Alternating electric field

Rowell and co-workers [62-64] have developed an electrophoretic fingerprint to uniquely characterize the properties of charged colloidal particles. They present contour diagrams of the electrophoretic mobility as a function of the suspension pH and specific conductance, pX. These fingerprints illustrate anomalies and specific characteristics of the charged colloidal surface. A more sophisticated electroacoustic measurement provides the particle size distribution and potential in a polydisperse suspension. Not limited to dilute suspensions, in this experiment, one characterizes the sonic waves generated by the motion of particles in an alternating electric field. O Brien and co-workers have an excellent review of this technique [65]. 

The measurement of mass using a quartz crystal microbalance is based on the piezoelectric effect.When a piezoelectric material, such as a quartz crystal, experiences a mechanical stress, it generates an electrical potential whose magnitude is proportional to the applied stress. Gonversely, when an alternating electrical field is... 

Capacitive interference the production of electrical potentials in conductors due to the influence of alternating electrical fields (e.g., by high-voltage transmission lines under power). 

P. Zumbusch, W. Kulcke, G. Brunner. Use of alternating electric fields as antifouling strategy in ultrafiltration of biological suspensions. Introduction of a new experimental procedure for crossflow filtration. J Memb Sci 142-.15 (1998). R. L. Rowley, T. D. Shupe, M. W. Schuck. A direct method for determination of chemical potential with molecular dynamics simulations. 1. Pure components. Mol Phys 52 841, 1994. 

The second effect is caused by the operation of alternating electrical fields on the dielectric in the system. This can happen to insulation at power frequencies as well as higher frequencies. This is not the dielectric... 

A microwave plasma can also be produced by electron cyclotron resonance (ECR), through the proper combination of electric and magnetic fields.Cyclotron resonance is achieved when the frequency of the alternating electric field is made to match the natural frequency of the electrons orbiting the lines of force of the... 

If an electric held of the proper frequency is applied across the quartz crystal, the crystal wiU oscillate in a mechanically resonant mode. These condihons correspond to the creation of a standing acoustic shear wave that has a node midpoint between the two faces of the crystal and two antinodes at both faces of the disk. This is depicted schematically in Eig. 21.20b. In an EQCM experiment the crystals are operated at the fundamental resonant frequency that is a function of the thickness of the crystal. A crystal with a thickness of 330pm has a resonant frequency of 5 MHz. Crystals with these characteristics are commercially available. In an EQCM experiment, an alternating electric field of 5 MHz is applied to excite the quartz crystal into... 

The dielectric constant of a polymer (K) (which we also refer to as relative electric permittivity or electric inductive capacity) is a measure of its interaction with an electrical field in which it is placed. It is inversely related to volume resistivity. The dielectric constant depends strongly on the polarizability of molecules tvithin the polymer. In polymers with negligible dipole moments, the dielectric constant is low and it is essentially independent of temperature and the frequency of an alternating electric field. Polymers with polar constituents have higher dielectric constants. When we place such polymers in an electrical field, their dipoles attempt... 

Finally, ferroelectricity has been shown for columnar metallomesogens.35 Serrano and co-workers have shown that metal ft-diketonates, provided with chiral side chains (e.g., 32), form helical columns (vide supra), which can also be switched under an alternating electric field. 

On this subject notice that, possibly combined with various heating methods, several physical effects may be considered which allow free flotation of solid and even liquid matter. Materials may be levitated for instance by a jet of gas, by intense sound waves or by beams of laser light. Conductors levitate in strong radiofrequency fields, charged particles in alternating electric fields, magnets above superconductors or vice versa. A review on levitation in physics with the description of several techniques and their principles and applications was made by Brandt (1989). 

Dielectric particles show a reduced tendency for bubbling and a larger range of velocities over which particulate expansion occurs when an alternating electrical field is applied. 

M. Abe, A. Yamamoto, M. Orita, T. Ohkubo, H. Sakai, and Z. Momozawa, Control of particle alignment in water by an alternating electric field, Langmuir 20, 7021-7026 (2004). 

Let us now turn our attention to the application of the sound wave to a liquid since this is the medium of importance to the practising chemist. The sound wave is usually introduced to the medium by either an ultrasonic bath or an ultrasonic horn (see Chapter 7). In either case, an alternating electrical field (generally in the range 20-50 kHz) produces a mechanical vibration in a transducer, which in turn causes vibration of the probe (or bottom of the bath) at the applied electric field frequency. The horn (or bath bottom) then acts in a similar manner to one prong of a tuning fork. As in the case of air, the molecules of the liquid, under the action of the applied acoustic field, will vibrate about their mean position and an acoustic pressure (P = P sin 2k ft) will be superimposed upon the already ambient pressure (usually hydrostatic, Pjj) present in the liquid. The total pressure, P, in the liquid at any time, t, is given by Eq. 2.4. 

A slice of quartz develops a net positive charge on one side and a net negative charge on the other side when pressure is applied. The same effect is found when pressure is applied by means of an alternating electric field. This effect is known as the piezoelectric effect and is used for quartz watches and clocks, TVs, hearing aids, etc. 

The permeability of giant vesicles increased in an alternating electric field m-RNA synthesis occurred. 

Because of its piezoelectric properties, synthetic CC-quartz is used for frequency control in electrical oscillators and filters and in electromechanical transducers. When mechanically stressed in the correct direction, CC-quartz develops an electric polarization. The opposite is also tme an applied electric field gives rise to a mechanical distortion in the crystal. Thin sections of quartz are cut to dimensions that produce the desired resonance frequency when subjected to an alternating electric field the vibrating crystal then reacts with the driving circuit to produce an oscillation that can be narrowly controlled. Quartz is ideal for this application because it is hard, durable, readily synthesized, and can be tuned to high accuracy, for example, quartz crystal clocks can be made that are stable to one part in 109. 

The behaviour of dielectrics in alternating electric fields may be treated in the framework of forced harmonic oscillation. The displacement is then given by... 

When an alternating electric field of small amplitude is applied, we can measure the chemically induced complex dielectric increment (e )ch = ( )ch — i(e")ch [i = (— 1)1/2] as a function of frequency to. It can be shown (124) that t is then given by... 

Only those vibrations that result in a rhythmical change in the dipole moment of the molecule are observed in the IR. The alternating electric field, produced by the changing charge distribution accompanying a vibration, couples the molecule vibration with the oscillating electric field of the electromagnetic radiation. 

There are many sources of this paradoxical situation, in which a theoretical understanding lags far behind experiment in such a practically relevant area as electro-diffusion. There was a period of intense qualitative development in this area in the 1920s until the early 1950s when the modern classics of chemical physics developed the theory of electrolytic conductance and related phenomena [11]—[13]. These works were mainly concerned with the mean field approach to microscopic mechanisms determining such properties of electrolyte solutions as ion diffusivity, dielectric susceptibility, etc. in particular, they were concerned with the effects of an externally applied stationary and alternating electric field upon the above properties... 

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