Di-n-butyl ketone

Di-n-butyl ketone n-Butyl bromide Tri-n-butyl carbinol 91... 

Di-N-Butyl Ketone Nonene 1-Nonene Nonene Nonanol... 

Di-n-butyl ketone ra-Butyl bromide T ri-n-butyl earbinol 91... 

Rearrangement of NJV-dilmloanunesf N,N-Dichloro-tri-n-butylcarbinamine (2), prepared by treatment of tri-n-butylcarbinamine (I) with calcium hypochlorite, when treated with aluminum chloride in methylene chloride at - 30°, followed by acid hydrolysis, gives di-n-butyl ketone (3) and n-butylaminc (4) in high yield. The reaction is considered to involve alkyl migration to electron-deficient nitrogen. 

The keto ester is refluxed for 3-4 hours with a 5% solution of potassium hydroxide in 90% ethanol followed by removal of the ethanol by distillation. The residue is diluted with water, and the organic layer is separated and distilled to give a 72% yield of di-n-butyl ketone boiling at 88°/22 mm. 

A recent publication describes the preparation by the peracid method of oxaziridines unsubstituted at nitrogen. The ketimines used were of benzo-phenone and di-n-butyl ketone. 

Di-N-Butyl Ketone Rubber gloves goggles or face shield. Remove to fresh air administer artificial respiration if needed. Flush with water. Flush with water for at least 15 minutes. 

Di-N-Butyl Ketone Data not available Data not available Data not available Data not available... 

Di-N-Butyl Ketone Data not available Data not available Data not available Data not available Foam, dry chemical, carbon dioxide Water may be ineffective Data not available Data not available No ... 

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