Anode Gaskets

The anode gaskets and rings are of soft and ebonite rubber, respectively. The inlet box is of rubber lined mild steel construction having a feed brine (sodium chloride) distributor and mercury seal. 

Anode gasket Cathode gasket Anode coating... 

Zn in KOH gel (anode. -) Gasket Separator Pellets of Aq20 in graphite (cathode. +)... 

Eig. 19. CME monopolar electrolyzer a, membrane b, cathode element c, half-cathode element d, current distributor e. Teflon tube f, CI2 + depleted brine manifold g, conductor rod h, CI2 + depleted brine outlet nozzle i, base frame j, recycled NaOH manifold k, recycled NaOH inlet nozzle 1, gasket (the gasket-to-element ratio is quite small) m, tie rod n, anode element o, H2 + NaOH manifold p, end plate, q, under cell bus bar (simplifies piping... 

The cell head is fabricated from a 2.54-cm steel plate and has separate compartments for fluorine and hydrogen. The oudet-gas manifolds, hydrogen fluoride feed and purge lines, and electrical connections are on top of the head. The gas separation skirt is made of Monel. An insulating gasket maintains the seal between the tank and the head. The anode assembly consists of 32 carbon blades bolted onto a copper bar, each of which contains three copper conductor posts. The cathode assembly consists of three vertical, 0.6-cm parallel steep plates. The plates surround the anode assembly and are supported by three steel posts which also serve as conductors. 

Polytetrafluoroethylene (PTFE) provides the most satisfactory electrical insulation. Concentric rings of PTFE and PTFE impregnated with calcium fluoride are used for the packing glands which support the anode and cathode posts. Rubber is used as the gasket material to form a seal between the cover... 

Plate and frame coolers using HasteUoy C-276 plates have been used successfuUy. Anodically protected plate coolers are available as weU as plate coolers with plates welded together to minimize gasketing. Another promising development is the introduction of plate coolers made of HasteUoy D205 (105). This aUoy has considerably better corrosion resistance to concentrated sulfuric acid at higher temperatures than does C-276. Because of the close clearance between plates, cooling water for plate coolers must be relatively clean. 

Anode electrode assembly, electrode panel between compression molded gaskets. 

Figure 19.21 shows the types of crevices used by Wilde " for studying crevice corrosion and pitting of Cr-Ni-Fe alloys in the laboratory and in the field. Types 1 and 5 were used for anodic polarisation studies in nitrogen-saturated 1 mol dm NaCl and in aerated 3-5 mass% NaCl, respectively, and it can be seen that attachment to the conducting lead is by means of a Stern-Makrides pressure gasket Types 3 and 4 were used for field tests... 

The anodes are platinized titanium (titanium plated with 5 microns of platinum) the cathodes are also titanium plated with 2.5 microns of platinum. All gaskets are Viton GF (peroxide grade), and the cell membranes are DuPont Nation 324. Flow through the cells is in parallel using manifolds with /4-inch fluid-flow inlet port orifices to provide equal flow to all cells. 

End plates and ports to be PVDF-lined ductile cast iron. Gaskets to be Viton for agent and Viton GF for energetics. Electrodes to be platinized titanium, pinhole-free, to a thickness of 5 micrometers for the anodes and 2.5 micrometers for the cathodes. 

In Fig. 9, the cathode block (4) of stainless steel includes inlet and outlet channels (6) that are each cormected by 6 boreholes for uniform flow distribution to the cathode surface (details see cross section 7). The anode (2) is a platinum foil of 18 cm active area with the brass cover plate (1) as current feeder. The electrode distance is given by the sealing gasket (3), for example, silicon rubber of 0.2-1 mm [85]. 

Fig. 10 Examples of parallel-plate and frame designs for laboratory flow-through cells (a) cell chamber for strong mixing and (b) various parts of a cylindrical cell. A anode (with preelectrode) G sealing gaskets AC anode compartment (glass ring, reduced mixing requirements) M membrane (diaphragm) CC cathode compartment (three tubes for gas outlet, sufficient mixing by gas evolution) C cathode (current feeders outside the cell at the four corners).

The plate cell was assembled from a flat platinum anode (18.5 x 5 cm) and a Monel cathode (18.5 x 5 cm) separated by a 0.5-2 mm thick Teflon gasket of the same size with an excision of 17 x 3 cm. The electrolyte was circulated through the cell and ail open reservoir at a rate of about 50 mL min 1 using a peristaltic pump. The minimum holdup of the loop was 7 mL. The electrolysis was carried out at rt (20 25 C) and 192.9 kC mol . Concentrations of the substrate varied from 25-250 g L Current density was maintained constant (3-6mA cm-2) using a potentiostat. After electrolysis. H,0 (200 mL) and CH2CI2 (100 mL) were added. The mixture was neutralized to pH 9 with K2CO,. The organic layer was filtered over silica gel. 

Cell DC-2. Earlier demineralization studies by Lyon (9) employed cell DC-2. This was a sandwich-type cell with Lucite side plates bolted together with two epoxy resin-gasketed graphite electrodes separated by an anion-permeable membrane. The membrane was necessary because a suitable anion-responsive electrode was not then known. The principle of operation is that in the cathode compartment, after several current reversal conditioning cycles, sodium ions are removed by the cathode while chloride ions migrate from the cathode through the membrane to the anion chamber. In the anode chamber, sodium ions, from the previous half cycles, are rejected from the anode. The net result was salt depletion in the cathode chamber and a similar concentration increase in the anode chamber. 

The metered valve crimped on an aluminum can (anodized or plastic coated) glass bottle creates the uniqueness of the MDI dosage form. The dimensions of the valve parts related to the crimp, such as ferrule and gasket thickness... 

Gasket Anode Printed Circuit Board Segmented Flow-Field Current Collector... 

Pt orAg mesh anode-supported ceil mica gasket Mi mesh Ni flow field Ni foil... 

Figure 8 (Top) Electrochemical flow cell for the oxidation of phenol and aniline (a) Pb anode feeder (b) packed bed of 1-mm lead pellets (c) stainless steel cathode plate (d) Nation membrane (e) stainless steel screen (f) Luggin capillary (g) glass beads (h) gasket (i) reactor inlet (j) reactor outlet. (Bottom) Schematic of apparatus (a) electrochemical reactor (b) peristaltic pump (c) water bath (d) heater (e) anolyte reservoir (t) gas sparging tube (g) C02 adsorbers. (From Ref. 39.)... 

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