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Aimed Structures

In a second step, an array of dots of molecules that will attract the nanoparticies are deposited onto the substrate. Although more recently, 16-thiohexadecanoic add has been used to bind positively charged particles such as protonated amine-or amidine-modified polystyrene spheres as building blocks from solution, the unpattemed regions of the gold substrate previously were passivated using an alkanethiol. [Pg.357]

It can be foreseen that not only two different sizes of the same type of metal can be used to generate those or other structures, but also that different metals can be used, leading to many possibilities with respect to future appHcations. [Pg.358]

This form of nanopartides organization is related to a method which is based on the wetting instabilities of monomolecular layers when transferred onto solid [Pg.359]

An external magnetic field orients the magnetic dipoles of individual nanopartides in one direction, fadlitating the formation of linear head-to-taU superstmctures. The chain of dipole-dipole-interacting nanopartides will align itself in the direction of an [Pg.361]

Currently, the best tool for fabricating aimed nanostructures is, without doubt, the atomic force microscope tip this was used by Mirkin et al. to develop DPN for [Pg.362]


D self-assembly of metal nanoparticles requires special conditions since 3D growth of any kind of material is preferred. Two principal strategies to generate 2D organizations of metal nanoparticles have been developed during the last 1-2 decades true self-assembly, guided self-assembly and aimed structures. [Pg.13]

This impressive example indicates possible routes to aimed structures of quantum dots that can be applied in future storage systems. [Pg.5954]

J.P. Aime Structural Characterization of Conjugated Polymer Solutions in The Undoped and Doped State in Conjugated Polymers, (Ed.) J.L. Bredas and R. Silbey, Kluwer Academic Publishers, Dordrecht (1991), p. 229. [Pg.247]

BLOCK ETAL. Antibacterial Compounds and Nalidbdc AiM Structure 303... [Pg.303]

The generation of 2-D and 1-D structures of metal nanoparticles can be achieved using very different techniques of (i) self assembly, (ii) guided self-assembly and (iii) aimed structures. Examples of these three principal routes are presented and discussed in the following subsections. [Pg.338]

The route to generate aimed structures in general, and those of metal nanoparticles in particular, via the electro-oxidation of SAMs shows great promise. A series of examples other than those discussed here is available in Ref. [111]. Further developments of this strategy will be necessary to render it competitive by comparison with current lithographic methods. Although the generation of extended nanostructured surfaces by means of automated techniques has already been achieved [112], the use of multi-tip systems should lead to remarkable improvements in the efficiency of the technique. [Pg.367]

On the other hand, in recent decades a wealth of experimental and theoretical evidence has been accumulated demonstrating molecular-like structure for systems not traditionally considered as molecular systems. One may include in this list the nuclear molecules in nuclear physics [18, 19], various exotic molecules composed of fundamental particles other than electron, protons and neutrons [20-31], artificial molecules in condensed-matter physics [32-35], and the molecular Bose-Einstein condensates [36-39]. In considering such molecular-like systems the question emerges whether any underlying AIM structure is derivable from the wavefunctions of these systems. To answer this question one must apply the AIM analysis to these systems however, all such systems are intrinsically non-Coulombic in their nature and the formalism of the orthodox QTAIM must be modified to be... [Pg.90]

Deffieux, A., Schappacher, M., Hirao, A., and Watanabe, T. (2008) Synthesis and AIM structural imaging of dendrimer-like star-branched polystyrenes. Journal ofthe American Chemical Society, 130,5670-5672. [Pg.164]

We have presented a neural network based spectrum classifier (NSC) aimed at ultrasonic resonance spectroscopy. The ultrasonic spectroscopy and the NSC has been evaluated in many industrial applications, such as concrete inspection, testing of aerospace composite structures, ball bearings, and aircraft multi-layer structures. The latter application has been presented in some detail. [Pg.111]

The research activity here presented has been carried out at the N.D.T. laboratory of l.S.P.E.S.L. (National Institute for Occupational Safety and Prevention) and it is aimed at the set up of the Stress Pattern Analysis by Measuring Thermal Emission technique [I] applied to pressure vessels. Basically, the SPATE system detects the infrared flux emitted from points resulting from the minute temperature changes in a cyclically stressed structure or component. [Pg.408]

Classification Societies exist to promote the safe construction of ships and to protect that condition throughout the life of the vessel. One of the tools available to shipbuilders, shipowners and surveyors that can be used to achieve these aims is Non-Destructive Examination (NDE). The intent of this presentation is to describe the application of NDE to hull structure during construction and also during periodic surveys as seen from the viewpoint of the Classification Surveyor. [Pg.1041]

There is a large volume of contemporary literature dealing with the structure and chemical properties of species adsorbed at the solid-solution interface, making use of various spectroscopic and laser excitation techniques. Much of it is phenomenologically oriented and does not contribute in any clear way to the surface chemistry of the system included are many studies aimed at the eventual achievement of solar energy conversion. What follows here is a summary of a small fraction of this literature, consisting of references which are representative and which also yield some specific information about the adsorbed state. [Pg.418]

