Di-n-hexyl ketone

Di-n-hexyl ketone Methyl ethyl ketone Methyl n-propyl ketone Methyl iso-propyl ketone Methyl n-butyl ketone Methyl iso-butyl ketone Methyl n-amyl ketone Methyl n-hexyl ketone Chloroacetone. ... 

The products of methyl n-hexyl ketone oxidation are capronic and acetic acids, capronic aldehyde, and diketone (130°C) [126], The hydroperoxide formed by the oxidation of di-iso-propyl ketone is relatively stable [127]. Decay of hydroperoxide produces acetone and isobutyric acid... 

Caspary (1968a) indicated the usefulness of low temperature for the identification of materials having room-temperature spectra which are similar to each other (e.g., -hexyl bromide and n-heptyl bromide -butylamine and n-hexylamine and sebacic acid di-n-butyl ester and azelaic acid di- -butyl ester [Fig. 3.16]). He compared other compounds at room temperature and low temperature, such as various ketones (19686) and aldehydes (1965). These substances, all of which are liquids at room temperature, show many differences at the low temperature. 

C6H5-C = CHC4Hg-n from a-diazoketones. Ethereal methyllithium added dropwise at 0 to a soln. of di-n-butyl-(l-phenyl-l-hexenyloxy)borane prepared from diazoacetophenone and tri-n-butylborane in tetrahydrofuran, the ice bath removed, stirred 1 hr. at room temp., methyl iodide added, and stirring continued 1.5 hrs. 2-hexyl phenyl ketone. Y 69%. Via vinyloxyboranes, a,a- and ,/5-dialkylated ketones can be obtained in good yield from a-diazoketones and methyl vinyl ketone respectively. F. e. s. D. J. Pasto and P. W. Wojtkowski, J. Org. Chem. 36, 1790 (1971). 

D, dodecane DCIE, 1,2-dichlorethane DOS, di-n-octyl sebacate HMK, hexyl methyl ketone... 

---