Brittle fracture case

The transition from superplasticity to intermediate behavior (even at ductile fracture possibility) reduces A more than an order and some even less the value A in brittle fracture case. 

The glass-fibre nylons have a resistance to creep at least three times as great as unfilled polymers. In the case of impact strength the situation is complex since unfilled nylons tend to break showing tough fracture whereas the filled polymers break with a brittle fracture. On the other hand the glass-filled polymers are less notch sensitive and in some tests and service conditions the glass-filled nylons may prove the more satisfactory. 

From this therefore it is evident that the failure stress, ductile/brittle transitions which may be observed in plastics. According to line B, as the fiaw size decreases the failure stress tends towards infinity. Clearly this is not the case and in practice what happens is that at some defect size ([Pg.132]

Use materials that are applicable over the full range of operating conditions such as normal, startup, routine shutdown, emergency shutdown, and draining the system. For example, carbon steel may be acceptable for normal operating conditions but may be subject to brittle fracture at low temperatures under abnormal conditions (as in the case of a liquefied gas). Cold water, of less than 60°F, during hydrotest may cause brittle fracture of carbon steel. 

A detailed qualitative hazard assessment was performed for Process Unit 2. During this review, it was determined that the evaluation case event involving brittle fracture of the nitrogen vapor vessel was the only event of concern for process plant buildings for Process Unit 2. While other events... 

Hiestand has developed many indices that are useful for tablet formulations (16 18). These include the frequently cited brittle fracture index (BFI), the best-case bonding index (Bib), the worse-case bonding index (BI ), and the viscoelastic index (VI) (15,16). 

Strain rate sensitivity of (or the effect of press speed on) the formulation is of primary concern in scale-up. Whether the product development work was performed on a single-stroke press or a smaller rotary press, the objective in operations will be to increase efficiency, in this case the tablet output rate and, therefore, the speed of the press. For a material that deforms exclusively by brittle fracture, there will be no concern. Materials that exhibit plastic deformation, which is a kinetic phenomenon, do exhibit strain rate sensitivity, and the effect of press speed will be significant. One must be aware that although specific ingredients (such as calcium phosphate and lactose) may exhibit predominately brittle fracture behavior, almost everything has some plastic deformation component, and for some materials (such as microcrystalline cellulose) plastic deformation is the predominant behavior. The usual parameter indication is that target tablet hardness cannot be achieved at the faster press speed. Slowing the press may be the only option to correct the problem. 

Fracture often determines the reliability of a material in its practical applications. Brittle fracture of a material is the reason for a sudden catastrophe. The mechanical property ductile or brittle determines, in essence, whether or not a tool can be made from a given material. Let us identify the imperfections of a crystal and the chemical processes which cause ductility and brittleness. We distinguish two limiting cases of failure 1) A crystal, under external stress, deforms by forming a narrowing neck until eventually ductile rupture occurs. Dislocations are the only imperfections involved in this process of failure. 2) Crystals fracture suddenly. A sharp crack propagates and causes the failure. 

The main questions raised at the very beginning of the studies can be briefly formulated as follows. Can the potential energy accumulated in the mechanically nonequilibrium matrix of a frozen sample of reactants be released by its brittle fracture Will the accumulated mechanical energy transform into chemical energy, and will a chemical conversion take place in this case ... 

The explosive character of the photoinduced solid-state chlorination reaction of MCH was first described in ref. 31, the phenomenon being interpreted on the assumption of a decrease in the chain-growth activation energy due to the thermoelastic stresses induced in the sample. A possible role of brittle fracture was not considered in that case. However, it would be of interest also to take account of that effect under the conditions used in ref. 31, the more so in that the evaluated values of stresses required to reduce the activation energy markedly are far above the thresholds of brittle fracture of the corresponding matrices (for details, see Section XII). 

Using the experimental values for the width of the traveling wave front (portion be, Fig. 8), let us estimate the propagation velocity for the case of a thermal mechanism based on the Arrhenius law of heat evolution from the known relationship U = a/d, where a 10"2 cm2/s is the thermal conductivity determined by the conventional technique. We obtain 5 x 10"2 and 3 x 10-2cm/s for 77 and 4.2 K, respectively, which are below the experimental values by about 1.5-2 orders of magnitude. This result is further definite evidence for the nonthermal nature of the propagation mechanism of a low-temperature reaction initiated by brittle fracture of the irradiated reactant sample. 

Therefore, neither the appreciable plastic deformation (both in the case of uniform compression and of local fracture) of the solid reaction systems studied nor their static state of high stress is a factor conditioning the critical phenomena and autowave processes observed during the chemical conversion in the systems. In other words, this series of experiments has provided another telling argument for the decisive role of brittle fracture in the mechanism of the phenomena considered. 

In the case of good adhesion between fiber and matrix, brittle fracture of the fibers is observed. A further disadvantageous behavior was found in composites used in ultracentrifuges running at high temperature (60). Internal fracturing destroyed the integrity of the matrix, and loss of matrix as carbon dust was observed. These observations led to systematic studies of carbon/carbon composites with hybrid matrices (34). 

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