Dry etching is a commonly used teclmique for creating highly anisotropic, patterned surfaces. The interaction of gas phase etchants with surfaces is of fundamental interest to understanding such phenomena as undercutting and the dependence of etch rate on surface structure. Many surface science studies aim to understand these interactions at an atomic level, and the next section will explore what is known about the etching of silicon surfaces. [Pg.934]

In this chapter we review some of the most important developments in recent years in connection with the use of optical teclmiques for the characterization of surfaces. We start with an overview of the different approaches available to tire use of IR spectroscopy. Next, we briefly introduce some new optical characterization methods that rely on the use of lasers, including nonlinear spectroscopies. The following section addresses the use of x-rays for diffraction studies aimed at structural detenninations. Lastly, passing reference is made to other optical teclmiques such as ellipsometry and NMR, and to spectroscopies that only partly depend on photons. [Pg.1780]

A multitude of different variants of this model has been investigated using Monte Carlo simulations (see, for example [M])- The studies aim at correlating the phase behaviour with the molecular architecture and revealing the local structure of the aggregates. This type of model has also proven useful for studying rather complex structures (e.g., vesicles or pores in bilayers). [Pg.2377]

The method presented in this chapter is aimed mainly at providing information on the presence of conical intersections in large molecules, and helps in the calculation of their energies and structures. In this section, we review briefly some other procedures used to characterize conical intersections, and compare them with the present method. [Pg.381]

Abstract. Molecular dynamics (MD) simulations of proteins provide descriptions of atomic motions, which allow to relate observable properties of proteins to microscopic processes. Unfortunately, such MD simulations require an enormous amount of computer time and, therefore, are limited to time scales of nanoseconds. We describe first a fast multiple time step structure adapted multipole method (FA-MUSAMM) to speed up the evaluation of the computationally most demanding Coulomb interactions in solvated protein models, secondly an application of this method aiming at a microscopic understanding of single molecule atomic force microscopy experiments, and, thirdly, a new method to predict slow conformational motions at microsecond time scales. [Pg.78]

The systematic lUPAC nomenclature of compounds tries to characterize compounds by a unique name. The names are quite often not as compact as the trivial names, which are short and simple to memorize. In fact, the lUPAC name can be quite long and cumbersome. This is one reason why trivial names are still heavily used today. The basic aim of the lUPAC nomenclature is to describe particular parts of the structure (fi agments) in a systematic manner, with special expressions from a vocabulary of terms. Therefore, the systematic nomenclature can be, and is, used in database systems such as the Chemical Abstracts Service (see Section 5.4) as index for chemical structures. However, this notation does not directly allow the extraction of additional information about the molecule, such as bond orders or molecular weight. [Pg.21]

This tutorial, which is based on the Beilstein update BS0202PR (May, 2002) and on the retrieval program Cro.ssFire Commander V6,. shows. some typical advanced search examples in the Beilstein database. It is assumed that the user already knows some of the basic features of the retrieval program. Moreover, in this tutorial the CrossFire Structure Editor is used instead of the (SIS/Draw Structure Editor. The first example is a combined application of structure aiM fact retrieval, whereas the second example demonstrates reaction retrieval. [Pg.249]

The TeleSpec system, which was funded by the DFN [77], was developed with the aim to provide a method to relieve this difficulty by simulating an IR spectrum for a given input structure. [Pg.530]

In contrast to IR and NMR spectroscopy, the principle of mass spectrometry (MS) is based on decomposition and reactions of organic molecules on theii way from the ion source to the detector. Consequently, structure-MS correlation is basically a matter of relating reactions to the signals in a mass spectrum. The chemical structure information contained in mass spectra is difficult to extract because of the complicated relationships between MS data and chemical structures. The aim of spectra evaluation can be either the identification of a compound or the interpretation of spectral data in order to elucidate the chemical structure [78-80],... [Pg.534]

We aim to show below how an explicit coding of the chemical structures of the starting materials and products of biochemical reactions and their reaction centers might allow us to achieve progress in our understanding of biochemical pathways. Furthermore, it will be shown how a bridge between chemoinformatics and bioinformatics can be built. [Pg.558]

The aim of a retrosynthetic analysis is the transformation of a synthesis target into progressively simpler structures, following a pathway to commercially available starting materials. [Pg.570]

The process of target identification analyzes a complex disease process by dissecting it into its fundamental components. This makes it possible to identify the one that is most integral to the manifestation of the disease. Target identification aims to understand the biological processes related to a disease, and to identify its mechanism and the structure of individual elements of the disease. Commonly these individual elements are receptors, enzymes, etc., which become the target of new drugs. [Pg.600]


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AIM

The aim and structure of this book

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