) 

In general, conventional theory has been tested for flow in micro-channels by comparing the experimental and theoretical data on pressure drop as a function of flow rate. During the last few years, better methods have been used for measurement of the mean velocity, as well as rms of the velocity fluctuations (Maynes and Webb 2002 Sharp and Adrian 2004). 

Wall Material Glass, Silica, Stainless steel 

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Table 6.1 Onset of nucleate boiling. Characteristics of experiment...

This kind of relativity is becoming recognized in psychology under the topics of experimenter bias and the implicit demand characteristics of experiments. An experimenter s desire to prove the hypothesis he believes in not only can influence how he perceives his data, but also can subtly influence his subjects to cooperate in ways that will erroneously "prove" his hypothesis. Your beliefs about the nature of things around you can influence the way you see things and subtly influence others to uphold your view of reality. 

The results of both experiments showed that the analysis in the frequency domain provides new technological possibilities of testing characteristics of austenitic steels. Using known phase-frequency characteristics of structural noises it is possible to construct algorithms for separation of useful signal from the defect, even through amplitude values of noise and signal are close in value. 

Rowell and co-workers [62-64] have developed an electrophoretic fingerprint to uniquely characterize the properties of charged colloidal particles. They present contour diagrams of the electrophoretic mobility as a function of the suspension pH and specific conductance, pX. These fingerprints illustrate anomalies and specific characteristics of the charged colloidal surface. A more sophisticated electroacoustic measurement provides the particle size distribution and potential in a polydisperse suspension. Not limited to dilute suspensions, in this experiment, one characterizes the sonic waves generated by the motion of particles in an alternating electric field. O Brien and co-workers have an excellent review of this technique [65]. 

It should be noted that a number of different enzyme preparations can now be purchased directly from manufacturing chemists. It must be emphasised that the activity of an enzyme, whether purchased or prepared in the laboratory, may vary between rather wide limits. The activity is dependent on the source of the enzyme, the presence of poisons and also on the temperature. It appears, for example, that the quality of horseradish peroxidase depends upon the season of the year at which the root is obtained from the ground. It cannot be expected therefore that all the experiments described below will work always with the precision characteristic of an organic reaction proceeding under accurately known conditions. 

Experiments seem to show that the element possesses a moderately stable dipositive (11) oxidation state in addition to the tripositive (111) oxidation state, which is characteristic of the actinide elements. 

Characteristics of the system as nitrating reagents Wibaut, who introduced the competitive method for determining reactivities (his experiments with toluene, benzene and chlorobenzene were performed under heterogeneous conditions and were not successful), pointed out that solutions of nitric acid in acetic anhydride are useful in making comparisons of reactivities because aromatic compounds are soluble in them. ... 

Comparing two or more complex alternatives is more difficult than examining equipment capacity or first cost. Characteristics of alternatives should be weighted for relative importance and measured on a common scale to aEow proper evaluation. Many characteristics such as first cost, capacity, space requirement, and annual energy use can be measured objectively and used for system comparisons. Experience has shown that items such as maintenance expense, component life, and downtime can also be rehably estimated. Other factors, eg, system maintainabEity, flexibEity, and comfort, are more arbitrary. 

R = N(CH2CH3 )2) (LSD-25, as the tartrate salt) could be absorbed through the skin with resulting inebriation. In a bold experiment, it was then demonstrated that oral ingestion resulted in symptoms characteristic of schizophrenia which, although temporary, were quite dramatic (64). 

Flavor has been defined as a memory and an experience (1). These definitions have always included as part of the explanation at least two phenomena, ie, taste and smell (2). It is suggested that in defining flavor too much emphasis is put on the olfactory (smell) and gustatory (taste) aspects (3), and that vision, hearing, and tactile senses also contribute to the total flavor impression. Flavor is viewed as a division between physical sense, eg, appearance, texture, and consistency, and chemical sense, ie, smell, taste, and feeling (4). The Society of Flavor Chemists, Inc, defines flavor as "the sum total of those characteristics of any material taken in the mouth, perceived principally by the senses of taste and smell and also the general senses of pain and tactile receptors in the mouth, as perceived by the brain" (5). 

Asthma is an extremely complex condition characterized by variable and reversible airways obstmction combiaed with nonspecific bronchial hypersensitivity (1 3). The cause of asthma, which is not always readily diagnosed (4), remains unknown. Days, if not weeks, ate needed to document the spontaneous reversal of the airways obstmction ia some patients. Asthmatics experience both an immediate hypersensitivity response and a delayed late-phase reaction, each mediated by a different pathway. Chronic asthma has come to be viewed as an inflammatory disease (5). The late-phase reaction plays a key role ia iaduciag and maintaining the inflammatory state which ia turn is thought to iaduce the bronchial hyperresponsiveness (6). The airways obstmction results from both contraction of airways smooth muscle and excessive bronchial edema. Edema, a characteristic of inflammatory states, is accompanied, ia this case, by the formation of a viscous mucus which can completely block the small airways. 

Transport Models. Many mechanistic and mathematical models have been proposed to describe reverse osmosis membranes. Some of these descriptions rely on relatively simple concepts others are far more complex and require sophisticated solution techniques. Models that adequately describe the performance of RO membranes are important to the design of RO processes. Models that predict separation characteristics also minimize the number of experiments that must be performed to describe a particular system. Excellent reviews of membrane transport models and mechanisms are available (9,14,25-29). 

Ha2ard is the likelihood that the known toxicity of a material will be exhibited under specific conditions of use. It follows that the toxicity of a material, ie, its potential to produce injury, is but one of many considerations to be taken into account in assessment procedures with respect to defining ha2ard. The following are equally important factors that need to be considered physicochemical properties of the material use pattern of the material and characteristics of the environment where the material is handled source of exposure, normal and accidental control measures used to regulate exposure the duration, magnitude, and frequency of exposure route of exposure and physical nature of exposure conditions, eg, gas, aerosol, or Hquid population exposed and variabiUty in exposure conditions and experience with exposed human populations. 

Variables It is possible to identify a large number of variables that influence the design and performance of a chemical reactor with heat transfer, from the vessel size and type catalyst distribution among the beds catalyst type, size, and porosity to the geometry of the heat-transfer surface, such as tube diameter, length, pitch, and so on. Experience has shown, however, that the reactor temperature, and often also the pressure, are the primary variables feed compositions and velocities are of secondary importance and the geometric characteristics of the catalyst and heat-exchange provisions are tertiary factors. Tertiary factors are usually set by standard plant practice. Many of the major optimization studies cited by Westerterp et al. (1984), for instance, are devoted to reactor temperature as a means of optimization. 

The choice of size, shape, and type of electrode is based on economic considerations and is usually determined by the characteristics of the gas and suspended matter and by mechanical considerations such as flue arrangement, the available space, and previous experience with the electrodes on similar problems. The spacing between collecting electrodes in plate-type precipitators and the pipe diameter... 

Torque Rating The choice of torque rating has been discussed earlier. Torque is a function of such factors as quantity and quality of underflow (therefore, of such parameters as particle characteristics and flocculant dosage that affect underflow character), unit area, and rake speed but, in the final analysis, torque must be specified on the basis of experience modified by these factors. Unless one is experienced in a given apphcation, it is wise to consult a thickener or clarifier manufacturer. 

For the analysis heat and mass transfer in concrete samples at high temperatures, the numerical model has been developed. It describes concrete, as a porous multiphase system which at local level is in thermodynamic balance with body interstice, filled by liquid water and gas phase. The model allows researching the dynamic characteristics of diffusion in view of concrete matrix phase transitions, which was usually described by means of experiments. 

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